Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University

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Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
Electrical Generation of Spin Currents

                                                      Andrew D. Kent
                                              Center for Quantum Phenomena
                                                  Department of Physics
                                                   New York University

Funding:
                 Energy Frontiers Research Center

         Quantum-Materials for Energy Efficient Neuromorphic-Computing

SPICE-SPIN+X Seminar: June 16th, 2021                                        1
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
Electrical Generation of Spin Currents

    Chris Safranski, IBM Jonathan Sun, IBM      Jun-Wen Xu, NYU   Haowen Ren, NYU        Laura Rehm, NYU

  C. Safranski et al., PRL 124, 197204 (2020)                            L. Rehm et al., APL 115, 182404 (2019)
                                                                         L. Rehm et al., PR Appl. 15, 034088 (2021)

SPICE-SPIN+X Seminar: June 16th, 2021                                                                                 2
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
Electrical Generation of Spin Currents

    Outline

      • Introduction: Spin torques and spin-orbit torques
      • Charge-to-spin conversion efficiency in switching perpendicular magnetic
        tunnel junction nanopillars
      • Planar Hall effect spin torques

SPICE-SPIN+X Seminar: June 16th, 2021                                              3
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
Electrical Generation of Spin Currents

    Outline

      • Introduction: Spin torques and spin-orbit torques
      • Charge-to-spin conversion efficiency in switching perpendicular magnetic
        tunnel junction nanopillars
      • Planar Hall effect spin torques

SPICE-SPIN+X Seminar: June 16th, 2021                                              4
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
NYU         Physics Prize
                      Prediction
                 2013 Oliver     of Spin-Transfer
                             E. Buckley  CondensedTorques
                                                      Matter Physics Priz
                 2013 Oliver E. Buckley Prize
                 2013 Oliver E. Buckley Condensed Matter Physics Priz
                 John Slonczewski
 s               Citation:
                  Luc Berger
                 "For predicting spin-transfer torque and opening the field of current-
ws                Carnegie
                 induced       Mellon    University
                 Citation: control over magnetic nanostructures."
ureships         “For  predicting
                 Citation:        spin-transfer torque and opening the
                 field of current-induced control over magnetic
                 Background:
                 nanostructures.”
                   "For predicting spin-transfer torque and opening the field of current-induced contro
ureships          John      Slonczewski        received
                   over magnetic nanostructures."
                   Foundational       papers:                 the  Physics   BS at Worcester   Polytechnic
                  Institute     in 1950
                   J. C. Slonczewski,  Phys. and
                                             Rev. B.the   Physics
                                                     39, 6996 (1989) PhD at Rutgers University in 1955. He
                   J. C. Slonczewski, J. Magn. Magn. Mater. 159, L1 (1996)
                  pursued
                   Background:
                   L.            solid-state
                      Berger, Phys.              theory
                                    Rev. B 54, 9353  (1996) as Research Staff Member in IBM from 1955
s,
                  until   retiring    in  2002.    He    was    located   at Yorktown Heights,  NY  USA,
hips
                  except
                   Luc Berger for sabbaticals
                                     1933-May-02      in 1965-6,
                                                           Emeritus  1970-1,  andof
                                                                       professor   1987 at Rueschlikon,
                                                                                     Physics  Carnegie Mellon Universit
s,                Switzerland.
                   5000 Forbes Avenue Pittsburgh, PA 15213 B.Sc., Mathematical Sciences, U. of
hips              His
 SPICE-SPIN+X Seminar
                         research
                   Lausanne,            in
                                    1955.  solids
                                              Ph.D., included
                                                         Physics, fundamental
                                                                     U.  of      theories
                                                                            Lausanne,     of
                                                                                       1960. graphite bands,
                                                                                              Postdoctoral research 5
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
NYU

                             Prediction of Spin-Transfer Torques
                                                                                                           The spin-up electrons are those with spin orientati
                                                                                                           electrons have anti-parallel alignment with the exte
                                                                                                           polarizations of the two ferromagnets, P1 and P2:

                                                                                                           If no voltage is applied to the junction, electrons tunn
                                                                                                           tunnel preferentially to the positive electrode. With
                                                                                                           can be described in a two-current model. The total cur
                                                                                                           another for the spin-down electrons. These vary depen
                                                                                                                          J. C, Applications:
                                                                                                                                SLONCZE~S~    New types of MRAM
              In magnetic tunnel junctions                                                                 There are two possibilities to obtain a defined anti-pa
                                                                                                                                  1.2
                                                                                                                                                                                                  —ik
                                                                                                           (by using different materials or different film thickne
                                                                                                                                                              &p

                                                                                                                                                    0.8
                                                                                                           antiferromagnet (exchange
                                                                                                                              ~      bias). In this case the mag
                                                                                                                                            ~

                                                                                                                                                    0.4
                                                                                                                                                O
                                                                                                              :// .        d a.       /   /T         0_   a           a c
                                                                                                                                                Q
                   h                                                                                                                            N
                                                                                                                                                    04

                                                                     Fg~    ~   -   Schelne of      ector dy a~&cs due to the trans
                                                                                      1ss j at&v e exchange co
                                                                                                             oupljng inducced by
                                                                                                                              b an                             0.2          0.4            0.6              0.8
                                                                                                       .                                                                          bafgQt    I    2/k    2
                                                                   e&ternal voltagge across the baarriver.

                                                                                                                                            FICx.. 7. Dissipativ
                                                                                                                                                           p 1v         h     ge       coup ling D e              (sn

                  In magnetic metallic multilayers                 (F~g   6)
                                                                                    Applications: Magnetic Random
                                                                                     g oPt~cal parlance
                                                                   wh      p~~fers t
                                                                                                 mor»
                                                                                    Access Memory, STT-MRAM barrier
                                                                                             is losing
                                                                                                                            direct~on
                                                                                                                            polarized
                        J. C. Sloncewski, JMMM 159, L1-L7 (1996)   electrons and S             rift away fr       sS     shown.
                                                                                                                                                         er ace greatly in'
                                                                                                                                                      interface
                                                                                                                                                    tht o dt'1     t 'ldt           n includi
                                                                                          at actually th e spin cu«ennt through
                        L. Berger, PRB 54, 9353 (1996)                             .   Nature
                                                                   the junct' n (includin   g bothNanotechnology,               March
                                                                                                      longit u d inal and transverse      2015      , sur ace statess a nd the like                                r

                                                                                       Spin-transfer-torque              memory
SPICE-SPIN+X Seminar
                                                                    erms) is giv
                                                                              1ven simply

                                                                          Ils(W
                                                                                            by
                                                                                       = V —VA )(S„+Sa)
                                                                                     a)=D(                                    (5.7)
                                                                                                                                            The polarizat'
                                                                                                                                                       za ion coefficien
                                                                                                                                          (3.5 ) for the two-ba                    ,   ---"             hec6
                                                                                                                                                                                                            , g
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
NYU

                            Basic Physics of Spin Transfer
                          Based on conservation of angular momentum

                                                                            ~int        ~f
                                                                                        S        ~i
                                                                                                 S
                                                                           dS
                                                                                 ! ~⌧
                                                            θ      θ        dt               ~
                                                                                             S
                                                                             ~int
                                                                            dS     ~
                                                                                  = IP sin ✓
                                                        €                    dt    2e

                                          1 dM~    ~int
                                                  dS
                                                +       =0
                                             dt    dt
                                        magnetization   itinerant charge

          ‣Reference layer ‘sets’ spin-polarization of current
          ‣Enables readout of magnetization state through the tunnel magnetoresistance (TMR),
            giant magnetoresistance (GMR), or anisotropic magnetoresistance (AMR) effects

SPICE-SPIN+X Seminar                                                                                  7
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
NYU

                         Charge Current to Spin Current Conversion

Ferromagnetic layers to                                     Spin-orbit torques
  polarize the current

 Spin-polarization direction set by                              Spin-polarization direction set by layer geometry
 reference layer magnetization                                   and current flow direction
 direction

  Spin torque foundational theory papers:
                                                                    Heavy metals/Ferromagnet bilayers
  J. C. Slonczewski, Phys. Rev. B. 39, 6996 (1989)
                                                                    M. Miron et al., Nature Materials 2010
  J. C. Slonczewski, J. Magn. Magn. Mater. 159, L1 (1996)
                                                                    L. Liu et al., Science 2012
  L. Berger, Phys. Rev. B 54, 9353 (1996)
                                                            Review article: J. Sinova et al., Spin Hall Effects, RMP 87, 1213 (2015)
SPICE-SPIN+X Seminar                                                                                                                  8
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
NYU

                         Charge Current to Spin Current Conversion

Ferromagnetic layers to                                                     Spin-orbit torques
  polarize the current                                          z                                               ℓ
                                                                    y
                                                                        x
                                                                                                                                                 t
                                                  FL

                                                  RL
 spin-current
   density
charge current
                  Js /Jc ≃ P                                                                        Js /Jc = θSH
    density
                   Is /Ic ≃ P                                                             Is /Ic ≃ θSH(ℓ/t)
spin current is                                                                          −ℏ
 ℏJs /(2e)                      Q ∼ m̂ RL ⊗ z ̂                                       Q=      ξσSHE(z ̂ × E) ⊗ z ̂
                                                                                         2e
                                Polarization ⊗ Flow direction                                           Polarization ⊗ Flow direction
  Spin torque foundational theory papers:
                                                                                    Heavy metals/Ferromagnet bilayers
  J. C. Slonczewski, Phys. Rev. B. 39, 6996 (1989)
                                                                                    M. Miron et al., Nature Materials 2010
  J. C. Slonczewski, J. Magn. Magn. Mater. 159, L1 (1996)
                                                                                    L. Liu et al., Science 2012
  L. Berger, Phys. Rev. B 54, 9353 (1996)
                                                                            Review article: J. Sinova et al., Spin Hall Effects, RMP 87, 1213 (2015)
SPICE-SPIN+X Seminar                                                                                                                                  9
Electrical Generation of Spin Currents - Andrew D. Kent Center for Quantum Phenomena Department of Physics New York University
Electrical Generation of Spin Currents

    Outline

      • Introduction: Spin torques and spin-orbit torques
      • Charge-to-spin conversion efficiency in switching perpendicular
        magnetic tunnel junction nanopillars
      • Planar Hall effect spin torques

SPICE-SPIN+X Seminar                                                      10
NYU
                                                                                                                                                                                                                                                                              memories
                                                                                                                                                                                                                                                                      LETTERS
                                                                                                                                                                                                                                                                              Andrew D. Kent and Daniel C. Worledge
                                                                                                                                                                                                                                                Solid-state memory devices with all-electrical read and write operation
                                                                                                                                                                                                                                                information storage.
                                                                                                                                                                                                      PUBLISHED ONLINE: 11 JULY 2010 | DOI: 10.1038/NMAT2804

                                                                                                                                                                                                                                                                              S
                                                                                                                                                                                                                                                                 pin-transfer-torque magnetic random                        Spin-transfer torque provides a
                                                                                                                                                                                                                                                                 access memory (STT-MRAM) devices                      mechanism to write information. On
                                                                                                                                                                                                                                                                 store information in the orientation                  the other hand, information can be read
                                                                                                                                                                                                                                                           of the magnetization of nanometre-scale                     by measuring the device resistance. The

                                                                  A perpendicular-anisotropy CoFeB–MgO                                Applied Physics Letters                                                                                              ferromagneticARTICLE
                                                                                                                                                                                                                                                                              elements. As such, they are
                                                                                                                                                                                                                                                           like hard disk drives, which use magnetic
                                                                                                                                                                                                                                                           states to store information. In contrast to
                                                                                                                                                                                                                                                           hard disk drives, however, STT-MRAM is
                                                                                                                                                                                                                                                                                                               scitation.org/journal/apl
                                                                                                                                                                                                                                                                                                                       magnetoresistance refers to the percentage
                                                                                                                                                                                                                                                                                                                       change in resistance between parallel and
                                                                                                                                                                                                                                                                                                                       antiparallel magnetization alignment of the
                                                                                                                                                                                                                                                                                                                       electrodes in a magnetic tunnel junction,

                                                                  magnetic tunnel junction
                                                                                                                                                                                                                                                           written and read electrically, and does not                 which is made of a ferromagnetic metal/
                                                                                                                                                                                                                                                           have moving parts. This is a key difference                 insulator/ferromagnetic metal stack5. Until
                                                                                                                                                                                                                                                           that enables the integration of magnetic                    2004, the maximum magnetoresistance
                                                                                                                                                                                                                                                           devices with semiconductor chips. Such                      reported6–8 at room temperature was 70%.
                                                                                                                                                                                                                                            TABLE I. TMR        andmight
                                                                                                                                                                                                                                                           devices    fit parameters
                                                                                                                                                                                                                                                                              fulfil the speed from    the pulsed switching
                                                                                                                                                                                                                                                                                                  requirements                         measurements
                                                                                                                                                                                                                                                                                                                       Magnetoresistance           greater thanfor    vari-
                                                                                                                                                                                                                                                                                                                                                                   100%   had,
                                                                                                                                                                                                                                            ous temperatures       and theworking
                                                                                                                                                                                                                                                           of a computer’s       corresponding
                                                                                                                                                                                                                                                                                           memory while optimal write      energies.
                                                                                                                                                                                                                                                                                                                       however,     been predicted in crystalline
                                                                  S. Ikeda *, K. Miura , H. Yamamoto , K. Mizunuma , H. D. Gan , M. Endo , S. Kanai ,
                                                                    1,2                         1,2,3                                      1,2,3                                       2                         1                     2                     2 the inherent advantages of using
                                                                                                                                                                                                                                                           having
                                                                                                                                                                                                                                                           magnetic states — that no energy is needed
                                                                                                                                                                                                                                                                                                                       Fe/MgO/Fe tunnel junctions9 and was then
                                                                                                                                                                                                                                                                                                                       observed experimentally 10,11. Subsequent

                             LETTERS                                       3
                                                                              news & views                *
                                                                  J. Hayakawa , F. Matsukura and H. OhnoNATURE MATERIALS
                                                                                                                 1,2                                 1,2                                               DOI: 10.1038/NMAT2804
                                                                                                                                                                                                                                            T TMRadvances
                                                                                                                                                                                                                                                                      V   c  (mV)
                                                                                                                                                                                                                                                           to retain information.
                                                                                                                                                                                                                                                               STT-MRAM is the result of important
                                                                                                                                                                                                                                                                      in physics and materials science
                                                                                                                                                                                                                                                                                                               s 0 (ns)rapid advances in the growth   E   (fJ)  of thin-film
                                                                                                                                                                                                                                                                                                                       materials have led to junctions with large
                                                                                                                                                                                                                                                                                                                       magnetoresistance of several hundred per
                                                                                                                                                                                                                                            (K) (%) made      APover !P the pastP!         APTheAP
                                                                                                                                                                                                                                                                                     20 years.        first!key P P cent,      AP AP
                                                                                                                                                                                                                                                                                                                        ! through          the use!ofPtransition
                                                                                                                                                                                                                                                                                                                                                             P ! metalAP
                                                                                                                                                                                                                                                           finding was the theoretical prediction of                   electrodes (typically CoFeB).
                             a     Magnetic tunnel junctions (MTJs) with ferromagnetic replaced by the demagnetization energy E
                                                                                  a                                          a
                                                                                                                             b                                                                                                       , resulting in large E,
                                                                                                                                                                                                     of the interface are needed to correlatedemag         spin-transfer torque between conduction
                                                        V¬                                                                                   tCoFeB = 2.0 nm                                                Applications: New types of MRAM 4
                                                                                                                                                                                                     structure and properties in these materials.
                                                                                                                                                                                                                                                     200          399and magnetization:
                                                                                                                                                                                                                                                           electrons                 421 spin-polarized 0.94            1.03                   103               286
                                   electrodes possessing a perpendicular magnetic easy axis which is the reason why perpendicular anisotropy is required for the
                                                                                                                                        1                                                                 Another question is related to the75 fact 193 electrical393 currents can   416 transfer spin0.94angular       1.05             Bit line
                                                                                                                                                                                                                                                                                                                                                98               283
                                   are of great interest as they have a potential for realizing reduction of switching current. This equation shows that low ↵ is                                    that CoFeB films show low damping.
                                                                                                                                                                                                                                                           momentum to the magnetic moments of a
                                                     Cr/Au                                                                                                                                                                                  150 182 ferromagnet,  381 thus reorienting
                                                                                                                                                                                                                                                                                     403 them0.96        1–3
                                                                                                                                                                                                                                                                                                            . In        1.10                    94               287

                                                                                                                                                  M (T)
                                   next-generation high-density non-volatile memory and logic needed for low switching current for a given E. However, commonly
                                                                                              m         Free layer                     0                                                             However,     in the  devices fabricated               a ferromagnet, the majority and minority
                                                                                                                                               +m
                                   chips with high thermal stability and low critical current for known perpendicular-anisotropy materials and structures use                 –m                     by Ohno     and colleagues, which have
                                                                                                                                                                                                             In plane                       295 117 electron      225spin states are 305                1.48
                                                                                                                                                                                                                                                                                          shifted in energy.            1.38                    51               195
                                                   5 nm Ru                                                                                                                                           very thin CoFeB layers, the damping is                Thus, if the spin polarization of electrons
                                                                                                                            1–3                                                                                                                        18
                                   current-induced magnetization switching . To attain perpen- noble metals with high spin–orbit interaction , which increases ↵
                                                    5 nm Ta                                                                           ¬1                                                             stronglyOutenhanced,
                                                                                                                                                                                                                   of plane and the origin of this         incident on a ferromagnetic layer is not                                                                     Word line

                                                                                                                                                                                                     enhancement is not well understood. In                aligned with its magnetization (that is,
                                   dicular anisotropy, a number of material systems have been (refs 3,19–21). For example, the typical ↵ is larger than 0.1 for Co/Pt
                                                 tCoFeB CoFeB                                                                                                                                        acquiring a PMA, the damping apparently        The    devices
                                                                                                                                                                                                                                                           the electronare is notfirst     characterized
                                                                                                                                                                                                                                                                                   in a definite   majority         by measuring their field and
                                   explored as electrodes, which include rare-earth/transition- (ref. 19). In addition, there is no established material system that
                                Al2O3                                                        mp         Hard layer                     ¬0.5                                0                             0.5 comparable to other
                                                                                                                                                                                                     becomes                          1.0thin-film
                                                                                                                                                                                                                                            current pulse  or minority spin-state), the electron spin
                                                                                                                                                                                                                                                                  resistance hysteresis loops. Figure 1(b) shows the free
                                                                                                                                                                                                                                                           precesses rapidly around a momentum-
                                                  tMgO MgO             4,5   V+                                                      3,6,7                        U                   µ 0H (T)       materials with PMA , which typically
                                   metal alloys , L1 -ordered (Co, Fe)–Pt alloys
                                                                               0                                      and Co/(Pd, provides high tunnel magnetoresistance (TMR) ratio apart from the                          7
                                                                                                                                                                                                                                            layer hysteresis
                                                                                                                                                                                                                                                           dependentloop       (i.e.,field
                                                                                                                                                                                                                                                                         internal       a ofhysteresis
                                                                                                                                                                                                                                                                                              the ferromagnet. loop in which the applied field is
                                                                           1,8–10                                                                                                                    have   large  distributions  in their magnetic        Electron spins dephase because of the
                                   Pt) multilayers
                                                 tCoFeB CoFeB  . However, none of them so far satisfy well-known body-centred cubic (bcc) (001) CoFe(B)–MgO system.
                                                                                                                             b                                                                       properties that may lead to variations always
                                                                                                                                                                                                                                                 in lessdistribution
                                                                                                                                                                                                                                                             than theofcoercive               field associated
                                                                                                                                                                                                                                                                               electron momenta         of the SAF layers) of a 40 nm diame-
                                                                              Figure
                                                                                  b  1 | A perpendicularly    magnetized   magnetic  tunnel    t
                                                                                                                                             junction. =a,1.3 nm
                                                                                                                                                           Structure of a perpendicular   MTJ,
                                   high thermal stability at reduced dimension, low-current The crystal structures of perpendicular-anisotropy materials are
                                                    5 nm Ta                   consisting  of hard (fixed) and   free (switchable)       1
                                                                                                                                   magnetic
                                                                                                                                                 CoFeB
                                                                                                                                              layers separated   by a thin MgO   tunnel barrier.
                                                                                                                                                                                                          1 characteristics. Do such distributions
                                                                                                                                                                                                     device                                 ter  pMTJ     device      measured
                                                                                                                                                                                                                                                           with current     flow 4. As a in     antheapplied perpendicular
                                                                                                                                                                                                                                                                                           result,                                              field at 4 K. We
                                                                                                                                                                                                                                                                                                                                 Bit-line complement
                                                                                                                                                                                                     exist in CoFeB–MgO bilayers? To answer                component of spin-polarization transverse

                                                                                                                                                                                                              K. tCoFeB
                                                                                                                                                                                                             (mJ m–2)
                                   current-induced magnetization switching and high tunnel usually different from bcc, and on annealing the initially amorphous
                                                                              Arrows represent the direction of magnetizations of the hard (mp) and free (m) magnetic layers. b, The
                                                                                                                                                                                                     this question, further studies of filmsobserve
                                                                                                                                                                                                                                                 and sharp to the switching
                                                                                                                                                                                                                                                                   magnetization from            the P to AP state and vice versa with a
                                                                                                                                                                                                                                                                                       decays, transferring
                                                   10 nm Ru

                                                                                                                                                  M ( T)
                                                                              PMA of the free layer leads to a large energy barrier (U) to the magnetization switching between up and                    0
                                   magnetoresistance ratio all at the same time. Here, we CoFeB tends to crystallize in structures other than the wanted bcc
                                                                              down orientations.                                       0                                                                                                    field
                                                                                                                                                                                                     device arrays are necessary. In addition,      offset spin angular momentum to the ferromagnet. Figure 1 | STT-MRAM bit cell. A magnetic tunnel
                                                                                                                                                                                                                                                            of 56 mT,
                                                                                                                                                                                                                                                           In transition
                                                                                                                                                                                                                                                                                reflecting
                                                                                                                                                                                                                                                                            metal   ferromagnets,
                                                                                                                                                                                                                                                                                                   thethisfringe field        from the SAF acting on
                                                                                                                                                                                                                                                                                                                       junction is formed by a fixed reference layer
                                                    5 nm Ta                                                                                                                                          the switching speed and energy are critical
                                   use interfacial perpendicular anisotropy between the ferro- because they are deposited in direct contact with the perpendicular-                                  metrics   for  applications.  In
                                                                                                                                                                                                                                            the
                                                                                                                                                                                                                                      perpendicular
                                                                                                                                                                                                                                                   free   layer.   18
                                                                                                                                                                                                                                                                         This occurs
                                                                                                                                                                                                                                                           dephasing typically       sample   at theexhibits
                                                                                                                                                                                                                                                                                                      interface      a (purple),
                                                                                                                                                                                                                                                                                                                         tunnel          magnetoresistance
                                                                                                                                                                                                                                                                                                                                  a tunnel    barrier (grey) and a free-layer
                                                                                                                                                                                                       ¬1                                                  of the ferromagnet, on a length scale of                    element (red), with both layers magnetized
                                   magnetic electrodes and the tunnel barrier of the MTJ by anisotropy materials . In the following, we show that all three                                                0 10 junctions,
                                                  Si/SiO2 sub.                magnetization      states
                                                                                                   40
                                   employing the material combination of CoFeB–MgO, a system conditions
                                                                                                        at
                                                                                                       nm  Field induced
                                                                                                           room     temperature
                                                                              thin-film elements of less than only 10 nmFIG.  1.
                                                                                                                                   in
                                                                                                                                  (a)
                                                                                                                                      ¬1 of plane. A steady increase in the PMA
                                                                                                                                      Schematic        of  a   Current-induced
                                                                                                                                                              pMTJ    device    with  the  pulse  and
                                                                                                                                                                                                     spin-valve
                                                                                                                                                                                                         readout
                                                                                                                                                                                                                        1
                                                                                                                                                                                                                    measurement
                                                                                                                                                                                                                    tCoFeB
                                                                                                                                                                        for high-performance perpendicular MTJs can be met
                                                                                                                                          is seen with decreasing CoFeB thickness,                   switching with        (nm)
                                                                                                                                                                                                                        pulses
                                                                                                                                                                                                                                    2       (TMR)
                                                                                                                                                                                                                               magnetization-
                                                                                                                                                                                                                               as short as 0.3
                                                                                                                                                                                                                                            1(c)
                                                                                                                                                                                                                                                        ratio   of
                                                                                                                                                                                                                                                ns showsferromagnetic
                                                                                                                                                                                                                                                                     203%
                                                                                                                                                                                                                                                              voltage-induced
                                                                                                                                                                                                                                                                                  and      an
                                                                                                                                                                                                                                                                              layer responds
                                                                                                                                                                                                                                                                                                 average
                                                                                                                                                                                                                                                           several atomic layers. However, the entire
                                                                                                                                                                                                                                                                                                switching
                                                                                                                                                                                                                                                                                                                coercive
                                                                                                                                                                                                                                                                                                  to the torquesof arrows).
                                                                                                                                                                                                                                                                                                                       the same
                                                                                                                                                                                                                                                                                                                               field toofthe283
                                                                                                                                                                                                                                                                                                                       perpendicular
                                                                                                                                                                                                                                                                                                                                 The bit is 40
                                                                                                                                                                                                                                                                                                                                                  plane mT.      Figure
                                                                                                                                                                                                                                                                                                                                                        of the junction
                                                                                                                                                                                                                                                                                                                                                    nmby adiameter
                                                                                                                                                                                                                                                                                                                                               selected
                                                                                                                                                                                                                                                                                                                                                                        (black
                                                                                                                                                                                                                                                                                                                                                              word line and
                                                                                                                        circuit. Nanosecond
                                                                                                                                          clearly duration
                                                                                                                                                    indicatingwrite
                                                                                                                                                                 that pulses
                                                                                                                                                                       PMA is are     applied throughhas the
                                                                                                                                                                                                           beencapacitive   port of
                                   widely adopted to produce a giant tunnel magnetoresistance                    free layer with the CoFeB–MgO
                                                                              in diameter. Moreover, these magnetization
                                                                              states are expected to be readily altered a biasusing    ¬0.5
                                                                                                                                          effect.
                                                                                                                                 tee, while    theAnother
                                                                                                                                                     DC portimportant
                                                                                                                                                                is used for0
                                                                                                                                                                                 an interface
                                                                                                                                                                         switching
                                                                                                                                                                            result is that
                                                                                                                                                                               device      the
                                                                                                                                                                                         readout.        0.5
                                                                                                                                                                                                                 demonstrated,
                                                                                                                                                                                                   (b)of Resistance
                                                                                                                                                                                                         0.1 pJ in thermally
                                                                                                                                                                                                                                  with energies
                                                                                                                                                                                             standard material system that is widely used
                                                                                                                                                                                                                                      1.0   device
                                                                                                                                                                                                                               stable elements8.
                                                                                                                                                                                                                       vs perpen-                     in
                                                                                                                                                                                                                                                           because of the strong exchange coupling of
                                                                                                                                                                                                                                                          zero    field     with       100
                                                                                                                                                                                                                                                           moments throughout its thickness.  ms     duration
                                                                                                                                                                                                                                                                                                                       transistor, and operated by applying biases to the
                                                                                                                                                                                                                                                                                                                     voltage
                                                                                                                                                                                                                                                                                                                       bit lines. pulses. We observe a
                             Figure 1 | MTJ structure. a, Schematic of an MTJspin-transfer
                                   ratio in MTJs with in-plane anisotropy       device for torque
                                                                                               TMR 2,3and     . free
                                                                                                                 This
                                                                                                               CIMS
                                                                                                         , a new    mechanism11–13
                                                                                                                       layerapproach
                                                                                                                               hysteresis loop for of a in-plane-anisotropy
                                                                                                                                                               µ 0 diameter device at 4MTJs.
                                                                                                                                  for anisotropy of the interface is shown toHbe(T)                                      bistable region
                                                                                                                                                                                                     However, the ultimate switching speed of     around zero applied voltage and voltage-induced
           measurements. b, Top view of an MTJ no
                                   requires               magnetization
                                               pillarmaterial
                                                      taken by scanning
                                                                  other      switching
                                                                               electron
                                                                               than     that
                                                                                         those
                                                                                                 dicular field
                                                                                             makes
                                                                                                 ratiopossible
                                                                                                      used
                                                                                                        is      switching
                                                                                                                in
                                                                                                            203%.  sufficient
                                                                                                                    (c)         to
                                                                                                                     conventional  overcome
                                                                                                                         Voltage-induced       the strong
                                                                                                                                               switching
                                                                                                                                                           40 nm
                                                                                                                                                          Alltendency
                                                                                                                                                             withthelongstack  CoFeB–MgO
                                                                                                                                                                           duration structures
                                                                                                                                                                                       (100   ms)
                                                                                                                                                                                                 K. The TMR
                                                                                                                                                                                                  requires
                                                                                                                                                                                                        in
                                                                                                                                                                                                     pulses  further
                                                                                                                                                                                                              this
                                                                                                                                                                                                               of    study
                                                                                                                                                                                                                     study  and
                                                                                                                                                                                                                                 are
                                                                                                                                                                                                                         switching
                                                                                                                                                                                                                                         NATURE NANOTECHNOLOGY | VOL 10 | MARCH 2015 | www.nature.com/naturenanotechnology
                                                                                                                                                                                                                                        prepared
                                                                                                                                                                                                                                        with   pulse  on    ther-
                                                                                                                                                                                                                                                       amplitudes         of 405    mV      for    AP    ! R. P   switching
                                                                                                                                                                                                                                                                                                              Beach    et al., IEDM   and 2008
                                                          spin transfer torque MRAM (STT-MRAM).                    of CoFeB layers to be magnetized in plane as optimization. Devices with non-collinear                                                                                   © 2015 Macmillan Publishers Limited. All rights reserved
           microscope.             in-plane-anisotropy    This MTJs.         The perpendicular
                                                                has led to intense               the   Figure
                                                                                                      same
                                                                                     worldwide efforts to MTJs   2 |
                                                                                                               deviceIn-plane
                                                                                                                        at 4  K  in
                                                                                                                          consisting
                                                                                                                   a result         and
                                                                                                                                    zero out-of-plane
                                                                                                                                          applied
                                                                                                                              of magnetic shapemally field.   magnetization
                                                                                                                                                             The   junction
                                                                                                                                                    anisotropyoxidized
                                                                                                                                                                  (that              curves
                                                                                                                                                                              resistance        for
                                                                                                                                                                                              for  the
                                                                                                                                                                                   Si(001) substrate
                                                                                                                                                                               magnetizations           data   in
                                                                                                                                                                                                    can switch evenby       RF
                                                                                                                                                                                                                         $358
                                                                                                                                                                                                                       faster 9
                                                                                                                                                                                                                                , mVsputtering
                                                                                                                                                                                                                                          for P !atAProom     switching. Table I shows the TMR values
                                                          realize STT-MRAM show                  panels
                                                                                   with perpendicularly    (b) andresults
                                                                                                       CoFeB/MgO.    (c) isa,from
                                                                                                                              measured
                                                                                                                               tCoFeB      with
                                                                                                                                       = 2.0
                                                                                                                                    magnetic      a 30b,
                                                                                                                                                 nm.
                                                                                                                                               dipole      mV  DC=bias,
                                                                                                                                                           tCoFeB
                                                                                                                                                        interactions)       a without
                                                                                                                                                                       1.313nm.bias   much
                                                                                                                                                                                   Inset:      less dependence
                                                                                                                                                                                            tCoFeB
                                                                                                                                                                                          nanosecond  thanincubation
                                                                                                                                                                                                             the        delays  10
                                   of Ta/CoFeB/MgO/CoFeB/Ta                                  a   high      tunnel      magnetore-                  temperature              .  The      MTJ        structures        consist
                                                                                                                                                                                                                         extracted of, from
                                                                                                                                                                                                                                        from the the pulsed
                                                                                                                                                                                                                                                      substrate
                                                                                                                                                                                                                                                              voltage loops from 4 to 295 K. We observe
           (µ0 : permeability in free    space).  Theover magnetized
                                                        saturation       layers. The  focus
                                                                           magnetization     of  switching
                                                                                                the  efforts  voltage.
                                                                                                                   for  layer  thicknesses   of about    1 nm                  seen   in collinearly    magnetized    structures.
                                                          hasAlso,          D.C.       Worledge                 et(~3
                                                                                                                    atal.,
                                   sistance   ratio,          120%,          highmultilayers
                                                                                     thermal           of the product       ofApplied              Physics
                                                                                                                                 K and tCoFeB , where                    Letter
                                                                                                                                                              the intercept           the98,
                                                                                                                                                                                  to(10)/Ta vertical022501
                                                                                                                                                                                                        axis andFe(2011)
                                                              been   on complex                   of stability            dimension
                                                                                                                         monolayers    of CoFeB).side,        Ta     (5)/Ru    Nonetheless,         (5)/Co
                                                                                                                                                                                                 there  is great20        B20
                                                                                                                                                                                                                            for (tCoFeB
                                                                                                                                                                                                                       60almost
                                                                                                                                                                                                                  potential                : 1.0–1.3)/MgO
                                                                                                                                                                                                                                    a factor   of two increase in the TMR at 4 K compared to its value
           is 1.58 T. The perpendicular-anisotropy
                                   as low as 40 nm diameter  energy
                                                          magnetic         density
                                                                         and
                                                                      transition   lowKswitching
                                                                                 aelements    at as Co
                                                                                             such      the slope ofThe
                                                                                                             current     thework
                                                                                                                           of  linear
                                                                                                                                49     extrapolation
                                                                                                                                    goes
                                                                                                                                     µA. further to(t       of the data
                                                                                                                                                             :  0.85
                                                                                                                                                       demonstrate       or
                                                                                                                                                                       the   correspond
                                                                                                                                                                              0.9)
                                                                                                                                                                               perpendicularly
                                                                                                                                                                                        /Co     to Kmagnetized
                                                                                                                                                                                                   Fe i and
                                                                                                                                                                                                          B      (1.0–1.7)/Ta
                                                                                                                                                                                                                    CoFeB–MgO
                                                                                                                                                                                                                         at room        (5)/Ru
                                                                                                                                                                                                                                      temperature,  (5)  (num-
                                                                                                                                                                                                                                                        which     is consistent         with    earlier    studies.     5,19
                                                                                                                                                       MgO                                     20      60 20
                       5     3         The    Perspective:
           this CoFeB thickness, which determines
                                             three
                                                          andthe
                                                      conditions
                                                          magnetic
                                                                       CoA.
                                                               Ni, orthermal
                                                                          that
                                                                      elements
                                                                                 D.
                                                                            and Fe  withKent,
                                                                                    stability,
                                                                                         heavier
                                                                                   high-performance
                                                                                 like Pt and  Pd.
                                                                                                      Perpendicular
                                                                                                   non-
                                                                                                time
                                                                                                   These
                                                                                                                  2
                                                                                                         b MS incorporation
                                                                                                       Kdecreases        µ0 . Circles
                                                                                                                    /2 with
                                                                                                                    perpendicular
                                                                                                                   in a  device.   A
                                                                                                                                         all
                                                                                                                                     of this
                                                                                                                                         and
                                                                                                                                 temperature,    the
                                                                                                                                             interface
                                                                                                                                                squares
                                                                                                                                                      in
                                                                                                                                                   bers
                                                                                                                                     perpendicularly
                                                                                                                                                            way,
                                                                                                                                                          anisotropy
                                                                                                                                                            are obtained
                                                                                                                                                           contrast
                                                                                                                                                             are
                                                                                                                                                          magnetized
                                                                                                                                                                        Nature
                                                                                                                                                                        to
                                                                                                                                                                    nominal
                                                                                                                                                                               devices.
                                                                                                                                                                             macrospin    ItMaterials
                                                                                                                                                                                             should
                                                                                                                                                                                from magnetization
                                                                                                                                                                                     thicknesses
                                                                                                                                                                               increase   their
                                                                                                                                                                                                model      pre-
                                                                                                                                                                                                          in
                                                                                                                                                                                                  anisotropy
                                                                                                                                                                                                               and9, 699
                                                                                                                                                                                                       be straightforward
                                                                                                                                                                                                                nanometres)
                                                                                                                                                                                                                further to
                                                                                                                                                                                                                             to (2010)
                                                                                                                                                                                                                           permit     (Fig. 1a),spin-torque
                                                                                                                                                                                                                                   High-speed        which areswitching was studied by applying a less
           is 2.1 ⇥ 10 J m , a value comparable materials  to thatareof        theto have
                                                                                      Co–Pd            FMR The
                                                                                                dictions.      measurements,
                                                                                                                     largest reductionrespectively.
                                                                                                                                                 inprocessed
                                                                                                                                                     switching        time
                                   MTJs    need  to  satisfy  impose         a stringent
                                                                           known               set   of
                                                                                           perpendicular  requirements
                                                                                                                   CoFeB-MTJ       on  theis shown
                                                                                                                                    device              to have a largeintooccurscircular
                                                                                                                                                                               stable     between devices
                                                                                                                                                                                        magnetization    room
                                                                                                                                                                                                           stateswith    asmaller
                                                                                                                                                                                                                  in eventhan405 ns or duration
                                                                                                                                                                                                                                         150 nmcurrentdiameter pulse and determining the junction state (P
SPICE-SPIN+X  Seminar multilayers
           perpendicular                25
                                           and high enough
                                   materials to be used
                                                                       to secure
                                                          magnetic anisotropy
                                                              in the MTJ structure.(PMA),goodandtemperature         andthe 150thermal
                                                                                                  are already magnetoresistance
                                                                                                     First of all,                 K. Further,
                                                                                                                                          (>100%).atWhen
                                                                                                                                                   by low        temperatures,
                                                                                                                                                                these
                                                                                                                                                           electron-beam       magnetic there     is a factor
                                                                                                                                                                                            elements,
                                                                                                                                                                                      lithography        for example, by
                                                                                                                                                                                                              and Ar-ion oradding
                                                                                                                                                                                                                             AP)milling
                                                                                                                                                                                                                                     before and(Fig.after
                                                                                                                                                                                                                                                       1b).theForpulse. We start the measurement sequence 11
ectrodes
   NYU    (typically CoFeB).                                                         moment of the free layer to be reversed by
                                                                                     spin-transfer torque.
                                                               Magnetic Tunnel Junction    Nanopillars
                                                                                FOCUS | COMMENTARY
                     Bit line                                                        Device attributes and applications
                                                 a
                                                                                                STT-MRAMs           b
                                                                                                                                  are potentially suitable for
                                                                                                a variety of uses, including as replacement
                                                                                                of battery-backed static random access                                                             Micromagnetic simulations
                                                       1.0                                                                 1.0

                                                 Resistance (kΩ)

                                                                                                     Resistance (kΩ)
                                                                                                memory (SRAM) and as a fast-write
                                                      0.75                                                               0.75
                                                                                                buffer in a hard disk or solid-state drive.
                                                                      Word line
                                                       0.5
                                                                                                Table 1 lists0.5the key features of existing
                                                                                                and emerging −0.6                 memory −0.4 -0.2
                                                                                                                                                        technologies.
                                                                                                                                                         0    0.2 0.4 0.6
                                                             −40        −20          0          20        40
                                                                            Magnetic field (mT)STT-MRAM is the only                                Voltagenon-volatile
                                                                                                                                                            (V)

                                                  c
                                                                                                memory expected                  5
                                                                                                                                            to    have        unlimited
            +m                   -m                      3                                      endurance. This is because there is no
                                                                                                inherent magnetic                           wear-out mechanism

                                                                                                                       1/t (GHz)
                                                                                                                               2.5

                         Eb                              2
                                                                                                for     switching               magnetic                moments               back        and
                                                                                                forth. No atoms                        are      moved           during           writing       N. Statuto et al., PRB 103, 014409 (2021)
                                                             I/Ic0

                                                                                                                                 0
                                                                                                                                                                                               P. Bouquin et al., APL 113, 222408 (2018)
                                                                                                operations,                 as    is   the      case       in    phase        change
                                                                                                                                   0          1          2         3
                                                                                                                                                    I/I
                        ) & 60
                                                                                                                                   c0
        Bit-line
           Eb /(kTcomplement                              1                                                                                                                                     I. Volvach et al., APL 116, 192408 (2020)
                                                                                                memory (PCM) or resistive random access                                                        J. B. Mohammadi et al., APL 118, 132407 (2021)
                                                                                                memory               (RRAM);                 only        the     magnetization
               ℏ ( P bit         )cell.
               4e 1 + P 2 Eb
    Vc = α
gure 1 | STT-MRAM                     GP A magnetic−10tunnel−9                                  is rotated.             There           is,−5 however,              an −3 electrical
                                                         0
                                                                                                −8            −7             −6                           −4
                                                                                                                   log t (s)
nction
    J. C.isSlonczewski,
             formed by   PRB a 71,
                                 fixed
                                     024411reference
                                                (2005)         layer                            wear-out mechanism — the dielectric
                         Figure 2 | STT-MRAM electrical characteristics. a, Resistance versus applied magnetic field, showing bistable resistance states near zero-field associated
 urple),
    J. C. a  tunnel barrier
           Slonczewski  &with
                           J. Z.    (grey)
                                  Sun,
                              parallel
                                          JMMM   and310,a169
                                       (P) and antiparallel   free-layer
                                                             (AP)
                                                                  (2007)                        breakdown
                                                                   magnetized bits. b, Resistance    versus voltage, showingof switching
                                                                                                                                  the MgO   between AP   tunnel
                                                                                                                                                           and P states barrier.           Tovice versa
                                                                                                                                                                         (positive bias) and

ement (red),A.with        both
                         the
                    D. ofKentpulse  layers
                                    duration
                                     and      D.magnetized
                                             proportional
                                                    C.      to pulse amplitude, characteristic
                                                           Worledge,              “A     new    avoid
                                                                                                 of spin      this,
                                                                                                    the ballistic
                                                                                                              on          the
                                                                                                                  switching
                                                                                                                     magnetic limitwrite         voltage
                                                                                                                                    at shortmemories,”
                                                                                                                                             times,               must
                                                                                                                                                     while the dashed-dotted
                                                                                                                                                                      Nature  beline kept
                         (negative bias). c, Pulse switching amplitude versus pulse duration, on a logarithmic scale for fixed switching probability. The dashed line shows the inverse of
                                                                                                                                                                                     isNanotechnology
                                                                                                                                                                                       characteristic          10,  187 (2015)
erpendicular to themagnetization
                            plane
                             et al.,
                H. Liuduration
                                       ofreversal
                                            theΔjunction
                                          "Dynamics = U/(kT)   (ref.
                                                                     (black
                                                                    of
                                                                     20); spin      torque
                                                                          measurements     of
                                                                                                sufficiently
                                                                                              these  switching
                                                                                                    device  characteristics
                                                                                                                           low
                                                                                                                             incan
                                                                                                                                     (roughly
                                                                                                                                   all-perpendicular
                                                                                                                                   thus  be used  to
                                                                                                                                                           400
                                                                                                                                                     estimate   Δ.
                                                                                                                                                                    mV
                                                                                                                                                                   The    spin
                                                                                                                                                                       inset
                                                                                                                                                                              across
                            the long-time behaviour, thermally activated transitions assisted by STT. The slope of the dashed-dotted line is inversely related to the energy barrier to
                                                                                                                                                                             shows    valve
                                                                                                                                                                                     the          nanopillars,"
                                                                                                                                                                                         inverse pulse            JMMM    358, 233  (2014)
 rows). The bit is selected        versusby   a amplitude
                                          pulse  word inline          and
                                                                the short
                                                                                                the     tunnel           barrier)           12
                                                                                                                                                . STT-MRAM                      can       be
                                                                          time limit. The slope of this curve is the STT dynamic parameter A, and the intercept with the x axis occurs at I , the
                                                                                                                                                                    c0

  SPICE-SPIN+X Seminar   threshold current for STT switching, permitting determination of key device parameters from short-time pulse switching data.                                                                                           12
NYU

                                                                                   High Speed Magnetization Switching
                                                                                                                                                                                                   40 nm diameter nanopillar
         Pulse
                                                                                                                                                                                                                                         1.0

                                                                                                                                                                                 Amplitude (mV)
                                                                                CoFeB/W/CoFeB FL                                                                                                  700                     AP→P
                             Bias Tee                                           MgO
                                                                                                                                                                                                  600                      295 K
                                        DC
                                                                                                                                                                                                  500                                    0.8
                                                                                  SAF
                                                                                                                                                                                                  400
                                                                                                                                     1                           T = 295 K

                                                                                                                                                                                                                                               Probability
                        a)                                                                                                                                                                        300
                                                                                                                                                                      AP to P                                                            0.6
                                                                                                                                                                      P to AP

                                                                                                           Switching Error Rate
                                                                                                                                    0.1                                                           200
                    9                                                  9
  Resistance (kΩ)

                                                     Resistance (kΩ)

                                                                                                                                                                                 Amplitude (mV)
                    8                                                  8                                                                                                                          800
                                                                                                                                   0.01                                                                                   P→AP
                    7                                                  7                                                                                                                          700                                    0.4
                    6                                                  6
                                                                                                                                                                                                                          295 K
                    5                                                  5
                                                                                                                                  0.001                                                           600
                    4   b)                                             4
                                                                           c)                                                                                                                     500                                    0.2
                                                                                                                                  1E-4
                    3                                                  3
                                                                                                                                                                                                  400
                        -400 -200   0        200   400             -900 -600 -300       0    300 600 900
                              Field (mT)                                        Voltage (mV)                                      1E-5
                                                                                                                                          -600    -400    200   400     600                       300
                                                                                                                                                 Pulse Amplitude (mV)                                                                    0.0
                        Laura Rehm et al., Appl. Phys. Lett. 115, 182404 (2019)
                        Laura Rehm et al., Phys. Rev. Appl. 15, 034088 (2021)
                                                                                                                                                                                                                  ✓                 ◆
  For pulse duration τ0 the                                                                                                                                                                              1   1        I        Ic
  spin-charge conversion                                                                    Ns   (mFL /μB)                                                                                                 =
                                                                                               =            ≃ 0.23                                                                                       ⌧   ⌧0           Ic
  efficiency in a macrospin                                                                   Nc    (Icτ0 /e)
  model:                                                                                                                                                                        ⌧0 Ic = I⌧                        Ic ⌧                  Ic ≃ 100 μA
                                                                                                                                                     critical number
              Ns
                 =
                          P
                                   ≃ 0.11                                                    P = mr /(2 + mr)                                        of transmitted             eNc                      eN       dissipation
              Nc (1 + P 2)ln(4 πΔ)
                                                                                             Δ = Eb /(kBT )                                            charges Nc
SPICE-SPIN+X Seminar                                                                                                                                                                                    Write energy:           . 250 fJ                     13
Electrical Generation of Spin Currents

    Outline

      • Introduction: Spin torques and spin-orbit torques
      • Charge-to-spin conversion efficiency in switching perpendicular magnetic
        tunnel junction nanopillars
      • Planar Hall effect spin torques

SPICE-SPIN+X Seminar                                                               14
NYU

                                      Spin Orbit Torques

    • Separating read/write paths can
       • Allow separate optimization of read/write
         channels
       • Increase barrier longevity
       • Eliminate reference layer switching
         instabilities

    • Spin Hall and Rashba effects can
      be used to generate spin current.

                                                     L. Liu et al., "Spin-Torque Switching with the Giant Spin Hall
                                                     Effect of Tantalum." Science 336, 6081 (2012)

                                                     I. M. Miron et al. "Current-driven spin torque induced by the
                                                     Rashba effect in a ferromagnetic metal layer," Nature
                                                     Materials 9, 230(2010)

SPICE-SPIN+X Seminar                                                                                                  15
PHE                                       M             JPHE
     NYU
                                                              z                          z                                   z
                                                            Q PHE                      Q PHE         +Idc                  Q PHE
                         Ta/Au/FM/Ta
                         Ta/Pd/FM/Ta
                                            Spin Currents Set By Magnetization
                                            FM
                                            Au
                                                                        FM
                                                                        Au                           Au
                         Ta/Pt/FM/Ta        Ta                          Ta                           Ta

 0     Symmetry
        90   180of antidamping
                    270   360 spin torques:
                               f
                 ϕ (°)

  Ta/Au/FM/Ta                                     FM
                                                                                                 z

                                                  NM                                                        y   M
  Ta/Pd/FM/Ta
                                                                  PHT
                                                                                                                                   Blue=antidamping
                                                                                 SHT
                                                                                                                                   Red=damping
                                                  +I                                                            x
                                                    dc
  Ta/Pt/FM/Ta
 0         90     180     270      360
                 θ (°)
                                           From C. Safranski, E. A. Montoya & I. N. Krivorotov, Nature Nanotechnology 14, 27 (2019)

 tryCharge-to-spin
     and material dependenceconversion
                                  of SOTs. a,b, dΔH/dKdc measured at room temperature for different NM1 layers characterizes the
 ping SHT in the xy plane (a) and that of the antidamping PHT in the xz plane (b). c–e, Schematics of the flow of pure spin current
          • Spin-orbit
NM/FM interface             couplingplanar
                   by spin-polarized     in non-magnetic
                                               Hall current densitymaterials
                                                                       JPHE in the(e.g.  by for
                                                                                   FM layer   Spin-Hall,      Rashba
                                                                                                 Idc!>!0 (c) and            and
                                                                                                                  Idc!a!0.charge
                                                               Error bars show the
                                                                       current       standard
                                                                                   into a spinerror    of least
                                                                                                  current       squares
                                                                                                             with         fit (Methods).
                                                                                                                     a controlled       spin polarization that can
            exert torques on an adjacent magnetic layer and switch perpendicularly magnetized elements

tudinal spin current (p̂ ∣∣m̂ ) by the FM can give         net angular momentum transfer to the FM and zero PHT, as illus-
ng torque. An example
 SPICE-SPIN+X   Seminar of such a mechanism                trated in Fig. 3e. In contrast, we found that Au/AlO is a poor spin                                          16
NYU                                                                       The spin current flow in the z-direction for the anomalous Hall effect (AHE) mechanism is

                                                  Planar Hall Driven Spin Current
                                                                           proportional to my , and, again, with a SP direction m̂. So the maximum AHE spin current
                                                                           with a perpendicular spin component is when the magnetization is tilted in the y − z plane;
                                                                           it is zero when m̂ = ẑ because in this case there is no y-component of magnetization.
                                                                                The spin currents and spin torques associated with planar Hall effect (PHE) have a dif-
                                                                           ferent symmetry. For example, they are zero when m̂ = ŷ and can be non-zero when the

                              ℏ                                            magnetization is canted in the x − z plane. These symmetries provide a means to classify

                        Js = η (m̂ ⋅ Jdc) m̂
                                                                           the response experimentally, as indicated in Fig. 2b. Recently, a torque with a symmetry
                                                                           associated with the planar Hall effect has been identified in single Ni|Co multilayers [95]

                              2e                                           and a torque consistent with the anomalous Hall effect was observed [96–98]. Spin injec-
                                                                           tion/detection with anomalous Hall effect has also been reported [99]. Recent research from
                                                                           the PIs of this proposal has identified a spin torque from Ni|Co multilayers with symmetry
                                                                           associated with the planar Hall effect acting on a second (CoFeB) detector ferromagnet [34],
                                                                           which we plan to explore further in the proposed project.
        • Spin current needs to be injected into nearby
                                                     3.1.2FM
                                                           Spin                polarization associated with magnetic/nonmagnetic interfaces: It is
                                                                                                            Non-magnetic
                                                                 now appreciated that the nature of the interfaces   can change the layer       NM
                                                                                                                                      picture significantly.     (For
                                                                 an up-to-date review see [100].) Most notably, the spin polarization of interface-generated
       • Thus only the z component of current is important       spin currents is not necessarily in the plane of the interface or bound by crystal symmetry
                                                                 constraints [101]. Amin et al. has shown that at an interface between a ferromagnet and non-
                                                                 magnet in the presence of strong spin-orbit interactions, the resulting spin current entering

           ℏ                     ℏ
                                                                 the nonmagnet can have its polarization rotated from the plane of the interface [102–104].

      J = η (m̂ ⋅ x)(
                   ̂ m̂ ⋅ z)J
                           ̂  = η cos θ sin θ
                                                                 The spin-current polarization can be written as [102–104]: j = jf ŝ + jp m̂ × ŝ + jm ŝ × (m̂ × ŝ),
        sz                                    dc
                                                                 where j is the spin polarization direction and ŝ = ẑ × E. At nonmagnetic interfaces, jp and
           2e                    2e                              jm vanish, as expected for spin-Hall and Rasha-Edelstein effects (i.e. the spin polarization is
                                                                 in the plane of the interface perpendicular to the electric field). The new theoretical result
                                                                 is that at FM/NM interfaces the net spin current can acquire a polarization at an angle set
                                                                 by ŝ and the magnetization direction m̂. For
  T. Taniguchi, J. Grollier & M. Stiles, PR Applied 3, 044001 (2015)
                                                                 example, if the magnetization is parallel to x̂
  K. D. Belashchenko et al., PR Materials 3, 011401 (2019) & (parallel
                                                                  PRB 101,     020407
                                                                           to the current(2020)
                                                                                           flow direction) the term
  V. P. Amin, J. Zemen & M. D. Stiles. Interface-generated spin     currents.
                                                                 with           PRL 121,
                                                                       the prefactor          136805
                                                                                       jp gives        (2018) of
                                                                                                  a component
  V. P. Amin, P. M. Haney & M. D. Stiles, "Interfacial spin-orbitspin
                                                                   torques,"   arXiv:2008.01182
                                                                       polarization  in the ẑ direction, perpen-
                                                                 dicular to the interface. In brief, the micro-
                                                                 scopic mechanism is spin precession of spin-
SPICE-SPIN+X Seminar                                             polarized electrons in the interface spin-orbit                                                          17
NYU

                                               Patterned Samples

                                                                        • CoNi has large AMR and is grown with
                                                                          perpendicular anisotropy
                                                                        • CoFeB has small AMR and is grown to be
                                                                          weakly in-plane
                                                                        • A ~0.1 Tesla field can saturate both
                                                                          layers
                                                                                      1

                                                                                    0.5

                                                                              M/Ms
                                                                                      0

                                                                                   −0.5
                                                                                                             OOP
                                                                                                             IP
                                                                                     −1

                   • 400 nm x 3 µm bridges                                                −4   −2   0    2
                                                                                               Field (kOe)
                                                                                                               4

          SiO2/Ta(3)/Pt(3)/[Co(0.65)/Ni(0.98)]x2/Co(0.65)/Au(3)/CoFeB(1.5)/Ta(3)

SPICE-SPIN+X Seminar                                                                                               18
NYU

                  ST-FMR Angular Dependence
VIEW LETTERS 124, 197204 (2020)                                                        θ

        • Angular dependence of resonance field
          with f=14 GHz drive can identify the           H in-plane   H out-of-plane
          layer’s modes.
                                                            14 GHz
        (γ)
                2
         ω     2                             2
            = μ0 (H − Meff cos 2θ)(H − Meff cos θ)
                      Meff = Ms − Hp
         • CoNi has out-of-plane anisotropy (Meff < 0):
              Hres large for H in-plane

         • CFB has in-plane anisotropy (Meff > 0):
               Hres large for H out-of-plane

 SPICE-SPIN+X Seminar                                                                      19
NYU

                             ST-FMR Bias Dependence
                                                      f = 14 GHz, θ = 330 degrees

    • We work at high enough frequency so that the
      applied fields saturate both FM’s
      magnetizations parallel to the applied field.

    • Application of DC current changes the
      resonances linewidths

                    ω ℏ η       Idc
       ΔH = ΔH0 + 2α +               cos θ sin θ
                    γ  e MstFM wttot

SPICE-SPIN+X Seminar                                                                20
NYU

                                  Linewidth vs Bias
                                                      f = 14 GHz, θ = 330 degrees
       • Observe linear modulation of
         resonance linewidth for both layers.

       • The slope is proportional to the
         charge to spin conversion efficiency

                dΔH ℏ η cos θ sin θ
                     =
                dIdc   e Ms tFM wttot

SPICE-SPIN+X Seminar                                                                21
NYU

                                                   Linewidth vs Bias
                              H
                        PHYSICAL REVIEW LETTERS 124, 197204 (2020)
            θ = 330 degrees                                               θ = 205 degrees

                                                                                            H

                   • Changing    the   z component      of  the field changes  the   sign of the  spin-torques
-FMR signal at θ ¼ 330 degrees for three different dc bias. Resonance linewidth for each layer as a function of dc bias at
grees and (c) θ ¼ 205 degrees.
 SPICE-SPIN+X Seminar                                                                                                        22
the CFB layer from a spin current produced in the CoNi            layer.
 NYU
                                                          layer. In Ref. [21], a similar torque was observed in a single    sourc
                        Angular Dependence of Spin Torque ferromagnet paired with a spin sink. When comparing the              We
                                                          torque on the CoNi layer in this work to Ref. [21], the θ sign    Here
                                                          is consist with a larger spin current flow from CoNi in the       by a
                                                          direction of the Au layer. While there is a Pt layer on the       angle
   •Slope of linewidth vs bias follows                    other interface, its resistivity is high due to the thin nature   versio
    expected angular dependence:                          of the layer [40] and therefore its spin orbit generated spin     damp
                                                                                                                            Here,
         dΔH ℏ η cos θ sin θ                                                                                                the A
                =                                                                                                           conta
          dIdc    e MstFM wttot                                                                                             Assum
                                                                                                                            we w
                                                                                                                            linew
   •Overall charge to spin conversion                                                                                       Supp
    efficiency:

       •CFB η = 0.05
                                                                                                                            where
       •CoNi η = 0.09                                                                                                       partic
                                                                                                                            thickn
                                                                                                                            800 e
   •Similar conversion efficiency as spin                                                                                   dΔH
    Hall effect in materials like Pt.                                                                                       efficie
                                                          FIG.
                        C. Safranski, J. Z. Sun, J-W. Xu and   3. PRL
                                                             ADK, Angular
                                                                      124,dependence  of dΔH=dI dc for the CFB (top)
                                                                           197204 (2020)                                    from
SPICE-SPIN+X Seminar                                      and CoNi (bottom) layers with a fit to the expected angular       the23C
to charge-current   flow    in  the   z  direction,    but  the  thin-film
                                                                                                         σ~ E ¼the corrections due to the charge
                                                                                                  including                                            current itself
 NYU               ∇ðδμ=eÞ ¼ ð∂ z δμ=eÞez . The electric field adjusts itself so                                                  σ þ σ AMR m2z
                     geometry
                   that         treated
                         no electric     here prevents
                                      current     flows inthat. theExcept      for the applied
                                                                     z direction.                 being zero. The effective conductivities are
                                                                                                                  − ðζσ AH my − ησ AMR mz mx Þ;
                                                      Spin Currents Set By Magnetization
                     electric potential  eE    x,  only   the  z  components         of ∇μ̄ and                                                                       ð10Þ
                      In a particular ferromagnetic layer, we can solve Eqs. (6)
                                             x
                                                                                                                             m z Þðσ AH my − σ AMR mz mx Þ
                                                                                                                               2
                     ∇δμ   are  nonzero,    i.e.,  ∇ð  μ̄=eÞ   ¼  E  e    þ   ð∂   μ̄=eÞe   and               ðβσ   þ ησ AMR
                   and (7) together with the diffusion equation     x x          z [63], z           σ~ E ¼
                                                                                                    and
                     ∇ðδμ=eÞ ¼ ð∂ z δμ=eÞez . The electric field adjusts itself so                                           σ þ σ AMR m2z
                     that no electric current     flows in the↑ z direction.
                                       ∂ 2                      μ  −    μ ↓                                   − ðζσ AH my − ησ AMR2mz mx Þ;                     ð10Þ
                        In a particular ferromagnetic
                                            ðμ  ↑
                                                  −   μ ↓
                                                          Þ ¼layer, we can  ;   solve Eqs. (6)ð8Þ              σ
                                                                                                               ~ δμ ¼  σ þ σ AMR z m
                     and (7) together∂zwith the diffusion equation l2sf                                                                      !                   "
                                          2
                                                                                 [63],
        Spin      Hall effect in non-magnetic metals                                               and
                                                                                                                     − ðβσ þ ησ AMR mz Þ   2Spinβσ þHall     mz2
                                                                                                                                                      ησ AMREffect
                                                                                                                                                                     : ð11Þ
                             (a)                                                                                                                 σþ    σ AMR m2z
                                           z∂ ðμ↑ − μ↓ Þ ¼ μ − μ ;
                                             2              ↑      ↓

                                           ∂z2 y              l2sf
                                                                                           ð8Þ             σ~ δμ ¼ σ þ
                                                                                                                              −ℏ
                                                                                                                         σ AMR m2z
                                                                                                                                  !               "
                                      x
                                                                                                               − ðβσ Qþ ησ=   m  Þ  ξσ
                                                                                                     While the effective conductivities
                                                                                                                                   βσ þ ησ
                                                                                                                                      2
                                                                                                                                        SHE    (
                                                                                                                                           appear
                                                                                                                                                 z ̂ ×
                                                                                                                                                    AMR
                                                                                                                                                     :  E)
                                                                                                                                                       ð11Þ ⊗
                                                                                                                                               m complicated, 2
                                                                                                                                                              z z ̂
                                                                                                                               2emain results of this paper. If
                                                                                      dF             σ~ simplifies considerably inσ þ certain mlimits and gives
                                                                                                                                AMR   z                   2
                               (a)                m
                                                                                                       E                                σ          AMR    z
                                             z                                                       simple illustrations of the
                                     x           y                                    dN                 the
                                                                                                     While        anisotropic
                                                                                                                 the     effective       magnetoresistance
                                                                                                                                          conductivities          appear  ⊗
                                                                                                                                                                       Polarization
                                                                                                                                                                          can     be    neglected,
                                                                                                                                                                             complicated,            Flow direction
                           F                                                            dF
                                                                                                                → ðβ − ζÞm
                                                                                                     σ~ Eσ~ Esimplifies        considerably
                                                                                                                                     y σ AH , i.e.,in      certain
                                                                                                                                                       there           limitscurrent
                                                                                                                                                                is a spin       and giveswhenever
                                                   m
                                                                                                     simple       illustrations Polarization
                                                                                                         the magnetization              ofhas
                                                                                                                                            theamaincomponentresultsand of this
                                                                                                                                                                        along  flowpaper.
                                                                                                                                                                                 the      direction
                                                                                                                                                                                            If
                                                                                                                                                                                       y direction,     set by geometry
                          N                                                             dN           theQ anisotropic              magnetoresistance                canmagnetization
                                                                                                                                                                           be neglected,out of
                             F
                                                                      Ex                                     iz ∼   m  i m  y .  Thus,        by    tilting     the
                                                                                                           → ðβ −it ζÞm
                                                                                                     σ~ Eplane,                y σ AH , i.e.,tothere
                                                                                                                          is possible             get is ana out-of-plane
                                                                                                                                                                spin current whenever
                                                                                                                                                                                   component of
                                                                                                     thethe magnetization
                                                                                                                 spins flowing       has aintocomponent
                                                                                                                                                     the other   alonglayer,
                                                                                                                                                                          the y something
                                                                                                                                                                                  direction, not
                             N
       Spin Orbit Interaction
                          (b)                    in magnetic         Ex
                                                                             metals                  Qiz ∼ mi my . Thus, by tiltingAnomalous             the magnetization        Hallout Effect
                                                                                                                                                                                           of
                                                                                                         achievable with the spin Hall effect in nonmagnetic
                                                                                          d1         plane, it is possible to get an out-of-plane component of
                                                                                                         materials. This feature is illustrated in Fig. 1(b). The factor
                                                 m                                                   the spins flowing into the other layer, something not
                            (b)                                                           dN
                                                                                                         of ðβ − ζÞ arises from two contributions; the term propor-
                                                                                                     achievable with the spin Hall effect in nonmagnetic
                                                                                        d1               tional toThis
                                                                                                     materials.           ζ is     directly
                                                                                                                               feature     is    from theinpolarized
                                                                                                                                              illustrated          Fig.  1(b).   current
                                                                                                                                                                                The         accom-
                                                                                                                                                                                       factor
                           F1                     m
                                                                                          d          of  panying
                                                                                                          ðβ   −  ζÞ    the anomalous
                                                                                                                       arises     from     two    Hall current. The
                                                                                                                                                  contributions;        the   termpropor-
                                                                                                                                                                             term    proportional
                                                                                                                                                                                         Flow perpendicular to m and          E
                                                                                        dN 2
                                                                                                         to β to
                                                                                                     tional      comes
                                                                                                                     ζ   is  from
                                                                                                                             directly  thefrom
                                                                                                                                             polarization
                                                                                                                                                    the          of thecurrent
                                                                                                                                                           polarized       counterflow
                                                                                                                                                                                     accom-  current
                          N F1
                                                                                        d2
                                                                                                         that cancels
                                                                                                     panying       the          the anomalous
                                                                                                                          anomalous         Hall    current.Planar
                                                                                                                                                          Hall  The    termHall
                                                                                                                                                                   current.           Effect
                                                                                                                                                                              proportional
                          F2N                      p
                                                                                                              Whenfrom
                                                                                                     to β comes            the the anomalous
                                                                                                                                       polarizationHall   of the effect     can becurrent
                                                                                                                                                                     counterflow        neglected,
                                                                      Ex                                        → ðη −the
                                                                                                         σ~ Ecancels         βÞm       m   σ               σ
                                                                                                                                                                   . This expression is more
                                                                                                     that                        anomalous         Hall
                                                                                                                                     x z AMR σþσ AMR        current.
                                                                                                                                                               m2z
                             F                     p
                                                                                                          When the anomalous
                                                                                                         complicated            than     that    Halltheeffect
                                                                                                                                                for          anomalouscan beHall neglected,
                                                                                                                                                                                     effect above
                 FIG. 1. (a) Schematic geometry forExspin-Hall-effect-induced σ~ → ðη − βÞm m σ
                              2                                                                                                                     σ
                                                                                                        Ebecause thex anisotropic                         2 . This expression is more
                                                                                                                                    z AMR σþσ AMR m     magnetoresistance              affects the
                 spin-transfer torques. In this geometry, the dampinglike torque is
                                                                                                     complicated           than    that   for   the
                                                                                                                                                          z
                                                                                                                                                      anomalous
                                                                                                         conductivity in the z direction, as captured by the last       Hall  effect     Flow
                                                                                                                                                                                       above       parallel  to m
                 with
                   FIG.respect
                           1. (a)toSchematic
                                        the y axis,     i.e., mfor
                                                     geometry     × ðspin-Hall-effect-induced
                                                                       ŷ × mÞ (with a smaller
                                                                                                     because
                                                                                                         factor in   thethisanisotropic
                                                                                                                                expression.magnetoresistance
                                                                                                                                                    As with the previous       affects
                                                                                                                                                                                     case,thean out-
       Figures from
                   spin-transfer
                 fieldlike
                   with  T.
                                    torques.
                              torque).
                              Taniguchi
                           respect   to  the  y
                                               In this geometry,
                                          (b) Schematic
                                                 et   al.,
                                                  axis,     PR
                                                         i.e.,  m
                                                                     the dampinglike
                                                               geometry
                                                                  Applied
                                                                  ×   ŷ × mÞ
                                                                                        torque is
                                                                            for anomalous-Hall-
                                                                                  3, 044001
                                                                                 (with
                 effect-induced spin-transfer torques. In this case, the dampinglike
                                                                     ð                 a  smaller    conductivity
                                                                                                  (2015)                    in Polarization
                                                                                                                                 the    z   direction,       asand
                                                                                                         of-plane component of the magnetization gives an out-of-capturedflow  by   direction
                                                                                                                                                                                    the  last         set by magnetization!
                   fieldlike
                 torque         torque).
                           is with         (b) Schematic
                                     respect                   geometry
                                                to the fixed-layer                        direction factor
                                                                           for anomalous-Hall-
                                                                         magnetization                   plane  in this    expression.
                                                                                                                    component             to Asthewithspinthecurrent,
                                                                                                                                                                 previousQcase,      an out-
                                                                                                                                                                              iz ∼ mi mx mz . As
                 p,effect-induced
                     i.e., m × ðp ×   spin-transfer
                                         mÞ (with atorques.
                                                          smallerIn fieldlike
                                                                     this case, torque).
                                                                                the dampinglike      of-plane
                                                                                                         with the   component
                                                                                                                         previousofcase,    the magnetization
                                                                                                                                                   the factor of ðη      gives
                                                                                                                                                                            − βÞ anappears
                                                                                                                                                                                     out-of- from
                   torque is with respect to the fixed-layer magnetization direction                 plane component to the spin current, Qiz ∼ mi mx mz . As
                   p, i.e., m × ðp × mÞ (with a smaller fieldlike torque).                           with the previous case, the factor of ðη − βÞ appears from
SPICE-SPIN+X Seminar                                                                                                                                                                                                              24
dΔH=dI dc angular symmetry of ðm̂ · ŷÞ. This is incon-           CFB layer, t
 NYU                                                                         sistent with our observation. Spin currents produced by           be expected
                                             Angular Symmetry                AHE have a polarization following m̂ as well, however the
                                                                             flow direction follows m̂ × x̂. When magnetization lies in
                                                                                                                                               momentum
                                                                                                                                               decreases a
                                                                             the xz plane as studied here, there is no flow of spin current    known to h
                                                                             in the ẑ direction towards CFB [17].                             higher AM
                                                                                                                               *
                                                                                The angular dependence of the observed torques is
                                                                             consistent with the absorption of angular momentum in
                                                                                                                                               Material [29
                                                                                                                                               higher, resu
                                                                             the CFB layer from a spin current produced in the CoNi            layer. As su
                                                                             layer. In Ref. [21], a similar torque was observed in a single    source of p
                                                                             ferromagnet paired with a spin sink. When comparing the              We next
                                                                             torque on the CoNi layer in this work to Ref. [21], the sign      Here we aim
                                                                             is consist with a larger spin current flow from CoNi in the       by a dimen
                                                                             direction of the Au layer. While there is a Pt layer on the       angle. We
                                                                             other interface, its resistivity is high due to the thin nature   version effi
                                                                             of the layer [40] and therefore its spin orbit generated spin     damping-lik
                                                     *Symmetry of anti-damping torque under field reversal with fixed current direction        Here, interfa
                                                                                                                                               the Au laye
                                                                                                                                               contained i
                                                                                                                                               Assuming a
                                                                                                                                               we would e
                                                                                                                                               linewidth li
                                                                                                                                               Supplement

                                                                                                                                               where M s
                                                                                                                                               particular l
                                                                                                                                               thickness, a
                                                                                                                                               800 emu=cm
         C. Safranski, J. Z. Sun, J-W Xu and ADK, PRL 124, 197204 (2020)                                                                       dΔH=dI dc
                                                                                                                                               efficiency o
SPICE-SPIN+X Seminar                                                                                                                                    25
NYU

                   Electrical generation of spin currents
  Summary
       • Spin torque switching in perpendicular MTJ nanopillars
          -Charge-to-spin conversion efficiency can be 0.23 for switching!

       • Spin orbit torques with planar Hall effect symmetry have been
         observed in CoNi multilayers
          -Charge-to-spin conversion efficiency (~0.05) is on par with the Spin
           Hall effect in Pt.
          -The spin polarization can be partially out-of-plane, making the PHE
           a candidate for deterministic switching of perpendicularly
           magnetized MTJs                                   L. Rehm et al., APL 115, 182404 (2019)
 https://www.spintalks.org/talks/safranski   PRL 124, 197204 (2020)    L. Rehm et al., PR Appl. 15, 034088 (2021)

SPICE-SPIN+X Seminar                                                                                                26
NYU

                                Kent Group
                        Washington Square Park-June 2010

                                      June 2012
                       Washington Square Park, February 2013

                                                                          June 2018

                                                                  January 2020

                                                   http://www.physics.nyu.edu/kentlab/
SPICE-SPIN+X Seminar                                                                     27
NYU
                        POSTDOCTORAL POSITION: ANTIFERROMAGNETIC
                                  SPINTRONICS @ NYU
                                   Description: A postdoctoral position is available in Prof. Andrew Kent’s research group
                                   in the Center for Quantum Phenomena of the Department of Physics. The research
                                   focus is on antiferromagnetic spintronics, specifically spin-transport phenomena in thin
                                   films of antiferromagnetic insulators and at their interfaces with heavy metals,
                                   ferrimagnets and ferromagnets. The successful candidate will work within a multi-
                                   university and national lab team with expertise in thin film materials, magnetic imaging,
                                   measurement, nanofabrication and modeling. Experience with electronic transport and
                                   magnetic measurements, magnetic imaging (e.g. x-ray), thin film deposition,
                                   nanofabrication and magnetic characterization
                                                                          RES EARCH | R E S E A R C Hmethods
                                                                                                     ARTICLE is desirable. Good
                                   communication, writing and interpersonal skills are essential.   →
                                                                           with an effective field H eff comprising the ex-
                                                                           change field (m0HE = 47.05 T), the anisotropy field
                                                                           (m0 HA = 0.82 T), the externally applied field (H),
                                   Email: andy.kent@nyu.edu
                                                                                                        →
                                                                           and the microwave field ½H m ¼ ðHo cosð2pftÞ;
                                                                           Ho sinð2pft þ qÞ; 0Þ&, where the polarization is
                                                                           determined by changing the phase factor q
                                   Posted: NYU Physics/Interfolio websites soon
                                                                           from 0 to 2p, and i = 1, 2 labels the two sub-
                                                                           lattices. We used the following parameter
                                                                           values for the calculation: g ¼ ge , saturation
                                                                           magnetization Ms = 47.7 kA/m, and a = 0.001,
                                                                           in agreement with previously reported values
                                                                           (24, 25). The theoretical results are displayed
                                                                           in Fig. 1, together with the measured spectro-
                                                                           scopic antiferromagnetic resonance (AFMR)
                                                                           absorptions; the experimental data are rep-
                                                                           resented by solid symbols corresponding to
                                                                           three different samples studied at four avail-
                                                                           able frequencies (horizontal orange arrows).
                                                                           Figure S1 shows the corresponding spectra.
                                                                           The upper left inset to Fig. 1 shows the electron

                                                                                                                                                                                                                                                Downloaded from http://scie
                                                                           paramagnetic resonance (EPR) spectrum ob-
                                                                           tained at frequency f = 395 GHz (red curve)
                                                                           for the magnetic field range corresponding to
                                                                           the HFM resonance (blue triangle at m0 H ¼
                                                                           4:70 T). The EPR signal is markedly distorted
                                                                           by saturation of the probe, owing to the large        Fig. 1. Antiferromagnetic resonance of MnF2. Positions of the EPR spectroscopy resonances of MnF2.
       R. Lebrun et al., Nature 561, 222 (2018)                            thickness of the MnF2 single crystal used in
                                                                                                                                                          P. Vaidya et al., Science 268, 160 (2020)
                                                                                                                                 The solid curves are the computed resonance frequencies associated with the low- and high-frequency AF
                                                                           these experiments, but still allows us to deter-      modes (upper right inset), the SF transition (at m0 HSF e9:4 T), and the QFM at high fields. We use the
SPICE-SPIN+X Seminar                                                       mine the location of the resonances spectro-          fitting parameters m0 HA ¼ 0:82 T and m0 HE ¼ 47:05 T in Eq. 1. The different colors correspond to different   28
NYU

                                                Acknowledgments
                       NYU Team: Dirk Backes*, Gabriel Chaves*, Eason Chen*, Ege Cogulu, Daniel Gopman*, Christian
                       Hahn*, Jinting Hang*, Yu-Ming Hung*, Marion Lavanant*, Ferran Macia*, Jamileh Beik Mohammadi*,
                       Daniele Pinna*, Laura Rehm, Debangsu Roy*, Sohrab Sani*, Nahuel Statuto, Volker Sluka*, Georg
                       Wolf*, Li Ye* Yassine Quessab, Haowen Ren & Junwen Xu (*=group alumni)
 Collaborators         -NIST: Hans Nembach and Justin Shaw
                       -Advanced Light Source, Berkeley: Rajesh V. Chopdekar & Hendrik Ohldag
                       -IBM T. J. Watson Research Center: Chris Safranski & Jonathan Z. Sun
                       -NYU: Gabriel Chaves and Dan Stein
                       -University of Barcelona and ICMAB-CSIC: Nahuel Statuto & Ferran Macia
                       -Ohio State University: Fengyuan Yang
                       -UVA: Joseph Poon and Avik Ghosh
                       -UC Santa Cruz: David Lederman
                       -University of Central Florida: Enrique del Barco
                       -BBN Raytheon: Tom Ohki, Colm Ryan & Graham Rolands
                       -Spin Memory: Georg Wolf, Bartek Kardasz, Steve Watts & Mustafa Pinarbasi
                       -University of Buffalo: Igor Zutic
                       -Wayne State: Alex Matos Abiague
                       -University of Lorraine: Stephane Mangin
                       -U. Paris Saclay, C2N: Dafine Ravelosona
                       -UCSD: Eric Fullerton
SPICE-SPIN+X Seminar                                                                                                    29
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