WC NET ENERGY - DESCALER POWDER 2F0049/2

Safety Data Sheet
WC NET ENERGY - DESCALER POWDER
2F0049/2



Safety Data Sheet dated 12/12/2011, version 2

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
      1.1. Product Identifier
             Mixture identification:
             Trade name:                        WC NET ENERGY - DESCALER POWDER
             Product code:                      2F0049
             Product type and use:              Toilet cleaner
      1.2. Relevant identified uses of the substance/mixture and uses advised against
             Recommended use:
             See label: instructions and precautions
             Uses advised against:
             See label: instructions and precautions.
      1.3. Details of the supplier of the safety data sheet
             Company:
             BOLTON MANITOBA SPA
             Via Pirelli, 19
             20124 Milano - Italy
             Tel. +39 02 6709 333 - Fax +39 0362 378 228
             Distributor:
             Alf.Mizzi & Sons (Mktg) Group
             Zachary House
             Marsa Industrial Estate -
             MARSA LQA 06 -MALTA - tel. 00356 2554 0000

            +39 02 67 09 333
      Competent person responsible for the safety data sheet:
            safetyinfo@boltonmanitoba.it
      1.4. Emergency telephone number
            00356 2554 0000
            030 274 8888

2. HAZARDS IDENTIFICATION
      2.1. Classification of the substance or mixture
      Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
      Properties / Symbols:
               Xi Irritant
      R Phrases:
             R36 Irritating to eyes.

      Adverse physicochemical, human health and environmental effects:
           No other hazards

      2.2. Label elements




      Symbols:
              Xi Irritant
      R Phrases:
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            R36 Irritating to eyes.
      S Phrases:
            S2 Keep out of reach of children.
            S25 Avoid contact with eyes.
            S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
            advice.
            S46 If swallowed, seek medical advice immediately and show this container or label.

      2.3. Other hazards
            vPvB Substances: None - PBT Substances: None
      Other Hazards:
            No other hazards

      Regulation (EC) nr 648/2004 (Detergents).
      Contains:
      5 - 15 %          anionic surfactants
      Also contains:    perfumes

3. COMPOSITION/INFORMATION ON INGREDIENTS
      3.1. Substances
            N.A.
      3.2. Mixtures
            Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and
            related classification:
      30% - 50% CITRIC ACID
            CAS: 77-92-9, EC: 201-069-1
            Xi; R36

      20% - 30% sodium carbonate
            REACH No.: 01-2119485498-19, Index number: 011-005-00-2, CAS: 497-19-8, EC: 207-838-8
            Xi; R36
               3.3/2 Eye Irrit. 2 H319

      10% - 20% sulphamidic acid; sulphamic acid; sulfamic acid
            REACH No.: 01-2119488633-28, Index number: 016-026-00-0, CAS: 5329-14-6, EC: 226-218-8
            Xi; R36/38-52/53
               3.3/2 Eye Irrit. 2 H319
               3.2/2 Skin Irrit. 2 H315
            4.1/C3 Aquatic Chronic 3 H412

      5% - 10% Reaction product of Benzenesulfonic acid, 4-C10-C13-sec-alkyl derivs. and Benzenesulfonic
      acid, 4-methyl- and sodium hydroxide
             REACH No.: 01-2119565112-48, EC: 932-051-8
             Xi; R41-38
                3.2/2 Skin Irrit. 2 H315
                3.3/1 Eye Dam. 1 H318




4. FIRST AID MEASURES
     4.1. Description of first aid measures
     In case of skin contact:
            Immediately take off all contaminated clothing.
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             Areas of the body that have - or are only even suspected of having - come into contact with the
             product must be rinsed immediately with plenty of running water and possibly with soap.
             Wash thoroughly the body (shower or bath).
             Remove contaminated clothing immediatley and dispose off safely.
             After contact with skin, wash immediately with soap and plenty of water.
      In case of eyes contact:
             After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time,
             then consult an opthalmologist immediately.
             Protect uninjured eye.
      In case of Ingestion:
             Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
             IMMEDIATELY.
      In case of Inhalation:
             Remove casualty to fresh air and keep warm and at rest.
      4.2. Most important symptoms and effects, both acute and delayed
             None
      4.3. Indication of any immediate medical attention and special treatment needed
             In case of accident or unwellness, seek medical advice immediately (show directions for use or
             safety data sheet if possible).
             Treatment:
             None

5. FIRE-FIGHTING MEASURES
      5.1. Extinguishing media
            Suitable extinguishing media:
            Water.
            Carbon dioxide (CO2).
            Extinguishing media which must not be used for safety reasons:
            None in particular.
      5.2. Special hazards arising from the substance or mixture
            Do not inhale explosion and combustion gases.
            Burning produces heavy smoke.
      5.3. Advice for fire-fighters
            Use suitable breathing apparatus .
            Collect contaminated fire extinguishing water separately. This must not be discharged into
            drains.
            Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES
      6.1. Personal precautions, protective equipment and emergency procedures
            Wear personal protection equipment.
            Remove persons to safety.
            See protective measures under point 7 and 8.
      6.2. Environmental precautions
            Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
            Retain contaminated washing water and dispose it.
            In case of gas escape or of entry into waterways, soil or drains, inform the responsible
            authorities.
            Suitable material for taking up: absorbing material, organic, sand
      6.3. Methods and material for containment and cleaning up
            Wash with plenty of water.
      6.4. Reference to other sections
            See also section 8 and 13

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7. HANDLING AND STORAGE
      7.1. Precautions for safe handling
             Avoid contact with skin and eyes, inhaltion of vapours and mists.
             Don't use empty container before they have been cleaned.
             Before making transfer operations, assure that there aren't any incompatible material residuals
             in the containers.
             Contamined clothing should be changed before entering eating areas.
             Do not eat or drink while working.
             See also section 8 for recomened protective equipment.
      7.2. Conditions for safe storage, including any incompatibilities
             Keep away from food, drink and feed.
             Incompatible materials:
             None in particular.
             Instructions as regards storage premises:
             Adequately ventilated premises.
      7.3. Specific end use(s)
             None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
      8.1. Control parameters
            None.
      DNEL Exposure Limit Values
            N.A.
      PNEC Exposure Limit Values
            N.A.
      8.2. Exposure controls
      Eye protection:
            Use close fitting safety goggles, don't use eye lens.
      Protection for skin:
            No special precaution must be adopted for normal use.
      Protection for hands:
            Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
      Respiratory protection:
            Not needed for normal use.
      Thermal Hazards:
            None
      Environmental exposure controls:
            None

9. PHYSICAL AND CHEMICAL PROPERTIES
      9.1. Information on basic physical and chemical properties
             Appearance and colour:              Powder
             Odour threshold:                    Not Relevant
             pH:                                 4.5
             Melting point / freezing point:     N.A.
             Initial boiling point and boiling range:      Not Relevant
             Solid/gas flammability:             Not Relevant
             Upper/lower flammability or explosive limits:          Not Relevant
             Vapour density:                     N.A.
             Flash point:                        Not Relevant
             Evaporation rate:                   N.A.
             Vapour pressure:                    N.A.
             Relative density:                   0,95 kg/l
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            Solubility in water:              Complete
            Lipid solubility:                 Insoluble
            Partition coefficient (n-octanol/water):    Not Relevant
            Auto-ignition temperature:        N.A.
            Decomposition temperature:        N.A.
            Viscosity:                        Not Relevant
            Explosive properties:             N.A.
            Oxidizing properties:             Not Relevant
      9.2. Other information
            Miscibility:                      N.A.
            Fat Solubility:                   Not Relevant
            Conductivity:                     N.A.
            Substance Groups relevant properties        N.A.

10. STABILITY AND REACTIVITY
      10.1. Reactivity
             Stable under normal conditions
      10.2. Chemical stability
             Stable under normal conditions
      10.3. Possibility of hazardous reactions
             None
      10.4. Conditions to avoid
             Stable under normal conditions.
      10.5. Incompatible materials
             None in particular.
      10.6. Hazardous decomposition products
             None.

11. TOXICOLOGICAL INFORMATION
      11.1. Information on toxicological effects
      Toxicological information of the mixture:
              N.A.
      Toxicological information of the main substances found in the mixture:
              N.A.
      If not differently specified, the information required in Regulation 453/2010/EC listed below must be
      considered as N.A.:
              a) acute toxicity;
              b) skin corrosion/irritation;
              c) serious eye damage/irritation;
              d) respiratory or skin sensitisation;
              e) germ cell mutagenicity;
              f) carcinogenicity;
              g) reproductive toxicity;
              h) STOT-single exposure;
              i) STOT-repeated exposure;
              j) aspiration hazard.

12. ECOLOGICAL INFORMATION
      12.1. Toxicity
             Adopt good working practices, so that the product is not released into the environment.
      12.2. Persistence and degradability
             None
             N.A.
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      12.3. Bioaccumulative potential
             N.A.
      12.4. Mobility in soil
             N.A.
      12.5. Results of PBT and vPvB assessment
             vPvB Substances: None - PBT Substances: None
      12.6. Other adverse effects
             None

13. DISPOSAL CONSIDERATIONS
      13.1. Waste treatment methods
            Recover if possible. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION



      14.1. UN number
             Not classified as dangerous in the meaning of transport regulations.
      14.2. UN proper shipping name
             N.A.
      14.3. Transport hazard class(es)
             N.A.
      14.4. Packing Group
             N.A.
      14.5 Environmental hazards
      14.6. Special Precautions for User
             N.A.
      14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
             N.A.

15. REGULATORY INFORMATION
      15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
      Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC
      (Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to
      chemical agents at work). Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE.
      Regulation (CE) n. 1907/2006 (REACH), Regulation (CE) n. 1272/2008 (CLP), Regulation (CE) n.
      790/2009 (1° ATP CLP), Regulation (EU) n. 453/2010 (Annex I).
      Where applicable, refer to the following regulatory provisions :
             Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
             amendments.
             Regulation (EC) nr 648/2004 (detergents).
             1999/13/EC (VOC directive)
             Surfactants contained in this mixture comply biodegradability requirements prescribed by
             Detergent Regulation 648/2004/CE.


      15.2. Chemical Safety Assessment
            No



16. OTHER INFORMATION
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      Text of phrases referred to under heading 3:
            R36 Irritating to eyes.
            R36/38 Irritating to eyes and skin.
            R38 Irritating to skin.
            R41 Risk of serious damage to eyes.
            R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
            environment.

             H319 Causes serious eye irritation.
             H315 Causes skin irritation.
             H412 Harmful to aquatic life with long lasting effects.
             H318 Causes serious eye damage.

      Paragraphs modified from the previous revision:

             1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
             COMPANY/UNDERTAKING
             15. REGULATORY INFORMATION

      This document was prepared by a competent person who has received appropriate training.
      Main bibliographic sources:
              ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
              Commission of the European Communities
              SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
              Nostrand Reinold
              CCNL - Appendix 1
              Insert further consulted bibliography
      The information contained herein is based on our state of knowledge at the above-specified date. It
      refers solely to the product indicated and constitutes no guarantee of particular quality.
      It is the duty of the user to ensure that this information is appropriate and complete with respect to the
      specific use intended.
      This MSDS cancels and replaces any preceding release.

      ADR:             European Agreement concerning the International Carriage of
                       Dangerous Goods by Road.
      CAS:             Chemical Abstracts Service (division of the American Chemical Society).
      CLP:             Classification, Labeling, Packaging.
      DNEL:            Derived No Effect Level.
      EINECS:          European Inventory of Existing Commercial Chemical Substances.
      GefStoffVO:      Ordinance on Hazardous Substances, Germany.
      GHS:             Globally Harmonized System of Classification and Labeling of
                       Chemicals.
      IATA:            International Air Transport Association.
      IATA-DGR:        Dangerous Goods Regulation by the "International Air Transport
                       Association" (IATA).
      ICAO:            International Civil Aviation Organization.
      ICAO-TI:         Technical Instructions by the "International Civil Aviation Organization"
                       (ICAO).
      IMDG:            International Maritime Code for Dangerous Goods.
      INCI:            International Nomenclature of Cosmetic Ingredients.
      KSt:             Explosion coefficient.
      LC50:            Lethal concentration, for 50 percent of test population.
      LD50:            Lethal dose, for 50 percent of test population.
      LTE:             Long-term exposure.

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      PNEC:      Predicted No Effect Concentration.
      RID:       Regulation Concerning the International Transport of Dangerous Goods
                 by Rail.
      STE:       Short-term exposure.
      STEL:      Short Term Exposure limit.
      STOT:      Specific Target Organ Toxicity.
      TLV:       Threshold Limiting Value.
      TWATLV:    Threshold Limit Value for the Time Weighted Average 8 hour day.
                 (ACGIH Standard).
      WGK:       German Water Hazard Class.




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     (violet)

Safety Data Sheet dated 12/12/2011, version 2

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
     1.1. Product Identifier
            Mixture identification:
            Trade name:                        WC NET INTENSE GEL - LAVENDER FRESH / PROVENCE
            (violet)
            Product code:                      2F0038
            Product type and use:              Toilet cleaner
     1.2. Relevant identified uses of the substance/mixture and uses advised against
            Recommended use:
            See label: instructions and precautions
            Uses advised against:
            See label: instructions and precautions.
     1.3. Details of the supplier of the safety data sheet
            Company:
            BOLTON MANITOBA SPA
            Via Pirelli, 19
            20124 Milano - Italy
            Tel. +39 02 6709 333 - Fax +39 0362 378 228
            Distributor:
            Alf.Mizzi & Sons (Mktg) Group
            Zachary House
            Marsa Industrial Estate -
            MARSA LQA 06 -MALTA - tel. 00356 2554 0000

           +39 02 67 09 333
     Competent person responsible for the safety data sheet:
           safetyinfo@boltonmanitoba.it
     1.4. Emergency telephone number
           00356 2554 0000
           030 274 8888

2. HAZARDS IDENTIFICATION
     2.1. Classification of the substance or mixture
     Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
     Properties / Symbols:
            None.

     Adverse physicochemical, human health and environmental effects:
          No other hazards

     2.2. Label elements
     The preparation should not be considered as dangerous accordingly to dir. 1999/45/EC.

     2.3. Other hazards
           vPvB Substances: None - PBT Substances: None
     Other Hazards:
           No other hazards

     Regulation (EC) nr 648/2004 (Detergents).
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      Contains:
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            Wear personal protection equipment.
            Remove persons to safety.
            See protective measures under point 7 and 8.
      6.2. Environmental precautions
            Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
            Retain contaminated washing water and dispose it.
            In case of gas escape or of entry into waterways, soil or drains, inform the responsible
            authorities.
            Suitable material for taking up: absorbing material, organic, sand
      6.3. Methods and material for containment and cleaning up
            Wash with plenty of water.
      6.4. Reference to other sections
            See also section 8 and 13

7. HANDLING AND STORAGE
      7.1. Precautions for safe handling
             Avoid contact with skin and eyes, inhaltion of vapours and mists.
             Do not eat or drink while working.
             See also section 8 for recomened protective equipment.
      7.2. Conditions for safe storage, including any incompatibilities
             Keep away from food, drink and feed.
             Incompatible materials:
             None in particular.
             Instructions as regards storage premises:
             Adequately ventilated premises.
      7.3. Specific end use(s)
             None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
      8.1. Control parameters
            None.
      DNEL Exposure Limit Values
            N.A.
      PNEC Exposure Limit Values
            N.A.
      8.2. Exposure controls
      Eye protection:
            Not needed for normal use. Anyway, operate according good working practices.
      Protection for skin:
            No special precaution must be adopted for normal use.
      Protection for hands:
            Not needed for normal use.
      Respiratory protection:
            Not needed for normal use.
      Thermal Hazards:
            None
      Environmental exposure controls:
            None

9. PHYSICAL AND CHEMICAL PROPERTIES
      9.1. Information on basic physical and chemical properties
             Appearance and colour:          Transparent liquid
             Odour:                          Characteristic
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            Odour threshold:                    N.D.
            pH:                                 2.1
            Melting point / freezing point:     N.A.
            Initial boiling point and boiling range:      N.A.
            Solid/gas flammability:             Not Relevant
            Upper/lower flammability or explosive limits:        N.A.
            Vapour density:                     N.A.
            Flash point:                        N.A.
            Evaporation rate:                   N.A.
            Vapour pressure:                    N.A.
            Relative density:                   1.0 kg/l
            Solubility in water:                Complete
            Lipid solubility:                   Insoluble
            Partition coefficient (n-octanol/water):      N.A.
            Auto-ignition temperature:          N.A.
            Decomposition temperature:          N.A.
            Viscosity:                          1100 cps
            Explosive properties:               Not Relevant
            Oxidizing properties:               Not Relevant
      9.2. Other information
            Miscibility:                        N.A.
            Fat Solubility:                     N.A.
            Conductivity:                       N.A.
            Substance Groups relevant properties          N.A.

10. STABILITY AND REACTIVITY
      10.1. Reactivity
             Stable under normal conditions
      10.2. Chemical stability
             Stable under normal conditions
      10.3. Possibility of hazardous reactions
             None
      10.4. Conditions to avoid
             Stable under normal conditions.
      10.5. Incompatible materials
             None in particular.
      10.6. Hazardous decomposition products
             None.

11. TOXICOLOGICAL INFORMATION
     11.1. Information on toxicological effects
     Toxicological information of the mixture:
             N.A.
     Toxicological information of the main substances found in the mixture:
             N.A.
     If not differently specified, the information required in Regulation 453/2010/EC listed below must be
     considered as N.A.:
             a) acute toxicity;
             b) skin corrosion/irritation;
             c) serious eye damage/irritation;
             d) respiratory or skin sensitisation;
             e) germ cell mutagenicity;
             f) carcinogenicity;
             g) reproductive toxicity;
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            h) STOT-single exposure;
            i) STOT-repeated exposure;
            j) aspiration hazard.

12. ECOLOGICAL INFORMATION
      12.1. Toxicity
             Adopt good working practices, so that the product is not released into the environment.
             ALCOHOL, ETHOXYLATED - CAS: 68439-50-9
                    Test: LC50 - Species: Fish - Duration h: 96 - mg/l: 0.101-1
                    Test: EC50 - Species: Daphnia - Duration h: 48 - mg/l: 0.101-1
                    Test: EC50 - Species: Algae - Duration h: 96 - mg/l: 0.101-1
      12.2. Persistence and degradability
             None
             N.A.
      12.3. Bioaccumulative potential
             N.A.
      12.4. Mobility in soil
             N.A.
      12.5. Results of PBT and vPvB assessment
             vPvB Substances: None - PBT Substances: None
      12.6. Other adverse effects
             None

13. DISPOSAL CONSIDERATIONS
      13.1. Waste treatment methods
            Recover if possible. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION



      14.1. UN number
             Not classified as dangerous in the meaning of transport regulations.
      14.2. UN proper shipping name
             N.A.
      14.3. Transport hazard class(es)
             N.A.
      14.4. Packing Group
             N.A.
      14.5 Environmental hazards
      14.6. Special Precautions for User
             N.A.
      14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
             N.A.

15. REGULATORY INFORMATION
     15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
     Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC
     (Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to
     chemical agents at work). Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE.
     Regulation (CE) n. 1907/2006 (REACH), Regulation (CE) n. 1272/2008 (CLP), Regulation (CE) n.
     790/2009 (1° ATP CLP), Regulation (EU) n. 453/2010 (Annex I).
     Where applicable, refer to the following regulatory provisions :
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             Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
             amendments.
             Regulation (EC) nr 648/2004 (detergents).
             1999/13/EC (VOC directive)
             Surfactants contained in this mixture comply biodegradability requirements prescribed by
             Detergent Regulation 648/2004/CE.


      15.2. Chemical Safety Assessment
            No



16. OTHER INFORMATION
      Text of phrases referred to under heading 3:
            R22 Harmful if swallowed.
            R41 Risk of serious damage to eyes.
            R50 Very toxic to aquatic organisms.


      Paragraphs modified from the previous revision:

             1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
             COMPANY/UNDERTAKING
             15. REGULATORY INFORMATION

      This document was prepared by a competent person who has received appropriate training.
      Main bibliographic sources:
              ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
              Commission of the European Communities
              SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
              Nostrand Reinold
              CCNL - Appendix 1
              Insert further consulted bibliography
      The information contained herein is based on our state of knowledge at the above-specified date. It
      refers solely to the product indicated and constitutes no guarantee of particular quality.
      It is the duty of the user to ensure that this information is appropriate and complete with respect to the
      specific use intended.
      This MSDS cancels and replaces any preceding release.

      ADR:            European Agreement concerning the International Carriage of
                      Dangerous Goods by Road.
      CAS:            Chemical Abstracts Service (division of the American Chemical Society).
      CLP:            Classification, Labeling, Packaging.
      DNEL:           Derived No Effect Level.
      EINECS:         European Inventory of Existing Commercial Chemical Substances.
      GefStoffVO:     Ordinance on Hazardous Substances, Germany.
      GHS:            Globally Harmonized System of Classification and Labeling of
                      Chemicals.
      IATA:           International Air Transport Association.
      IATA-DGR:       Dangerous Goods Regulation by the "International Air Transport
                      Association" (IATA).
      ICAO:           International Civil Aviation Organization.
      ICAO-TI:        Technical Instructions by the "International Civil Aviation Organization"
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                 (ICAO).
      IMDG:      International Maritime Code for Dangerous Goods.
      INCI:      International Nomenclature of Cosmetic Ingredients.
      KSt:       Explosion coefficient.
      LC50:      Lethal concentration, for 50 percent of test population.
      LD50:      Lethal dose, for 50 percent of test population.
      LTE:       Long-term exposure.
      PNEC:      Predicted No Effect Concentration.
      RID:       Regulation Concerning the International Transport of Dangerous Goods
                 by Rail.
      STE:       Short-term exposure.
      STEL:      Short Term Exposure limit.
      STOT:      Specific Target Organ Toxicity.
      TLV:       Threshold Limiting Value.
      TWATLV:    Threshold Limit Value for the Time Weighted Average 8 hour day.
                 (ACGIH Standard).
      WGK:       German Water Hazard Class.




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WC NET SCARICHI DOMESTICI
2F0036/2



Safety Data Sheet dated 12/12/2011, version 2

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
      1.1. Product Identifier
             Mixture identification:
             Trade name:                        WC NET SCARICHI DOMESTICI
             Product code:                      2F0036
             Product type and use:              Homedrain cleaner
      1.2. Relevant identified uses of the substance/mixture and uses advised against
             Recommended use:
             See label: instructions and precautions
             Uses advised against:
             See label: instructions and precautions.
      1.3. Details of the supplier of the safety data sheet
             Company:
             BOLTON MANITOBA SPA
             Via Pirelli, 19
             20124 Milano - Italy
             Tel. +39 02 6709 333 - Fax +39 0362 378 228
             Distributor:
             Alf.Mizzi & Sons (Mktg) Group
             Zachary House
             Marsa Industrial Estate -
             MARSA LQA 06 -MALTA - tel. 00356 2554 0000

            +39 02 67 09 333
      Competent person responsible for the safety data sheet:
            safetyinfo@boltonmanitoba.it
      1.4. Emergency telephone number
            00356 2554 0000
            030 274 8888

2. HAZARDS IDENTIFICATION
      2.1. Classification of the substance or mixture
      Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
      Properties / Symbols:
             None.

      Adverse physicochemical, human health and environmental effects:
           No other hazards

      2.2. Label elements
      The preparation should not be considered as dangerous accordingly to dir. 1999/45/EC.

      2.3. Other hazards
            vPvB Substances: None - PBT Substances: None
      Other Hazards:
            No other hazards

     Regulation (EC) nr 648/2004 (Detergents).
     Contains:
Safety Data Sheet
WC NET SCARICHI DOMESTICI
2F0036/2


      Also contains:      perfumes
      Preservatives       1,2-benzisothiazol-3(2H)-one; 1,2-benzisothiazolin-3-one

3. COMPOSITION/INFORMATION ON INGREDIENTS
      3.1. Substances
            N.A.
      3.2. Mixtures
            Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and
            related classification:
      None.



4. FIRST AID MEASURES
      4.1. Description of first aid measures
      In case of skin contact:
             Wash with plenty of water and soap.
      In case of eyes contact:
             In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
      In case of Ingestion:
             Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
             IMMEDIATELY.
      In case of Inhalation:
             Remove casualty to fresh air and keep warm and at rest.
      4.2. Most important symptoms and effects, both acute and delayed
             None
      4.3. Indication of any immediate medical attention and special treatment needed
             Treatment:
             None

5. FIRE-FIGHTING MEASURES
      5.1. Extinguishing media
            Suitable extinguishing media:
            Water.
            Carbon dioxide (CO2).
            Extinguishing media which must not be used for safety reasons:
            None in particular.
      5.2. Special hazards arising from the substance or mixture
            Do not inhale explosion and combustion gases.
            Burning produces heavy smoke.
      5.3. Advice for fire-fighters
            Use suitable breathing apparatus .
            Collect contaminated fire extinguishing water separately. This must not be discharged into
            drains.
            Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES
     6.1. Personal precautions, protective equipment and emergency procedures
            Wear personal protection equipment.
            Remove persons to safety.
            See protective measures under point 7 and 8.
     6.2. Environmental precautions
            Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
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            Retain contaminated washing water and dispose it.
            In case of gas escape or of entry into waterways, soil or drains, inform the responsible
            authorities.
            Suitable material for taking up: absorbing material, organic, sand
      6.3. Methods and material for containment and cleaning up
            Wash with plenty of water.
      6.4. Reference to other sections
            See also section 8 and 13

7. HANDLING AND STORAGE
      7.1. Precautions for safe handling
             Avoid contact with skin and eyes, inhaltion of vapours and mists.
             Do not eat or drink while working.
             See also section 8 for recomened protective equipment.
      7.2. Conditions for safe storage, including any incompatibilities
             Keep away from food, drink and feed.
             Incompatible materials:
             None in particular.
             Instructions as regards storage premises:
             Adequately ventilated premises.
      7.3. Specific end use(s)
             None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
      8.1. Control parameters
            None.
      DNEL Exposure Limit Values
            N.A.
      PNEC Exposure Limit Values
            N.A.
      8.2. Exposure controls
      Eye protection:
            Not needed for normal use. Anyway, operate according good working practices.
      Protection for skin:
            No special precaution must be adopted for normal use.
      Protection for hands:
            Not needed for normal use.
      Respiratory protection:
            Not needed for normal use.
      Thermal Hazards:
            None
      Environmental exposure controls:
            None

9. PHYSICAL AND CHEMICAL PROPERTIES
      9.1. Information on basic physical and chemical properties
             Appearance and colour:              Opaque liquid
             Odour:                              Characteristic
             Odour threshold:                    N.D.
             pH:                                 8.8
             Melting point / freezing point:     N.A.
             Initial boiling point and boiling range:     N.A.
             Solid/gas flammability:             Not Relevant
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            Upper/lower flammability or explosive limits:        N.A.
            Vapour density:                   N.A.
            Flash point:                      N.A.
            Evaporation rate:                 N.A.
            Vapour pressure:                  N.A.
            Relative density:                 1.0 kg/l
            Solubility in water:              Complete
            Lipid solubility:                 Insoluble
            Partition coefficient (n-octanol/water):    Not Relevant
            Auto-ignition temperature:        N.A.
            Decomposition temperature:        N.A.
            Viscosity:                        800 cps
            Explosive properties:             Not Relevant
            Oxidizing properties:             Not Relevant
      9.2. Other information
            Miscibility:                      N.A.
            Fat Solubility:                   N.A.
            Conductivity:                     N.A.
            Substance Groups relevant properties        N.A.

10. STABILITY AND REACTIVITY
      10.1. Reactivity
             Stable under normal conditions
      10.2. Chemical stability
             Stable under normal conditions
      10.3. Possibility of hazardous reactions
             None
      10.4. Conditions to avoid
             Stable under normal conditions.
      10.5. Incompatible materials
             None in particular.
      10.6. Hazardous decomposition products
             None.

11. TOXICOLOGICAL INFORMATION
      11.1. Information on toxicological effects
      Toxicological information of the mixture:
              N.A.
      Toxicological information of the main substances found in the mixture:
              N.A.
      If not differently specified, the information required in Regulation 453/2010/EC listed below must be
      considered as N.A.:
              a) acute toxicity;
              b) skin corrosion/irritation;
              c) serious eye damage/irritation;
              d) respiratory or skin sensitisation;
              e) germ cell mutagenicity;
              f) carcinogenicity;
              g) reproductive toxicity;
              h) STOT-single exposure;
              i) STOT-repeated exposure;
              j) aspiration hazard.


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12. ECOLOGICAL INFORMATION
      12.1. Toxicity
             Adopt good working practices, so that the product is not released into the environment.
      12.2. Persistence and degradability
             None
             N.A.
      12.3. Bioaccumulative potential
             N.A.
      12.4. Mobility in soil
             N.A.
      12.5. Results of PBT and vPvB assessment
             vPvB Substances: None - PBT Substances: None
      12.6. Other adverse effects
             None

13. DISPOSAL CONSIDERATIONS
      13.1. Waste treatment methods
            Recover if possible. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION



      14.1. UN number
             Not classified as dangerous in the meaning of transport regulations.
      14.2. UN proper shipping name
             N.A.
      14.3. Transport hazard class(es)
             N.A.
      14.4. Packing Group
             N.A.
      14.5 Environmental hazards
      14.6. Special Precautions for User
             N.A.
      14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
             N.A.

15. REGULATORY INFORMATION
      15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
      Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC
      (Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to
      chemical agents at work). Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE.
      Regulation (CE) n. 1907/2006 (REACH), Regulation (CE) n. 1272/2008 (CLP), Regulation (CE) n.
      790/2009 (1° ATP CLP), Regulation (EU) n. 453/2010 (Annex I).
      Where applicable, refer to the following regulatory provisions :
             Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
             amendments.
             Regulation (EC) nr 648/2004 (detergents).
             1999/13/EC (VOC directive)
             Surfactants contained in this mixture comply biodegradability requirements prescribed by
             Detergent Regulation 648/2004/CE.


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      15.2. Chemical Safety Assessment
            No



16. OTHER INFORMATION


      Paragraphs modified from the previous revision:

             1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
             COMPANY/UNDERTAKING
             9. PHYSICAL AND CHEMICAL PROPERTIES
             15. REGULATORY INFORMATION

      This document was prepared by a competent person who has received appropriate training.
      Main bibliographic sources:
              ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
              Commission of the European Communities
              SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
              Nostrand Reinold
              CCNL - Appendix 1
              Insert further consulted bibliography
      The information contained herein is based on our state of knowledge at the above-specified date. It
      refers solely to the product indicated and constitutes no guarantee of particular quality.
      It is the duty of the user to ensure that this information is appropriate and complete with respect to the
      specific use intended.
      This MSDS cancels and replaces any preceding release.

      ADR:            European Agreement concerning the International Carriage of
                      Dangerous Goods by Road.
      CAS:            Chemical Abstracts Service (division of the American Chemical Society).
      CLP:            Classification, Labeling, Packaging.
      DNEL:           Derived No Effect Level.
      EINECS:         European Inventory of Existing Commercial Chemical Substances.
      GefStoffVO:     Ordinance on Hazardous Substances, Germany.
      GHS:            Globally Harmonized System of Classification and Labeling of
                      Chemicals.
      IATA:           International Air Transport Association.
      IATA-DGR:       Dangerous Goods Regulation by the "International Air Transport
                      Association" (IATA).
      ICAO:           International Civil Aviation Organization.
      ICAO-TI:        Technical Instructions by the "International Civil Aviation Organization"
                      (ICAO).
      IMDG:           International Maritime Code for Dangerous Goods.
      INCI:           International Nomenclature of Cosmetic Ingredients.
      KSt:            Explosion coefficient.
      LC50:           Lethal concentration, for 50 percent of test population.
      LD50:           Lethal dose, for 50 percent of test population.
      LTE:            Long-term exposure.
      PNEC:           Predicted No Effect Concentration.
      RID:            Regulation Concerning the International Transport of Dangerous Goods
                      by Rail.
      STE:            Short-term exposure.
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      STEL:      Short Term Exposure limit.
      STOT:      Specific Target Organ Toxicity.
      TLV:       Threshold Limiting Value.
      TWATLV:    Threshold Limit Value for the Time Weighted Average 8 hour day.
                 (ACGIH Standard).
      WGK:       German Water Hazard Class.




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Safety Data Sheet
WC NET EXTRA WHITE - OCEAN FRESH - Blue Solid Rim Block with
bleach
2F0023/2


Safety Data Sheet dated 12/12/2011, version 2

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
      1.1. Product Identifier
             Mixture identification:
             Trade name:                        WC NET EXTRA WHITE - OCEAN FRESH - Blue Solid Rim
                                                Block with bleach
            Product code:                       2F0023
            Product type and use:               Toilet bowl solid rim block
      1.2. Relevant identified uses of the substance/mixture and uses advised against
            Recommended use:
            See label: instructions and precautions
            Uses advised against:
            See label: instructions and precautions.
      1.3. Details of the supplier of the safety data sheet
            Company:
            BOLTON MANITOBA SPA
            Via Pirelli, 19
            20124 Milano - Italy
            Tel. +39 02 6709 333 - Fax +39 0362 378 228
            Distributor:
            Alf.Mizzi & Sons (Mktg) Group
            Zachary House
            Marsa Industrial Estate -
            MARSA LQA 06 -MALTA - tel. 00356 2554 0000

            +39 02 67 09 333
      Competent person responsible for the safety data sheet:
            safetyinfo@boltonmanitoba.it
      1.4. Emergency telephone number
            00356 2554 0000
            030 274 8888

2. HAZARDS IDENTIFICATION
      2.1. Classification of the substance or mixture
      Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
      Properties / Symbols:
               Xi Irritant
               N Dangerous for the environment
      R Phrases:
             R38 Irritating to skin.
             R41 Risk of serious damage to eyes.
             R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
             environment.

      Adverse physicochemical, human health and environmental effects:
           No other hazards

      2.2. Label elements



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      Symbols:
               Xi Irritant
               N Dangerous for the environment
      R Phrases:
            R38 Irritating to skin.
            R41 Risk of serious damage to eyes.
            R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
            environment.
      S Phrases:
            S2 Keep out of reach of children.
            S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
            advice.
            S37/39 Wear suitable gloves and eye/face protection.
            S46 If swallowed, seek medical advice immediately and show this container or label.
      Special Provisions:
            Warning! Do not use together with other products. May release dangerous gases (chlorine).

      2.3. Other hazards
            vPvB Substances: None - PBT Substances: None
      Other Hazards:
            No other hazards

      Regulation (EC) nr 648/2004 (Detergents).
      Contains:
      > 30 %            anionic surfactants

3. COMPOSITION/INFORMATION ON INGREDIENTS
      3.1. Substances
            N.A.
      3.2. Mixtures
            Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and
            related classification:
      50% - 75% Reaction product of Benzenesulfonic acid, 4-C10-C13-sec-alkyl derivs. and
      Benzenesulfonic acid, 4-methyl- and sodium hydroxide
            REACH No.: 01-2119565112-48, EC: 932-051-8
            Xi; R41-38
               3.2/2 Skin Irrit. 2 H315
               3.3/1 Eye Dam. 1 H318

      10% - 20% troclosene sodium, dihydrate
            Index number: 613-030-01-7, CAS: 51580-86-0, EC: 220-767-7
            Xn,Xi,N; R22-31-36/37-50/53
               3.3/2 Eye Irrit. 2 H319
               3.8/3 STOT SE 3 H335
               4.1/A1 Aquatic Acute 1 H400
               4.1/C1 Aquatic Chronic 1 H410
               3.1/4/Oral Acute Tox. 4 H302



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4. FIRST AID MEASURES
      4.1. Description of first aid measures
      In case of skin contact:
             Immediately take off all contaminated clothing.
             Areas of the body that have - or are only even suspected of having - come into contact with the
             product must be rinsed immediately with plenty of running water and possibly with soap.
             Wash thoroughly the body (shower or bath).
             Remove contaminated clothing immediatley and dispose off safely.
             After contact with skin, wash immediately with soap and plenty of water.
      In case of eyes contact:
             After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time,
             then consult an opthalmologist immediately.
             Protect uninjured eye.
      In case of Ingestion:
             Do not under any circumstances induce vomiting. OBTAIN A MEDICAL EXAMINATION
             IMMEDIATELY.
      In case of Inhalation:
             Remove casualty to fresh air and keep warm and at rest.
      4.2. Most important symptoms and effects, both acute and delayed
             None
      4.3. Indication of any immediate medical attention and special treatment needed
             In case of accident or unwellness, seek medical advice immediately (show directions for use or
             safety data sheet if possible).
             Treatment:
             None

5. FIRE-FIGHTING MEASURES
      5.1. Extinguishing media
            Suitable extinguishing media:
            Water.
            Carbon dioxide (CO2).
            Extinguishing media which must not be used for safety reasons:
            None in particular.
      5.2. Special hazards arising from the substance or mixture
            Do not inhale explosion and combustion gases.
            Burning produces heavy smoke.
      5.3. Advice for fire-fighters
            Use suitable breathing apparatus .
            Collect contaminated fire extinguishing water separately. This must not be discharged into
            drains.
            Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES
      6.1. Personal precautions, protective equipment and emergency procedures
            Wear personal protection equipment.
            Remove persons to safety.
            See protective measures under point 7 and 8.
      6.2. Environmental precautions
            Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
            Retain contaminated washing water and dispose it.
            In case of gas escape or of entry into waterways, soil or drains, inform the responsible
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            authorities.
            Suitable material for taking up: absorbing material, organic, sand
      6.3. Methods and material for containment and cleaning up
            Wash with plenty of water.
      6.4. Reference to other sections
            See also section 8 and 13

7. HANDLING AND STORAGE
      7.1. Precautions for safe handling
             Avoid contact with skin and eyes, inhaltion of vapours and mists.
             Don't use empty container before they have been cleaned.
             Before making transfer operations, assure that there aren't any incompatible material residuals
             in the containers.
             Contamined clothing should be changed before entering eating areas.
             Do not eat or drink while working.
             See also section 8 for recomened protective equipment.
      7.2. Conditions for safe storage, including any incompatibilities
             Keep away from food, drink and feed.
             Incompatible materials:
             None in particular.
             Instructions as regards storage premises:
             Adequately ventilated premises.
      7.3. Specific end use(s)
             None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
      8.1. Control parameters
            None.
      DNEL Exposure Limit Values
            N.A.
      PNEC Exposure Limit Values
            N.A.
      8.2. Exposure controls
      Eye protection:
            Use close fitting safety goggles, don't use eye lens.
      Protection for skin:
            Use clothing that provides comprehensive protection to the skin, e.g. cotton, rubber, PVC or
            viton.
      Protection for hands:
            Suitable gloves type:
            Butyl caoutchouc (butyl rubber).
            NR (natural rubber, natural latex).

      Respiratory protection:
            Not needed for normal use.
      Thermal Hazards:
            None
      Environmental exposure controls:
            None

9. PHYSICAL AND CHEMICAL PROPERTIES
      9.1. Information on basic physical and chemical properties
             Appearance and colour:          Pasty solid
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            Odour:                              Characteristic of chlorine
            Odour threshold:                    N.D.
            pH:                                 9 (10g/l)
            Melting point / freezing point:     Not Relevant
            Initial boiling point and boiling range:       Not Relevant
            Solid/gas flammability:             Not Relevant
            Upper/lower flammability or explosive limits:           N.A.
            Vapour density:                     N.A.
            Flash point:                        Not Relevant
            Evaporation rate:                   N.A.
            Vapour pressure:                    n.d. bar / 20°C
            Relative density:                   N.A.
            Solubility in water:                Partial
            Lipid solubility:                   Insoluble
            Partition coefficient (n-octanol/water):       N.A.
            Auto-ignition temperature:          N.A.
            Decomposition temperature:          N.A.
            Viscosity:                          Not Relevant
            Explosive properties:               N.A.
            Oxidizing properties:               N.A.
      9.2. Other information
            Miscibility:                        N.A.
            Fat Solubility:                     N.A.
            Conductivity:                       N.A.
            Substance Groups relevant properties           N.A.

10. STABILITY AND REACTIVITY
      10.1. Reactivity
             Stable under normal conditions
      10.2. Chemical stability
             Stable under normal conditions
      10.3. Possibility of hazardous reactions
             None
      10.4. Conditions to avoid
             Stable under normal conditions.
      10.5. Incompatible materials
             None in particular.
      10.6. Hazardous decomposition products
             None.

11. TOXICOLOGICAL INFORMATION
     11.1. Information on toxicological effects
     Toxicological information of the mixture:
             N.A.
     Toxicological information of the main substances found in the mixture:
             N.A.
     If not differently specified, the information required in Regulation 453/2010/EC listed below must be
     considered as N.A.:
             a) acute toxicity;
             b) skin corrosion/irritation;
             c) serious eye damage/irritation;
             d) respiratory or skin sensitisation;
             e) germ cell mutagenicity;
             f) carcinogenicity;
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            g) reproductive toxicity;
            h) STOT-single exposure;
            i) STOT-repeated exposure;
            j) aspiration hazard.

12. ECOLOGICAL INFORMATION
      12.1. Toxicity
             Adopt good working practices, so that the product is not released into the environment.
             Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
      12.2. Persistence and degradability
             None
             N.A.
      12.3. Bioaccumulative potential
             N.A.
      12.4. Mobility in soil
             N.A.
      12.5. Results of PBT and vPvB assessment
             vPvB Substances: None - PBT Substances: None
      12.6. Other adverse effects
             None

13. DISPOSAL CONSIDERATIONS
      13.1. Waste treatment methods
            Recover if possible. In so doing, comply with the local and national regulations currently in force.

14. TRANSPORT INFORMATION




      14.1. UN number
            ADR-UN Number:                   3077
            IATA-UN Number:                  3077
            IMDG-UN Number:                  3077
      14.2. UN proper shipping name
            ADR-Shipping Name:               SOLID SUBSTANCE - HARMFUL FOR THE ENVIRONMENT,
                                             N.A.S. (troclosene sodium, dihydrate
            IATA-Shipping Name:              SOLID SUBSTANCE - HARMFUL FOR THE ENVIRONMENT,
                                             N.A.S. (troclosene sodium, dihydrate
            IMDG-Shipping Name:              SOLID SUBSTANCE - HARMFUL FOR THE ENVIRONMENT,
                                             N.A.S. (troclosene sodium, dihydrate
      14.3. Transport hazard class(es)
             ADR-Class:                     9
             ADR - Hazard identification number:     90
             IATA-Class:                    9
             IATA-Label:                    Miscellaneous
             IMDG-Class:                    9
             IMDG-Class:                    9
      14.4. Packing Group
             ADR-Packing Group:             III
             IATA-Packing group:            III

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             IMDG-Packing group:             III
      14.5 Environmental hazards
             ADR-Enviromental Pollutant:     Yes
             IMDG-Marine pollutant:          Marine Pollutant
      14.6. Special Precautions for User
             IMDG-EmS:                       F-A , S-F
             IMDG-Storage category:          A
      14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
             N.A.

15. REGULATORY INFORMATION
      15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
      Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances). Dir. 99/45/EEC
      (Classification, packaging and labelling of dangerous preparations). Dir. 98/24/EC (Risks related to
      chemical agents at work). Dir. 2000/39/EC (Occupational exposure limit values); Dir. 2006/8/CE.
      Regulation (CE) n. 1907/2006 (REACH), Regulation (CE) n. 1272/2008 (CLP), Regulation (CE) n.
      790/2009 (1° ATP CLP), Regulation (EU) n. 453/2010 (Annex I).
      Where applicable, refer to the following regulatory provisions :
             Directive 82/501/EEC ('Activities linked to risks of serious accidents') and subsequent
             amendments.
             Regulation (EC) nr 648/2004 (detergents).
             1999/13/EC (VOC directive)
             Surfactants contained in this mixture comply biodegradability requirements prescribed by
             Detergent Regulation 648/2004/CE.


      15.2. Chemical Safety Assessment
            No



16. OTHER INFORMATION
      Text of phrases referred to under heading 3:
            R22 Harmful if swallowed.
            R31 Contact with acids liberates toxic gas.
            R36/37 Irritating to eyes and respiratory system.
            R38 Irritating to skin.
            R41 Risk of serious damage to eyes.
            R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
            environment.

            H315 Causes skin irritation.
            H318 Causes serious eye damage.
            H319 Causes serious eye irritation.
            H335 May cause respiratory irritation.
            H400 Very toxic to aquatic life.
            H410 Very toxic to aquatic life with long lasting effects.
            H302 Harmful if swallowed.

      Paragraphs modified from the previous revision:

            1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
            COMPANY/UNDERTAKING
            8. EXPOSURE CONTROLS/PERSONAL PROTECTION
2F0023/2
Page n. 7 of 8
Safety Data Sheet
WC NET EXTRA WHITE - OCEAN FRESH - Blue Solid Rim Block with
bleach
2F0023/2
             9. PHYSICAL AND CHEMICAL PROPERTIES
             14. TRANSPORT INFORMATION
             15. REGULATORY INFORMATION

      This document was prepared by a competent person who has received appropriate training.
      Main bibliographic sources:
              ECDIN - Environmental Chemicals Data and Information Network - Joint Research Centre,
              Commission of the European Communities
              SAX's DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS - Eight Edition - Van
              Nostrand Reinold
              CCNL - Appendix 1
              Insert further consulted bibliography
      The information contained herein is based on our state of knowledge at the above-specified date. It
      refers solely to the product indicated and constitutes no guarantee of particular quality.
      It is the duty of the user to ensure that this information is appropriate and complete with respect to the
      specific use intended.
      This MSDS cancels and replaces any preceding release.

      ADR:            European Agreement concerning the International Carriage of
                      Dangerous Goods by Road.
      CAS:            Chemical Abstracts Service (division of the American Chemical Society).
      CLP:            Classification, Labeling, Packaging.
      DNEL:           Derived No Effect Level.
      EINECS:         European Inventory of Existing Commercial Chemical Substances.
      GefStoffVO:     Ordinance on Hazardous Substances, Germany.
      GHS:            Globally Harmonized System of Classification and Labeling of
                      Chemicals.
      IATA:           International Air Transport Association.
      IATA-DGR:       Dangerous Goods Regulation by the "International Air Transport
                      Association" (IATA).
      ICAO:           International Civil Aviation Organization.
      ICAO-TI:        Technical Instructions by the "International Civil Aviation Organization"
                      (ICAO).
      IMDG:           International Maritime Code for Dangerous Goods.
      INCI:           International Nomenclature of Cosmetic Ingredients.
      KSt:            Explosion coefficient.
      LC50:           Lethal concentration, for 50 percent of test population.
      LD50:           Lethal dose, for 50 percent of test population.
      LTE:            Long-term exposure.
      PNEC:           Predicted No Effect Concentration.
      RID:            Regulation Concerning the International Transport of Dangerous Goods
                      by Rail.
      STE:            Short-term exposure.
      STEL:           Short Term Exposure limit.
      STOT:           Specific Target Organ Toxicity.
      TLV:            Threshold Limiting Value.
      TWATLV:         Threshold Limit Value for the Time Weighted Average 8 hour day.
                      (ACGIH Standard).
      WGK:            German Water Hazard Class.




2F0023/2
Page n. 8 of 8
Safety Data Sheet
WC NET BLEACH GEL - Intense / Extra White - Mountain fresh (green)
2F0020/2



Safety Data Sheet dated 12/12/2011, version 2

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
      1.1. Product Identifier
             Mixture identification:
             Trade name:                        WC NET BLEACH GEL - Intense / Extra White - Mountain
                                                fresh (green)
            Product code:                       2F0020
            Product type and use:               Toilet cleaner
      1.2. Relevant identified uses of the substance/mixture and uses advised against
            Recommended use:
            See label: instructions and precautions
            Uses advised against:
            See label: instructions and precautions.
      1.3. Details of the supplier of the safety data sheet
            Company:
            BOLTON MANITOBA SPA
            Via Pirelli, 19
            20124 Milano - Italy
            Tel. +39 02 6709 333 - Fax +39 0362 378 228
            Distributor:
            Alf.Mizzi & Sons (Mktg) Group
            Zachary House
            Marsa Industrial Estate -
            MARSA LQA 06 -MALTA - tel. 00356 2554 0000

            +39 02 67 09 333
      Competent person responsible for the safety data sheet:
            safetyinfo@boltonmanitoba.it
      1.4. Emergency telephone number
            00356 2554 0000
            030 274 8888

2. HAZARDS IDENTIFICATION
      2.1. Classification of the substance or mixture
      Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
      Properties / Symbols:
               Xi Irritant
      R Phrases:
             R36/38 Irritating to eyes and skin.

      Adverse physicochemical, human health and environmental effects:
           No other hazards

      2.2. Label elements




      Symbols:
              Xi Irritant
2F0020/2
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Safety Data Sheet
WC NET BLEACH GEL - Intense / Extra White - Mountain fresh (green)
2F0020/2


      R Phrases:
            R36/38 Irritating to eyes and skin.
      S Phrases:
            S2 Keep out of reach of children.
            S24/25 Avoid contact with skin and eyes.
            S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
            advice.
            S46 If swallowed, seek medical advice immediately and show this container or label.
      Special Provisions:
            Warning! Do not use together with other products. May release dangerous gases (chlorine).

      2.3. Other hazards
            vPvB Substances: None - PBT Substances: None
      Other Hazards:
            No other hazards

      Regulation (EC) nr 648/2004 (Detergents).
      Contains:
Safety Data Sheet
WC NET BLEACH GEL - Intense / Extra White - Mountain fresh (green)
2F0020/2


             After contact with skin, wash immediately with soap and plenty of water.
      In case of eyes contact:
             After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time,
             then consult an opthalmologist immediately.
             Protect uninjured eye.
      In case of Ingestion:
             Do NOT induce vomiting.
      In case of Inhalation:
             Remove casualty to fresh air and keep warm and at rest.
      4.2. Most important symptoms and effects, both acute and delayed
             None
      4.3. Indication of any immediate medical attention and special treatment needed
             In case of accident or unwellness, seek medical advice immediately (show directions for use or
             safety data sheet if possible).
             Treatment:
             None

5. FIRE-FIGHTING MEASURES
      5.1. Extinguishing media
            Suitable extinguishing media:
            Water.
            Carbon dioxide (CO2).
            Extinguishing media which must not be used for safety reasons:
            None in particular.
      5.2. Special hazards arising from the substance or mixture
            Do not inhale explosion and combustion gases.
            Burning produces heavy smoke.
      5.3. Advice for fire-fighters
            Use suitable breathing apparatus .
            Collect contaminated fire extinguishing water separately. This must not be discharged into
            drains.
            Move undamaged containers from immediate hazard area if it can be done safely.

6. ACCIDENTAL RELEASE MEASURES
      6.1. Personal precautions, protective equipment and emergency procedures
            Wear personal protection equipment.
            Remove persons to safety.
            See protective measures under point 7 and 8.
      6.2. Environmental precautions
            Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
            Retain contaminated washing water and dispose it.
            In case of gas escape or of entry into waterways, soil or drains, inform the responsible
            authorities.
            Suitable material for taking up: absorbing material, organic, sand
      6.3. Methods and material for containment and cleaning up
            Wash with plenty of water.
      6.4. Reference to other sections
            See also section 8 and 13

7. HANDLING AND STORAGE
      7.1. Precautions for safe handling
             Avoid contact with skin and eyes, inhaltion of vapours and mists.
             Don't use empty container before they have been cleaned.
2F0020/2
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Safety Data Sheet
WC NET BLEACH GEL - Intense / Extra White - Mountain fresh (green)
2F0020/2


            Before making transfer operations, assure that there aren't any incompatible material residuals
            in the containers.
            Contamined clothing should be changed before entering eating areas.
            Do not eat or drink while working.
            See also section 8 for recomened protective equipment.
      7.2. Conditions for safe storage, including any incompatibilities
            Keep away from food, drink and feed.
            Incompatible materials:
            None in particular.
            Instructions as regards storage premises:
            Adequately ventilated premises.
      7.3. Specific end use(s)
            None in particular

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
      8.1. Control parameters
            sodium hydroxide; caustic soda - CAS: 1310-73-2
                   TLV STEL: C 1,22 ppm - C 2 mg/m3
      DNEL Exposure Limit Values
            N.A.
      PNEC Exposure Limit Values
            N.A.
      8.2. Exposure controls
      Eye protection:
            Use close fitting safety goggles, don't use eye lens.
      Protection for skin:
            No special precaution must be adopted for normal use.
      Protection for hands:
            Use protective gloves that provides comprehensive protection, e.g. P.V.C., neoprene or rubber.
      Respiratory protection:
            Not needed for normal use.
      Thermal Hazards:
            None
      Environmental exposure controls:
            None

9. PHYSICAL AND CHEMICAL PROPERTIES
     9.1. Information on basic physical and chemical properties
            Appearance and colour:              Transparent liquid
            Odour:                              Characteristic of chlorine
            Odour threshold:                    N.D.
            pH:                                 13.0
            Melting point / freezing point:     Not Relevant
            Initial boiling point and boiling range:      Not Relevant
            Solid/gas flammability:             Not Relevant
            Upper/lower flammability or explosive limits:           Not Relevant
            Vapour density:                     N.A.
            Flash point:                        Not Relevant
            Evaporation rate:                   N.A.
            Vapour pressure:                    N.A.
            Relative density:                   1.08 kg/l
            Solubility in water:                Complete
            Lipid solubility:                   Insoluble
            Partition coefficient (n-octanol/water):      Not Relevant
2F0020/2
Page n. 4 of 8
Safety Data Sheet
WC NET BLEACH GEL - Intense / Extra White - Mountain fresh (green)
2F0020/2


            Auto-ignition temperature:    N.A.
            Decomposition temperature:    N.A.
            Viscosity:                    1000 cps
            Explosive properties:         N.A.
            Oxidizing properties:         N.A.
      9.2. Other information
            Miscibility:                  N.A.
            Fat Solubility:               N.A.
            Conductivity:                 N.A.
            Substance Groups relevant properties   Not Relevant

10. STABILITY AND REACTIVITY
      10.1. Reactivity
             Stable under normal conditions
      10.2. Chemical stability
             Stable under normal conditions
      10.3. Possibility of hazardous reactions
             None
      10.4. Conditions to avoid
             Stable under normal conditions.
      10.5. Incompatible materials
             None in particular.
      10.6. Hazardous decomposition products
             None.

11. TOXICOLOGICAL INFORMATION
      11.1. Information on toxicological effects
      Toxicological information of the mixture:
              N.A.
      Toxicological information of the main substances found in the mixture:
              N.A.
      If not differently specified, the information required in Regulation 453/2010/EC listed below must be
      considered as N.A.:
              a) acute toxicity;
              b) skin corrosion/irritation;
              c) serious eye damage/irritation;
              d) respiratory or skin sensitisation;
              e) germ cell mutagenicity;
              f) carcinogenicity;
              g) reproductive toxicity;
              h) STOT-single exposure;
              i) STOT-repeated exposure;
              j) aspiration hazard.

12. ECOLOGICAL INFORMATION
      12.1. Toxicity
             Adopt good working practices, so that the product is not released into the environment.
             Studio C.lab 84/2008
             WC NET BLEACH GEL - Intense / Extra White - Mountain fresh (green)
                    Test: EC50 - Species: Daphnia - Duration h: 48 - mg/l: 1.97
             sodium hypochlorite, solution - CAS: 7681-52-9
                    Test: LC50 - Species: Fish - Duration h: 96 - mg/l: 0.011-0.1
                    Test: EC50 - Species: Daphnia - Duration h: 48 - mg/l: 0.011-0.1
2F0020/2
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