ALLERGENS IN DETERGENTS AND CLEANING PRODUCTS - KRISTINA VILE, MSC MOLECULAR BIOMEDICIN WWW.ALLERGYCERTIFIED.COM - BCF
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ALLERGENS IN DETERGENTS AND CLEANING PRODUCTS KRISTINA VILE, MSC MOLECULAR BIOMEDICIN KRISTINA@ALLERGYCERTIFIED.COM WWW.ALLERGYCERTIFIED.COM
CONTACT DERMATITIS
ENVIRONMENTAL
EUROPA: 27 %
18-74 YRS
24-48 HOURS
MORE CHILDREN
CONCENTRATION
POPULATIONS STUDY
5 European countries (Sweden, The Netherlands, Germany, Italy and Portugal)
• 12,377 with 32 allergens
• 27 % (18-74 years)
• Women > men
• Allergens
• Nickel (14.5 %)
• Cobalt (2.2 %)
• Fragrance mix I (1.9 %)
• Fragrance mix II (1.9 %)
• Chloratranol (1.8 %) oak moss & tree moss
extract
• HICC (1.4 %) ban (2021)
• PPD: (1.0 %)
MAJOR CAUSES OF CONTACT DERMATITIS/SKIN ALLERGY • Metals (nickel, chrome) • Preservatives (MI) • Perfume • Coloring (metals, p-phenylenediamine) • Plants • Rubber • Glue • Sunscreen
ALLERGENS IN DETERGENTS AND CLEANING PRODUCTS Allergens Irritation • Perfume • Surfactants e.g. sodium lauryl • Preservatives sulfate • Airborne (MI and formaldehyde)
PRESERVATIVES KNOWN TO CAUSE ALLERGI
• Methylisothiazolinone/MI
MORE THAN
• Methylchloroisothiazolinone/MCI 6 % IN
EUROPE
• Kathon (MCI/MIT)
• Formaldehyde and -doners
• Benzylhemiformal
• 2-bromo-2-nitropropane-1,3-diol
• 5-bromo-5-nitro-1,3-dioxane
• Diazolidinyl urea
• DMDM hydantoin
• Formaldehyd
• Imidiazolidinyl urea
• Methenamine
• Paraformaldehyd
• Sodium hydroxymethylglycinate
• Quaternium-15
PERFUME ALLERGY – THE 26
Regulation 26 perfumes must be declared with names on cosmetic products
0.001 % leave on, 0.01 % rinse off
• Alpha isomethyl Ionone • Eugenol
• Amyl cinnamal • Evernia prunastri
• Amylcinnamyl alcohol • Evernia Furfuracea
• Anisyl alcohol
• Farnesol
• Benzyl alcohol
• Benzyl benzoate • Geraniol 19 organic
• Benzyl cinnamat
• Benzyl salicylat • Hexyl cinnamal
• Butylphenyl methylpropional • Hydroxycitronellal
• Hydroxyisohexyl 3-cyclohexene carboxaldehyde
• Cinnamal
• Cinnamyl alcohol • Isoeugenol
• Citral
• Citronellol • Linalool
• Coumarin
• Limonene • Methyl 2-octynoate
ARE THE TESTS GOOD ENOUGH?
IS THE NUMBERS MUCH HIGHER..?
82 Skin
sensitizing
perfumes • Most potent allergens of the 26
perfumes - not in test mix
26 allergens
• Patch test with 26 perfumes can
FM I: 8 identify 40 % more.
FM II: 6
Temamøde Miljøstyrelsen/Sundhedsstyrelsen 4.april 2016
oplæg v. Niels Højsager Bennike.
DETERGENT REGULATION (EU) • No rule about full declaration (as for cosmetics) • Contact information to find full declaration • Use and dosage information • Preservation, enzymes, disinfectants, optical white and perfume need to be declared • The 26 perfumes on EU’s list of most allergenic need to be declared with name
REGULATION – TRENDS FROM COSMETICS • New EU regulation on claims on cosmetics • Not allowed to write “free from” (e.g. parabens, hormone disrupters, triclosan) • Restrictions on hypoallergenic (misleading) • Not allowed to demean ingredients which are legal and approved for cosmetics • We believe that this focus will spread to detergents and cleaning products
EXAMPLES – TRENDS FROM COSMETICS • Methyldibromglutaronitril (MG) • Regulation for cosmetics – banned in leave-on in 2005 • Regulation for detergents and cleaning – banned in rinse-off in 2007 • Methylisothiazolinone (MI) • Regulation for cosmetics – Banned in leave-on in 2016 • Regulation for detergents and cleaning – 15 PPM in rinse-off in 2019
EXAMPLES – HYPOALLERGENIC MISLEADING?
Water, Sodium Coco Sulfate
(plant-powered surfactant),
Cocamidopropylamine Oxide
(plant-powered surfactant),
Lauramine Oxide (plant-powered
surfactant), Coco Betaine (plant-
powered surfactant),
Phenoxyethanol (preservative),
Ethylhexylglycerin (preservative),
Tetrasodium Glutamate Diacetate
(plant-powered water softener),
Natural Fragrance, Citric Acid
(plant-powered pH adjuster),
Limonene (essential oil
component), Citral (essential oil
component• Full declaration on detergents and
cleaning products
• Focus on claims – cosmetics regulation
as a precursor
THE FUTURE • Higher focus on skin friendly and not
only natural
• Think skin friendly in development of
products
• Be prepared by getting knowledge about
the cosmetic productsWHY CERTIFICATIONS?
Many misleading claims on products
Claims:
Free from Hypoallergenic
What has been used instead?
Dermatological tested
On how many, what were the result?
Hypoallergenic
Means less, but less than what?
Free from
parabens
Hypoallergenic
EWA@ALLERGYCERTIFIED.COMTERMS AND REQUIREMENTS FOR THE PRODUCERS
Prohibited New criteria
MSDS safety
chemical/ Recipe TDS raw Sample test
assessment
classified materialsFACTS
• AllergyCertified launched in February
2015
• >850 certified products
• International
• Health label
• Allergy
• Endocrine disrupting chemicals
• Carcinogen
• Raw materials
• Advisory boardHOW TO USE ALLERGYCERTIFIED? • Follow us on Facebook or LinkedIn https://www.facebook.com/allergycertified/ https://www.linkedin.com/company/allergycertified • See our website on chemical of the month http://allergycertified.com/blog/chemical-month-cocamidopropyl-betaine/ • Sodium Laureth Sulfate as chemical of the month http://allergycertified.com/blog/chemical-month-sodium-laureth-sulfate-sodium- lauryl-sulfate/ • Write us if you have any questions about allergy
THANK YOU
KRISTINA VILE
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