Polymer composites for automotive sustainability - SusChem

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Polymer composites for automotive sustainability - SusChem
Polymer composites
for automotive sustainability
Polymer composites for automotive sustainability - SusChem
Polymer composites
                      for automotive sustainability

             CEFIC
             Jacques KOMORNICKI
             Innovation Manager and SusChem Secretary
             Bax & Willems Consulting
             Laszlo Bax
             Founding partner
             Harilaos Vasiliadis
             Senior consultant

AUTH O R S
             Ignacio Magallon
             Consultant
             Kelvin Ong
             Consultant
Polymer composites for automotive sustainability - SusChem
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    Acknowledgements                                                                  List of reviewers
                                                                                      Thilo Bein	Professor, Head of Knowledge Management,
                                                                                                  Coordinator ENLIGHT project- Fraunhofer Institute
                                                                                                  for Structural Durability and System Reliability LBF
                                                                                      Peter Brookes          Business manager PU - Huntsman
                                                                                      Christoph Ebel	Group Leader Process Technology for Fibers - TUM (München)
                                                                                      Michel Glotin          Directeur Scientifique Matériaux - Arkema

       T   his publication is the result of a collaborative effort with different
           organizations following a step-by step process:
                                                                                      Christoph Greb	Head of Composites Division
                                                                                                      - Institut fuer Textiltechnik of RWTH Aachen University
                                                                                                      and Textiles
       The SusChem Board has established light-weight materials and
       composites materials among its priorities, as reported in the SusChem          Marc Huisman           Manager Advanced Thermoplastic Composites - DSM
       Strategic Innovation and Research Agenda (SIRA) which can be consulted
                                                                                      Joseph J. Laux	Director of Business Development and Advanced
       on-line http://www.suschem.org/publications.aspx
                                                                                                      Engineering (EU) - Light-weight Composites
                                                                                                      - Magna Management AG
       The SusChem Materials Working group has defined the main technical
       challenges spelled-out in the SusChem SIRA.                                    Gérard Liraut	Expert Leader for Polymers “Characterization and Process”
                                                                                                     - RENAULT GROUP
       The SusChem Working Group on Composites Materials for Automotive
                                                                                      Andrea Pipino	Research and Innovation Manager
       pulled together experts from the chemical industry, the automotive industry,
                                                                                                     - Group Materials Labs - Centro Ricerche Fiat
       the automotive parts suppliers as well as academia and recommended the
       publication of this position paper as well as a wider consultation with the    Jens Rieger	Senior Vice President / Advanced Materials and Systems
       established competence centres in Europe.                                                   Research - Technology Incubation – BASF
                                                                                                   - Member of the SusChem Board
       In the course of the work leading to this publication we have contacted and
                                                                                      Eckart Ruban           Head of Automotive Industry Team - Evonik
       interviewed the leaders of 10 European Clusters on Composites Materials
       who provided their views. 7 clusters also participated to a workshop           Uwe Seemann            Innovation Manager Automotive - BASF
       organized by SusChem.
                                                                                      Kristian Seidel	Senior Manager Body Department
                                                                                                       - Institute for Automotive Engineering
        number of experts from the chemical industry, the automotive industry
       A
                                                                                                       - RWTH Aachen University
       and from academia have reviewed the paper before its publication.
                                                                                      Paruchuri Sreenivas    R&D Frames Engineering - Faurecia Autositze GmbH
                                                                                      Thomas Staffenberger	Head of Research, Automotive Division
                                                                                                            - BENTELER SGL Composite Technology GmbH
                                                                                                      Emeritus professor - ex-Chairman Materials Reserach
                                                                                      Ignaas Verpoest	
                                                                                                      Centre, Coordinator HIVOCOMP project
                                                                                                      - University of Leuven (KU Leuven)
4
6                                                                                                                                                                                                7

    Contents
                                                                                                           Challenges                                                                       34

                                                                                                           4.1      Technical                                                               35

    1
                                                                                                                    4.1.1     Recycling process                                             35
                  Executive summary                                                       8                         4.1.2
                                                                                                                    4.1.3
                                                                                                                              Manufacturing process
                                                                                                                              Methods determining damage to materials
                                                                                                                                                                                            36
                                                                                                                                                                                            36
                                                                                                                    4.1.4     Joining techniques                                            36

        Introduction                                                                12
                                                                                                           4.2      Transversal
                                                                                                                    4.2.1     Cascade of knowledge and multi-material design process
                                                                                                                                                                                            36
                                                                                                                                                                                            37
                                                                                                                    4.2.2     Intra-industry cooperation                                    37
                                                                                                                    4.2.3     Synchronisation of policy and research agenda                 37
        1.1    Overview of polymer composites                                       13

                                                                                              5
        1.2    Resins: Thermosets, thermoplastics and bio-based resins              14
               1.2.1    Thermoset resins                                            14
               1.2.2    Thermoplastic resins                                        14
        1.3    Fibres: Carbon, glass and natural fibres
               1.3.1    Carbon fibres (CF)
                                                                                    15
                                                                                    16
                                                                                                  Possible approaches to address                                                       38

               1.3.2
               1.3.3
                        Glass fibres (GF)
                        Natural fibres (NFs)
                                                                                    16
                                                                                    16
                                                                                                  industry-wide challenges
        1.4    Processes: a comparative overview                                    17
        1.5	Milestones and recent examples                                         18
             of composites applied to the automotive sector                                       5.1   Increase coordination between existing centres                                 39
                                                                                                        5.1.1    Roles and responsibilities                                            39

    2
                                                                                                  5.2   Lead the creation of a highly visible flagship project                         40
                                                                                                        5.2.1    ULSAB: the steel industry lighthouse car project                      40
                                                                                                        5.2.2    Possible process                                                      41

                  The market and opportunities                                           20
                                                                                                  5.3   Stengthen technical/academic skills
                                                                                                        5.3.1    Skills training for workers / Tier 1 suppliers
                                                                                                                                                                                       41
                                                                                                                                                                                       42
                                                                                                        5.3.2    Education programme                                                   42
                                                                                                        5.3.3    Knowledge dissemination                                               42
                  2.1      Supply: the European automotive composites value chain        21
                                                                                                  5.4   Consolidate a roadmap: encourage further innovation                            42
                           2.1.1    European scientific and technical excellence         22
                                                                                                        5.4.1    Supporting innovative SMEs                                            42
                  2.2      Global outlook                                                24

                                                                                              6
                                                                                                        5.4.2    Inclusion of priority call topics for H2020 2016-17 calls             43
                           2.2.1    USA                                                  24
                                                                                                        5.4.3    Proposing to support the coordination of European centres             44
                           2.2.2    Japan                                                25
                  2.3      Market demand: CRP/GRP trends                                 25
                           2.3.1    Carbon composites and the CFRP market                26
                           2.3.2    Glass fibre composites and the GRP market            28
                                                                                                           Summary: a coordinated Vision

    3
                                                                                                                                                                                            46

                                                                                                           for European automotive composites
        The motivation and drivers                                                  30

                                                                                                           Annex A: Overview of existing European automotive composite                      48
                                                                                                           clusters that could form the possible basis of a virtual network
        3.1    Lightweighting                                                       31
                                                                                                           Annex B: Current and recent European R&D&I projects                              50
        3.2    CO2 Regulations                                                      31                     and initiatives on automotive composites
        3.3    Demand for fuel economy                                              32
        3.4    Increased uptake of electric vehicles                                33
Polymer composites for automotive sustainability                                                                                                                                              9
8
      Executive summary

                                                         Automotive composites:
                                                         a growing market driven by efficiency and emissions
                                                         The market for global automotive composite materials is                  However the high cost of materials and the lack of
                                                         forecast to reach €3.72 Bn (US$ 4.3 Bn) by 2017, up                      suitable higher volume manufacturing methods and
                                                         from €2.42 Bn (US$ 2.8 Bn) in 2011, and representing                     higher value recycling processes continue to be some
                                                         a compound annual growth rate (CAGR) of about 7%.1                       of the major limiting factors for future growth. Improving
                                                         This represents a sizable growth opportunity for the                     the value at end-of-life of composites through high
                                                         European chemical and composites industry. However,                      value recycling could help to improve the overall LCA
                                                         the current composites share of the average automotive                   score of composites, but remains challenging. This is
                                                         bill of materials stands at 3.6% with competing materials                especially important given the present EU end-of-life
                                                         such as steel and aluminium. Perhaps surprisingly the                    directive5 for cars (valid since 1st of January 2015),
                                                         automotive sector has the lowest composites penetration                  which stipulates mandatory reuse and recycling of 85%
                                                         in comparison to other advanced product segments                         of the vehicle (and does not consider ‘energy recovery’
                                                         such as the maritime (ships) or consumer goods. The                      of polymers to be recycling). Bio-based matrix materials

    Executive
                                                         automotive industry faces a new challenge aligning material              and fibres can help in reducing the environmental
                                                         properties, product design and production or assembly                    footprint of composites. For these materials to be
                                                         processes - especially in larger volume production series                widely used, important barriers with regard to their cost

    summary
                                                         vehicles. This industry could take more advantage of the                 effectiveness and their mechanical performance need to
                                                         potential of composites for light-weighting vehicles. High               be addressed. To enable larger scale adoption of FRP,
                                                         performance Fibre-reinforced Plastic (FRP) composites                    methods to determine damage to composite parts over
                                                         have the potential to outperform both steel and aluminium,               the lifetime of the vehicle also need to be developed.
                                                         but today both steel and aluminium producers are more
                                                                                                                                  In order to overcome these (and other) challenges,
                                                         successful in actively reducing weight in high volume
                                                                                                                                  various public-private partnership initiatives have
                                                         production car bodies.
                                                                                                                                  already been launched in EU Member States, such
                                                         The demand for weight reduction is driven by the                         as the establishment of composite and automotive
                                                         demand for better fuel efficiency and reduced                            lightweight materials innovation clusters (MAI Carbon
                                                         emissions in order to comply with EU legislation (from                   Augsburg, CiC UK, AZL Aachen, Jules Verne IRT
Polymer composites for automotive sustainability                                                                                                                                                                                                   11
10
                   Executive summary

     The Chemical industry’s key role in the quest for more energy                                                                  Key objective: Establishing a EU-wide programme and ensuring
     efficient, lower consumption vehicles: working closely together                                                                adequate support for automotive composites research and
     with the value chain                                                                                                           innovation for a competitive and energy efficient Europe
     The European Commission’s Horizon 2020 programme                       From its inception in 2004, SusChem identified          Taking into account SusChem’s SIRA roadmap as well                   However as a larger ambition level, beyond the
     aims to enable relevant R&D&I investments that can                     advanced materials as an enabling technology critical   as the main automotive roadmaps (EGVI Multiannual                    identification of individual topics, we envision the
     bring real societal and business impacts. Horizon                      to achieving its vision and mission. SusChem has        Roadmap9, EARPA roadmap10) this document                             creation of an EU-wide coordinated R&D&I programme
     2020 can and will definitely contribute to overcoming                  set innovation priorities for advanced materials to     integrates specific input from key stakeholders                      with long term committed funding to allow for a well-
     technological and market barriers towards lighter road                 be really adopted in key end user markets including     across the value chain, including those involved                     structured, coordinated effort to bring real innovation
     vehicles offering best-in-class NCAP 5 star safety                     automotive, as compiled in SusChem’s Strategic          in production equipment. This document provides                      uptake acceleration and leveraging the strong skills
     levels. While some OEMs focus on improving energy                      Innovation & Research Agenda (SIRA), which is           concrete recommendations to enable faster progress                   and expertise found in many regions in Europe.
     recovery, light-weighting has also been identified to                  now in the process of being updated in the general      in advanced composites light weighting innovation
                                                                                                                                                                                                         As well as a coordinated R&D&I programme, we
     be a potential enabler for electro-mobility uptake7,                   framework of Horizon 2020 8.                            uptake in the automotive industry, enhancing the
                                                                                                                                                                                                         propose the establishment of a European Automotive
     contributing to the reduction of carbon emissions.                                                                             competitiveness of the European economy.
                                                                            Aligned with that purpose and connecting chemistry                                                                           Composites Competence Network. This network
     Larger scale lighthouse R&D&I projects can inspire
                                                                            with its downstream allies in lightweighting road       A perceived uncertainty about continued, substantial                 of R&D&I clusters (many of which launched and/or
     EU players in the automotive and chemical industries
                                                                            transport, SusChem and the automotive R&D               EU funding dedicated to lightweight automotive                       strengthened over the last five years in various Member
     to accelerate their adoption of high performance FRP.
                                                                            association EARPA organised a joint workshop,           materials and specifically (C-)FRP is seen by many                   States) can improve the coordination between local
     The European chemical industry will continue as a key
                                                                            “Exploring    cross-innovation   opportunities   on     players as a factor that makes it more difficult to                  knowledge hubs in the following ways:
     player in this transition in close collaboration with its
                                                                            automotive composites and bio-based materials”,         launch and maintain a substantial, coordinated trans-
     value chain partners.
                                                                            held in Frankfurt on 15 October 2013. The outcomes      disciplinary push to overcome innovation adoption
                                                                                                                                                                                                               Facilitate the co-development of high volume
                                                                                                                                                                                                             1	
                                                                            of this workshop, as well as the feedback collected     barriers and really achieve breakthroughs.
                                                                                                                                                                                                               production processes with suppliers throughout
                                                                            by the stakeholder consultation held as a follow-up
                                                                                                                                    In the context of the Horizon 2020 programme,                              the value chain.
                                                                            exercise, are summarised in several key conclusions
                                                                                                                                    SusChem’s Working Group on Materials Technologies
                                                                            and recommendations within this document.                                                                                        2	Developing the necessary skills for successful
                                                                                                                                    together with the above mentioned input of key industry
                                                                                                                                                                                                                integration of composites in new vehicles
                                                                                                                                    stakeholders, understands the need to provide direct
                                                                                                                                                                                                                by automotive designers and engineers, as
                                                                                                                                    input to the Horizon 2020 agenda for 2016-17. A set
                                                                                                                                                                                                                well as facilitating the transfer of composites’
                                                                                                                                    of specific challenges is defined, with the purpose of
                                                                                                                                                                                                                knowledge to such designers and engineers.
                                                                                                                                    presenting a credible package of R&D&I topics that
                                                                                                                                    can remove barriers through cooperation between                          3	Establish training programmes that can instil the
                                                                                                                                    materials and vehicle actors. Some of the identified                        necessary skills into the workforce across the
                                                                                                                                    examples of the most critical needs for research                            value chain of automotive design, production,
                                                                                                                                    towards an accelerated implementation of advanced                           assembly and end-of-life, e.g. modelling and
                                                                                                                                    composite materials include:                                                simulation, safety, composites processing and
                                                                                                                                                                                                                assembly, LCA and materials recycling, etc.
                                                                                                                                         ovel and innovative polymer composite raw
                                                                                                                                         N                                                                   4	The unification and simplification of design tools,
                                                                                                                                         materials with enhanced recyclability properties.                      starting from material models and reaching
                                                                                                                                                                                                                simulation and vehicle design tools.
                                                                                                                                          ow cost adaptive, flexible and efficient
                                                                                                                                         L
                                                                                                                                         manufacturing and assembly processes specific
                                                                                                                                         to the high-volume automotive industry.
                                                                                                                                         
                                                                                                                                         Multi-attribute design optimization that works even
                                                                                                                                         in case of a multi-material architecture.
                                                                                                                                         
                                                                                                                                         Automated joining techniques for multi-materials
                                                                                                                                         and composites (foreseen in 2015 call).
                                                                                                                                         
                                                                                                                                         Invisible damage identification and repair
                                                                                                                                         techniques for composite parts.

     7 — http://www.rolandberger.com/press_releases/lightweight_can_stipulate_electric_car_development.html                         9 — http://www.egvi.eu/uploads/Modules/Publications/ppp-egvi-roadmap-oct2013.pdf
     8 — http://www.suschem.org/publications.aspx                                                                                   10 — http://www.earpa.eu/docs/2005/furore_road_map_final.pdf
13

               This chapter is intended as a primer for those who are not experts in the field of materials technology. It provides
               a basis for the discussion in the following chapters about the prospects and challenges of composites in the

Introduction
               automotive industry. As such, those working in the industry who are already familiar with the content presented
               here, can skip to the next chapter.

    1
                 1.1 Overview of polymer composites
               Polymer composites are materials defined by the combination of a polymer matrix (resin, either thermoset
               or thermoplastic) and a reinforcing agent, mainly fibres (usually carbon, glass or natural fibres). As a result,
               they are often referred as Fibre-Reinforced Plastics (FRP). In addition, FRP composites may contain fillers,
               modifiers and additives that modify the properties and improve the performance of the composite material,
               contributing to cost reduction.

               Fig.1 – Overview of polymer composites.

                                                                                                           Thermoplastics: PE, PP, PVC,
                                                                                                               PA, ABS, PEEK, etc.
                                                                     Matrices (resins)
                                                                                                           Thermosets: polyester, epoxy,
                                                                                                           phenolic, urethane, vinyl ester

                                                                                                                      Carbon

                                                                  Reinforcements (fibres)                              Glass

                                                                                                              Others: aramid, natural
                     Fibre-reinforced plastics (FRP)

                                                                Fillers: inorganics (calcium
                                                              carbonate, feldspar, silica, etc.)

                                                                  Additives and modifiers:
                                                                 catalysts, foaming agents,
                                                                antioxidants, colorants, etc.

               FRP composites are anisotropic instead of isotropic               The exact composition of FRP composites depends
               like steel and aluminium. Whereas isotropic materials             on each intended use according to many criteria. Both
               present uniform and identical properties in all directions,       the type and quantity of the constituent materials as
               FRP composites are directionally dependent, meaning               well as the manufacturing process used will affect
               that the best mechanical properties are in the direction of       the properties of the final composite. Overall, the
               the fibre placement. In many structures and components,           most relevant factors to consider for the design
               stresses and loads are different for different directions.        of composites include the fibre (type, volume and
               As a result, FRP composites allow a more efficient                orientation), type of resin, service conditions, the cost
               structural design. Other benefits include a low weight,           of the product, the manufacturing process and the
               high strength-to-weight ratio, corrosion and weather              volume of production.
               resistance, long-term durability, low maintenance and
               dimensional stability.
14    1            Polymer composites for automotive sustainability
                   Introduction
                                                                                                                                                                                                                                                                                15

                                                                                                                                     Thermoplastics: the next big composite development?
        1.2	Resins: Thermosets, thermoplastics and bio-based resins
                                                                                                                                     Thermoplastics are currently facing barriers                          Back in 2012, BASF announced two partnerships
     The primary functions of the resins are to transfer the          sources. Thermoset based composites account for                that thermoset composites have largely overcome,                      to develop automotive thermoplastic composites:
     stress and load between the fibres, to act as adhesives          about 60% of the total composites market. Bio-based            including a lack of familiarity, established design                   one with SGL3, based on caprolactam formulations
     that bond structural fibres firmly in place, and to              resins do not bring specific properties, but can possibly      codes, properties database, and proven production                     which will permit shorter processing cycles than
     protect the fibres from environmental and mechanical             influence the emissions balance/ environmental impact          technologies, etc. Investment has favoured                            conventional thermosetting RTM process, and
     damage. Bio-based resins refer to thermoset or                   of the materials.                                              reinforced thermosets instead of thermoplastics                       another with TenCate and Owens Corning4, focused
     thermoplastic resins that are obtained from natural                                                                             because the latter are considered as higher risk.                     on UD-tapes, prepregs and laminates. DSM has also
                                                                                                                                     However, the advantages of using thermoplastics                       started to offer a range of thermoplastic composites
     1.2.1 Thermoset resins                                                                                                          include shorter and more consistent cycle times                       based on polyamide resins for weight reduction of
                                                                                                                                     as well as the potential to more easily achieve                       automobile body, chassis parts and semi-structural
     Thermoset resins are usually liquids or low melting              and epoxy. Unsaturated polyester resin matrices
                                                                                                                                     post-life recycling.                                                  components5. Also Teijin announced the launch
     point solids in their initial form before curing. That           reinforced by glass fibres make up 80% (by weight)
                                                                                                                                                                                                           of Sereebo-brand CFR thermoplastic for use in
     allows for the convenient impregnation of reinforcing            of the thermoset based composites market. Vinyl                Recent developments confirm that reinforced
                                                                                                                                                                                                           manufacturing recyclable composite components
     fibres and ease of manufacturing. Thermoset resins               esters present superior physical properties (strength,         thermoplastics could indeed be the next wave1.
                                                                                                                                                                                                           at enhanced production speeds6. Lanxess also
     also present other desirable properties, including               durability) than polyesters, but are more expensive.           BMW’s i3 is the first mass-produced car to have
                                                                                                                                                                                                           acquired Bond Laminates, a producer of fully
     excellent resistance to solvents and corrosives, tailored        Epoxies present distinct advantages, including good            a thermoplastic exterior skin. Thermoplastic
                                                                                                                                                                                                           consolidated composite sheets with thermoplastic
     elasticity, excellent finishing and adhesion, resistance         electrical properties, long shelf life and excellent           wheel rims have also entered the market. BASF
                                                                                                                                                                                                           matrices7.
     to heat and high temperature. However, they cannot be            moisture and chemical resistance and provide high              introduced thermoplastic wheel rims reinforced with
     reshaped or remoulded. Through a catalytic chemical              thermo-mechanical properties.                                  long glass fibres in 2011, while Sabic, Kringlan
     reaction, the thermoset resin cures from liquid to                                                                              Composites and other industrial partners are
                                                                      To produce bio-based polyester resins, combinations
     solid, creating extremely strong bonds that cannot                                                                              developing the world’s first CF reinforced
                                                                      of diols and diacids are used to form the polyester resin
     be easily reversed or reformed. Because of this, the                                                                            thermoplastic (polyetherimide) composite wheel
                                                                      base, which is then further processed into polyester
     performance of this matrix material is superior to other                                                                        for a German automotive company2.
                                                                      resins. To produce bio-based epoxy resins, vegetable
     matrices; nevertheless recycling of thermoset resins
                                                                      oils can be epoxidised to form a reactive component,
     remains challenging.                                                                                                            1 — http://www.reinforcedplastics.com/view/39477/reinforced-thermoplastics-the-next-wave/
                                                                      which is further processed to become epoxy resins. A
                                                                                                                                     2 — http://www.plasticstoday.com/articles/worlds-first-thermoplastic-composite-wheel-polyetherimidecarbon-fiber-combination-140616a
     The most common thermoset resin used today                       number of chemical companies already offer diverse             3 — http://www.reinforcedplastics.com/view/28629/basf-and-sgl-to-develop-carbon-fibre-thermoplastics-for-automotive-applications/
     is unsaturated polyester, followed by vinyl ester                bio-based products on the market.                              4 — http://www.reinforcedplastics.com/view/31270/owens-corning-joins-tencate-basf-alliance-for-thermoplastic-automotive-composites/
                                                                                                                                     5 — http://www.dsm.com/products/ecopaxx/en_US/press-releases/2013/09/2013-09-10-dsm-launches-solutions-in-advanced-
                                                                                                                                          thermoplastic-composites-for-lighter-and-more-sustainable-automotive-applications.html
     1.2.2 Thermoplastic resins                                                                                                      6 — http://www.compositesworld.com/news/teijin-introduces-sereebo-brand-for-coming-cfrtp-products
                                                                                                                                     7 — http://lanxess.com/en/corporate/media/press-releases/lanxess-leading-supplier-of-lightweight-technology-to-automotive-industry/?tx_
     Thermoplastic resins are solids at room temperature.             are polypropylene (PP), thermoplastic polyurethane                  editfiltersystem_pi1%5Bname%5D=&tx_editfiltersystem_pi1%5Bnews_date_start%5D=01.08.2012&tx_editfiltersystem_
     As a result, they are processed through a melt-freeze            (TPU), polyethylene (PE), polyamide (PA) and polyvinyl              pi1%5Bnews_date_end%5D=30.09.2012&tx_editfiltersystem_pi1%5Bmatrix_segment%5D=0&tx_editfiltersystem_pi1%5Bmatrix_
                                                                                                                                          business_unit%5D=0
     route: thermoplastic resins become soft when heated,             chlorides (PVC).11
     may be moulded or shaped in the heated viscous
                                                                      Thermoplastic resins can also be obtained from bio-
     state and will become rigid when cooled down.
                                                                      based sources. It should be noted that the (bio)-
     Typical melting temperatures range from 100ºC (PE)
                                                                      sourcing of a thermoplastic material is independent of
                                                                                                                                    1.3 Fibres: Carbon, glass and natural fibres
     to 400ºC (PEEK – Polyether ether ketone). Therefore,
                                                                      its end-of-life options: not all bio-based thermoplastics
     they are potentially easier to recycle. Besides this                                                                         The main function of fibres is to carry load along its                   classified according to length, which ranges from
                                                                      are biodegradable, while conventionally sourced
     reforming ability, it is important to highlight that many                                                                    length (not across its width) providing strength and                     3mm to 75mm or can be continuous. As a result, three
                                                                      materials could be biodegradable.
     thermoplastic resins have an increased impact                                                                                stiffness in one particular direction. Fibres can be                     main groups are identified: short fibres (3mm-10mm),
     resistance to comparable thermoset resins. In                                                                                placed with a specific orientation (typically 0º, +/- 45º                long fibres (10-75mm) and continuous (endless). This
     addition, thermoplastic resins allow for faster moulding                                                                     or 90º) to provide tailored properties in the direction                  paper mainly features the use of continuous fibres in
     cycle times because there is no chemical reaction                                                                            of the loads applied. As a result, the mechanical                        composite materials.
     in the curing process. Examples of thermoplastic                                                                             properties of most FRP composites are considerably
                                                                                                                                                                                                           GFRP (as a short fibre) is by far the largest group
     resins common in automotive composite applications                                                                           higher than those of un-reinforced resins.
                                                                                                                                                                                                           of materials in the composites industry, used in over
                                                                                                                                  Depending on the reinforcing fibre, FRP composites                       95% of the total volume of composites. As indicative
                                                                                                                                  can be divided into three groups: GRP or GFRP                            data for the reader, Europe is expected to manufacture
                                                                                                                                  (Glass-reinforced plastics, or Fiberglass), CRP or                       2.2Mn tonnes of GFRP in 2014, while global demand
                                                                                                                                  CFRP (Carbon-reinforced plastics) and NRP or NFRP                        of CFRP is estimated at 79 000 tonnes in 2014 (AVK
                                                                                                                                  (Natural fibre reinforced plastics). Fibres can also be                  – CceV, 2014).

     11 — Plastics Europe, 2013, “The world moves with plastic”
16    1            Polymer composites for automotive sustainability
                   Introduction
                                                                                                                                                                                                                                                                    17

     1.3.1 Carbon fibres (CF)
                                                                                                                                              1.4 Processes: a comparative overview
     Carbon fibres, also known as graphite fibres, can be                     tows to chopped fibres and mats. The main benefits of
     based on three chemical sources: polyacrylonitrile                       carbon fibres include their low density and hence high        A thorough understanding of the available composite          production volume and rate, geometry and size of
     (PAN method that is led by Japanese manufacturers),                      strength-to-weight ratio and stiffness; however its main      manufacturing processes and their advantages,                the product, economic targets, surface complexity,
     rayon (such as from the Indian manufacturer Grasim)                      downsides, compared to other fibres, are its cost and         downsides and limitations will allow the selection of        materials and performance requirements.
     or petroleum pitch. About 90% of the carbon fibres                       brittleness.                                                  the most efficient. Some of the key factors include
     produced are made from PAN. The exact composition
                                                                              At 46 500 tonnes, global annual demand for CF
     of each precursor varies according to the recipe                                                                                       Fig. 2 – Overview of manufacturing processes.
                                                                              in 2013 has seen a growth of 15.1% CAGR since
     of the manufacturers. Whereas PAN-based fibres
                                                                              2009 (26 500 t). Global demand of CF is estimated to
     offer excellent mechanical properties for structural
                                                                              continue to grow reaching 71 000 t in 2018 and 89 000
     applications, pitch fibres present higher modulus                                                                                                                                                                                     Hand Lay-up
                                                                              t by 2020. Regarding production capacities, the most
     values and favourable thermal expansion coefficients.
                                                                              important regions are North America (30%), Europe                                                                Open Moulding                                 Spray-up
     Carbon fibres are usually grouped according to the
                                                                              (24%) and Japan (20%). The top five CF manufacturers
     modulus band in which their properties fall and are                                                                                                                                                                                Filament Winding
                                                                              according to production volumes in 2013 were Toray,
     supplied in different forms, from continuous filament
                                                                              Zoltek, Toho, MRC, SGL, in that order.
                                                                                                                                                                                                                                      Compression moulding

     1.3.2 Glass fibres (GF)                                                                                                                                                                                                                Pultrusion
     Glass fibre is based on an alumina-lime-borosilicate                     When referring to GFRP applied to the automotive
     composition. The recipe can be varied resulting in                       sector, it is important to define two typical processes:            Manufacturing processes                                                          Reinforced Reaction Injection
                                                                                                                                                                                                                                         Moulding (RIIM)
     different commercial compositions: E-glass (electrical),                 Sheet Moulding Compound (SMC) and Bulk Moulding                     for composites
     C-glass (chemical), R-glass, S-glass, and T-glass.                       Compound (BMC). Together this is by far the largest
                                                                                                                                                                                             Closed Moulding                      Resin Transfer Moulding (RTM)
     E-glass accounts for 90% of the GF market and is                         area of the total composites market: European
     often used in a polyester matrix offering high electrical                production in this area alone (estimated in 264 000 t                                                                                                   Vacuum Bag Moulding
     insulation properties, low susceptibility to moisture                    for 2014) is significantly larger than the global CFRP
     and high mechanical properties. C-glass GF presents                      market (estimated in 79 000 t for 2014). Whereas                                                                                                     Vacuum Infusion Processing
     the best resistance to chemical attack, while S-glass                    SMC is manufactured by compression moulding of
                                                                                                                                                                                                                                       Centrifugal Casting
     has higher strength, heat resistance and modulus.                        long chopped fibres in thermoset resins, BMC uses
     Overall, GFRP exhibit very good thermal insulation and                   chopped fibres and injection or compression moulding.                                                                                                   Continuous Lamination
     electrical properties and are also transparent; however,                 As a result, the longer fibres in SMC result in better
     they are heavier than CF and due to the lower modulus,                   strength properties than standard BMC components.
     they require special design treatment in applications
     where stiffness is critical.                                                                                                           There are two main categories of manufacturing               part. Open moulding can create very large parts, with
                                                                                                                                            processes: open moulding and closed moulding.                the only restriction to size being the ability to handle
                                                                                                                                            Whereas in open moulding the gel coat and laminate           the part. They are labour intensive, low volume but
     1.3.3 Natural fibres (NFs)
                                                                                                                                            are exposed to the atmosphere during the process due         low cost processes, where emissions can become an
     Natural fibres can also reinforce composites. Natural                    environmental footprint than carbon or glass fibres,          to the use of a one-sided mould, in closed moulding the      issue. On the other hand, closed moulding can offer
     fibres are fibres extracted from the fruits, stems and                   which can help automotive OEMs meet stringent                 composite is processed either in a two-sided mould           new strategies to meet emission standards. Additional
     leaves of specific plants. Dominant natural fibres                       end-of-life directives. In 2012, more than 124 000            set or within a vacuum bag. Open moulding and hand           benefits include: ability to make superior parts in a
     include flax, hemp, kenaf and jute. These are combined                   tonnes12 of natural fibre composites were shipped for         lay-up are the most common and widely used methods           consistent manner and higher volumes, reduction of
     mostly with polypropylene (also polyethylene) by                         automotive purposes globally.                                 to manufacture FRP. With open moulding, products             labour costs and finishing work, lower scrap rate, and
     compression or injection moulding.                                                                                                     are manufactured from the exterior to the interior of the    automation of parts with fewer moulds.
                                                                              However, the low impact resistance of NFs and the
     The automotive industry has been using more and                          moisture degradation that they face have been a
     more natural fibre reinforcements in the interior                        limiting factor in their uptake by the automotive industry,
     parts of vehicles as an alternative to glass fibres as                   as usage in structural applications is mostly targeted
     a light-weighting solution. NFs come from natural                        by the OEMs. R&D efforts are focused on improving
     and renewable sources and thus have a smaller                            these two aspects in NFs.

     12 — http://www.lucintel.com/LucintelBrief/Lucintel-brief-Opportunity-and-Challenges-in-Automotive-Composites-Industry.pdf
18   1                                             Polymer composites for automotive sustainability
                                                   Introduction
                                                                                                                                                                                                                                                                                                              19

     The table below presents an overview of the most typical manufacturing processes and the production volumes                                                               In recent years, more and more parts are being manufactured from composite materials, replacing traditional
     that they are suitable for.                                                                                                                                               materials in the process. The table below presents an overview of some examples of composites applied to
                                                                                                                                                                               automotive components in the market of the past five years.
     Table 1 – Comparison between manufacturing processes according to production volumes enabled.
                                                                                                                                                                               Table 2 – E
                                                                                                                                                                                          xamples of composite components applied to automotive.
                                                                                           Production Volume                                                                             (Sources: Lucintel, Alfa Romeo, Adler Plastics, Amber Composites).
      Process
                                                                                           Low ( parts)
                                                                                                                                                                               OEM-Model                       Application                         Material                     Year
      Compression Moulding
                                                                                                                                                                               BMW i3                          Passenger cell                      CFRP                         2013
      Bulk Moulding Compound (BMC)/
                                                                                                                                                      X
      Sheet Moulding Compound (SMC)                                                                                                                                            BMW i8                          Passenger cell                      CFRP                         2014

      Liquid Composite Moulding (LCM)                                                                                    X                                                     Alfa Romeo 4C                   Chassis                             Prepreg (CF, epoxy)          2013

      Injection Moulding                                                                                                                                                       Alfa Romeo 4C                   Outer body                          SMC                          2013

      Reinforced Reaction Injection Moulding (RRIM)                                                                                                   X                        Alfa Romeo 4C                   Bumpers and mudguards               CF + PUR-RIM                 2013

      Structural Reaction Injection Moulding (SRIM)                                                                                                   X                                                                                            CF monocell,
                                                                                                                                                                               McLaren MP4-12C Spider          Car roof, chassis, bodywork                                      2013
      Vacuum Infusion Processing (VIP)                                                     X                             X                                                                                                                         lightweight CF body panels

      Resin Transfer Moulding (RTM)                                                        X                             X                                                     BMW M6 convertible              Roof compartment cover, trunk lid   GFRP                         2013

      Filament winding                                                                                                   X                                                     BMW M6 Coupe                    Car Roof                            CFRP                         2012

      Pultrusion                                                                                                                                      X                        Daimler Smart
                                                                                                                                                                                                               Wheel rims                          GFRP                         2012
                                                                                                                                                                               3rd generation electric
      Prepregs + autoclave                                                                 X
                                                                                                                                                                               Callaway Corvette               Body aerodynamics Kit               CFRP                         2012

                                                                                                                                                                               Lexus LFA                       Cabin, floor, roof, pillars, hood   CFRP                         2012
        1.5	M ilestones and recent examples of composites                                                                                                                  Lamborghini Aventador LP700-4
                                                                                                                                                                                                               Front and rear bumpers,
                                                                                                                                                                                                                                                   CFRP                         2012
                                                                                                                                                                                                               body aerodynamics kit
               applied to the automotive sector                                                                                                                                                                Instrument panel,
                                                                                                                                                                               Land Rover – Evoque                                                 GFRP                         2011-12
                                                                                                                                                                                                               inner door modules
     Fig. 3. – “Composites in automotive applications” timeline.
                                                                                                                                                                               Faurecia Jeep Liberty SUV       Door module                         GFRP                         2010

                                                                                                                                                                               Daimler AGT-Mercedes            Fluid filter module                 GFRP                         2009-10
                                                   1940s       Composites have a long track record in the automotive industry, dating back to the 1940s, when they were
                                                               first used as a material for car parts. The Stout 46 developed by Owens Corning and William Stout in 1945 is
                                                               acknowledged as the world’s first composite prototype car, with a fiberglass body shell and air suspension.     Furthermore, carmakers are specifically targeting some              housing, load floor, deck lid, air duct, airbag housing,
                                                                                                                                                                               car parts with more potential for development with                  front end module, engine cover.
                                                   1950s       In 1953, MGF launched the first production model with fiberglass body panels: Chevrolet Corvette.
                                                               Regarding CF, it wasn’t until the late 1950s that high tensile strengths CF were discovered,                    composites: chassis, exterior and interior. This includes
                                                                                                                                                                                                                                                   CFRP: chassis / monocoque, roof, tailgate, hood, floor
                                                                                                                                                                               the following parts and components, as examples:
           Composites in automotive applications

                                                               with rayon being the first precursor.
                                                                                                                                                                                                                                                   panel, side panels, trunk lid, hood frame, fender, rear
                                                   1960s       The 1960s saw the discovery
                                                                                                                                                                               GFRP: interior headliner, underbody system, air intake              spoiler, bumper.
                                                               of the SMC process.
                                                                                                                                                                               manifold, instrument panel, bumper beam, air cleaner
                                                   1981        The McLaren MP4/1 (1981) was the first F1 car
                                                               to use a CF composite monocoque.

                                                   1984        But it was not until 1984 that it was applied to a high-volume car:
                                                               the Pontiac Fiero, with body panels made from SMC.

                                                   1980s       Some supercars have incorporated CFRP extensively
                                                               (monocoque chassis and other components).

                                                   1990s       However, only recently the material began to be used,
                                                               albeit in limited quantities, in mass-produced cars.

                                                   2013        The i3 model by BMW (2013) represents the automotive world’s first
                                                               attempt at mass-producing CF.
21

                       2.1 Supply: the European automotive composites value chain

The market
                    The automotive composites value chain is currently               From 2009 onwards, the industry has seen numerous
                    undergoing a major redesign. Composites in the                   automotive manufacturers partner with composite
                    automotive sector have in the past enjoyed considerable          suppliers. To meet the high volume requirements,
                    success in Formula 1 motorsport and in the supercars             currently hampered by high material costs, long

and opportunities
                    segment. This has created a fragmented support                   production cycles and lack of automation, as well
                    industry, consisting of numerous and diverse small               as industrialising manufacturing to meet emissions
                    high-tech players with specialised knowledge. In recent          regulations, Tier 1 suppliers and OEMs have adopted
                    years, CFRP usage is cascading from these high-                  different strategies to allow vertical integration of the
                    end luxury segments down to higher volume vehicles.              value chain. This includes: partnerships, joint ventures
                    Composites suppliers need to upgrade their capabilities          and acquisitions. Examples of these strategies are
                    and translate their expertise into higher volume                 provided below.
                    segments. This lack of experience and industrialisation
                    in producing mainstream composites will drive OEMs to
                    look for reliable suppliers who can provide an increasing
                    proportion of the composites value chain.

                    Table 3 – S
                               trategies from OEMs and Tier1 suppliers to allow vertical integration in high volume automotive composites.
                              (Sources: Lucintel, Ricardo).

          2
                     Strategy             Companies involved                                   Goal
                                                                                               Accelerate industrialisation of CRP, develop
                                          BASF + SGL Carbon
                                                                                               processing times suitable for mass production.
                                                                                               Develop a new CF material for mass
                                          Toray + Nissan, Honda
                                                                                               production market.

                     Partnership          GM + Teijin                                          Develop technology to improve fuel economy.

                                                                                               Develop cost-effective composites automotive
                                          JRL + Cytec
                                                                                               structures for high-volume production.
                                                                                               Use CFR in high-volume vehicles
                                          Ford + Dow Automotive
                                                                                               to improve fuel efficiency.
                                                                                               Supply semi-finished CF products exclusively
                                          BMW + SGL Carbon
                                                                                               to BMW.
                                          Daimler + Toray                                      Manufacture automotive CFRP parts.
                                                                                               Cost-efficient solutions of fibre-composites
                     JVs                  SGL Group + Benteler Automotive                      components, from the initial design
                                                                                               to series production.

                                                                                               Production of high-performance materials
                                          SGL Group + Kümpers GmbH                             from carbon, glass and aramid fibres for the
                                                                                               composites industry.

                                                                                               Sora Composites had an automotive business unit,
                                          Faurecia acquired Sora Composites                    with expertise in glass and carbon fibre
                                                                                               for automotive applications.
                     Acquisition
                                                                                               Mass production of fully consolidated thermoplastic
                                          Lanxess acquired Bond laminates                      composite sheets for Consumer Electronic, Sports
                                                                                               and Automotive business.
22   2            Polymer composites for automotive sustainability
                  The market and opportunities
                                                                                                                                                                                                                                                                                  23

     The graph below summarizes the value chain for automotive composites, indicating some of the diverse players                                   Fig. 5 – Indicative mapping of EU (automotive) composites hubs.
     previously described.                                                                                                                                    Brief descriptions of the various clusters can be found in Annex A

     Fig. 4 – Overview of the polymer composites value chain for automotive.
                                                                                                                                                       Composites Innovation Cluster                                                                Composites Centre Sweden
                                                                                                                                                       Hertfordshire, UK                                                                                        Lulea, Sweden
                  R&D institutes and centres of excellence: design, materials modelling and simulation, etc. (Swerea, TUM, KUL, IKA…)

                                                                                                                                                       AZL                                                                                                            LIGHTer
                                       Offer (materials)                                      Demand (materials)            Demand (components)
                                                                                              + offer (components)          + offer (vehicles)         Aachen, Germany                                                                                                Sweden

                                        Resins: DSM,
                                       Huntsman, BASF,
                                       Henkel, Dow, etc.                                                                                               ARENA 2036                                                                                      Open Hybrid Lab Factory
                                                                   Semifinished
                                                                 material (pre-pregs,            TIER 1, TIER 2:                                       Stuttgart, Germany                                                                                  Wolfsburg, Germany
              Raw materials,                                                                                                    OEMs: BMW,
                                                                   compounds):                    Benteler-SGL,
                 chemicals                                                                                                    Fiat, Daimler, JLR,
                                                                 Chomarat, Oxeon,                Magneti Marelli,
              (e.g. PAN, etc.)                                                                                                   Renault, etc.
                                                                  SGL Kumpers,                 Faurecia, Magna, etc.
                                                                    Hexcel, etc.                                                                       MAI Carbon                                                                                                     MERGE
                                         Fibres: SGL,                                                                                                  Augsburg, Germany                                                                                   Chemnitz, Germany
                                           DowAksa

                                                                            JVs: SGL-BMW, Toray-Daimler                                                IRT Jules Verne                                                                                                 IMAST
                                                                                                                                                       Nantes, France                                                                                             Naples, Italy

                                                                 Machine suppliers                              Machine suppliers

                                                                      Dieffenbacher,
                                                                                                                 Tooling, moulds,
                                                                       KraussMaffei
                                                                                                                  assembly lines,
                                                                      Group, Schuler
                                                                                                                  testing system,
                                                                     SMG, Hennecke,
                                                                                                                 equipment (e.g.
                                                                     Global Machine
                                                                                                                    Autoclave).
                                                                     Manufacturing…
                                                                                                                                                    The UK has also made moves that indicate its desire to             centre in Italy and the Composites Centre in Sweden,
                                                                                                                                                    step up to the composite challenge. The Composites                 show that European governments recognise the
                                                                               End of life: ELG Carbon Fibre, etc.                                  Innovation Cluster in Hertfordshire, a consortium of               importance of developing new ways of manufacturing
                                                                                                                                                    25 organisations includes the National Composites                  and using automotive composites for the future.
                                                                                                                                                    Centre (NCC), was founded in 2011. It entered
                                                                                                                                                                                                                       Furthermore, recent collaborative projects have
     2.1.1 European scientific and technical excellence                                                                                             Phase II in November 2014, with expanded facilities to
                                                                                                                                                                                                                       already seen research efforts bearing fruit. As Annex
                                                                                                                                                    better fulfil its function as a High Value Manufacturing
     In recent years, governments across Europe have                              operates several centres that involve collaborations                                                                                 B illustrates, many projects in the European Research
                                                                                                                                                    Catapult for the UK. Together with partners such as
     begun recognising the opportunities in automotive                            between the plastics, composites and automotive                                                                                      Framework Programmes (and continuing in the new
                                                                                                                                                    GE, Rolls-Royce, TenCate and the University of Bristol,
     composites. Large investments have been made to                              industries, academia and government. Munich-                                                                                         Horizon 2020 programme) have made significant
                                                                                                                                                    it coordinates a network of regional composite centres
     set up research centres, often in collaboration with                         Augsburg-Ingolstadt (MAI) Carbon was set up in                                                                                       advances in the fields of lightweighting vehicles
                                                                                                                                                    and supports the UK Composites Strategy that was
     universities and industry partners.                                          2007 at the suggestion of Carbon Composites                                                                                          using composite materials (TECABS, ENLIGHT), of
                                                                                                                                                    launched in 2009. It aims to improve aspects of
                                                                                  eingetragener Verein (CCeV). This was followed by                                                                                    developing composite components and methods for
     With the advances in the US and Japan, Europe                                                                                                  composite technology, manufacturing, and skills and
                                                                                  other centres such as Aachen Centre for Integrated                                                                                   use in mass production (HIVOCOMP) and in lowering
     needs to maintain its industrial leadership. Germany,                                                                                          training to ready the UK composites supply chain to
                                                                                  Lightweight Production (AZL Aachen) (2013), Hybrid                                                                                   the cost of carbon fibres and precursor materials
     recognised as one of the leading countries, already                                                                                            be competitive in meeting future global demands for
                                                                                  Open Labfactory (2013) and Arena 2036 (2013).                                                                                        (CARBOPREC, NEWSPEC, FIBRALSPEC).
                                                                                                                                                    skilled personnel, technologies and processes.
                                                                                                                                                                                                                       However, these centres and initiatives remain
                                                                                                                                                    Developments elsewhere in Europe, such as the Jules
                                                                                                                                                                                                                       independent and uncoordinated, reducing the
                                                                                                                                                    Verne Institut de Recherche Technologique (Jules
                                                                                                                                                                                                                       potential to create impact at an EU-wide level. Linking
                                                                                                                                                    Verne IRT) in France founded in 2012, the Ingegneria
                                                                                                                                                                                                                       them together could provide the impetus for faster and
                                                                                                                                                    dei Materiali polimerici e compositi e STrutture (IMAST)
                                                                                                                                                                                                                       bigger technological breakthroughs.
24    2              Polymer composites for automotive sustainability
                     The market and opportunities
                                                                                                                                                                                                                                                                                                         25

                                                                                                                                                            Recent federal initiatives are also encouraging for                         This federal initiative follows private initiatives. Aiming at
        2.2 Global outlook                                                                                                                                  advanced composites, including for automotive                               driving a transition to fossil-fuel-free US transportation
                                                                                                                                                            applications. From January 2015, the US Department of                       by 2050 via making cars lighter, the Rocky Mountain
     The investments of the past years have kept Europe                              that remain unconnected from each other. Harnessing
                                                                                                                                                            Energy will be investing $70 million, with a consortium                     Institute (RMI) launched the Autocomposites
     at the cutting edge of composite automotive                                     these various initiatives and spheres of expertise could
                                                                                                                                                            of 122 industry partners, universities and non-profit                       Commercialization Launchpad (ACL)14 in June 2013.
     technologies. However, the established centres are                              propel the industry forward in the coming decades of
                                                                                                                                                            organisations who themselves will be investing more                         The ACL has two key focus area: developing a
     often independent collaborations between private                                increased competition from other parts of the world,
                                                                                                                                                            than $180 million to launch an advanced composites                          commercialization project that unites the supply chain
     manufacturers, research institutions and government                             such as the USA and Japan.
                                                                                                                                                            manufacturing institute. OEM members of this initiative                     to incorporate a CFRP part on a mainstream vehicle
                                                                                                                                                            include Volkswagen, Honda and Ford. The institute,                          at the highest production volume ever achieved; and
     2.1.1 USA
                                                                                                                                                            headquartered in Knoxville, Tennessee, aims to lower                        setting an innovation hub focused on centralizing and
     The USA recognises the opportunities in the sector                              industries in close collaboration. The challenges that it              the manufacturing costs of advanced composites                              coordinating R&D and collaborative progress in the
     too. The Corporate Average Fuel Economy (CAFE)                                  aims to solve include mass manufacturing processes,                    for all applications, to reduce the energy needed to                        FRP industry.
     regulations released in 2012 aims to raise the average                          improving collaboration between different parts of the                 produce composites, and to improve their recyclability.
     fuel efficiency of new cars and vehicles to 54.5 miles                          value chain and lowering the costs of composite parts.
     per gallon13 by 2025 to reduce national dependence on                                                                                                  2.2.2 Japan
                                                                                     Ultimately, implementing these priority actions would
     oil. This regulatory pressure means that the American
                                                                                     make the automotive composites players in the USA                      Japan is traditionally a strong automotive composite                        has invested about €300 million in its production
     automotive industry has to use solutions such as light-
                                                                                     work closely together to improve the USA’s position                    player. It is home to industry giants such as Toray, Teijin                 facilities for diverse products including automotive
     weighting to meet fuel efficiency targets.
                                                                                     in the world market. Lobbying organisations such as                    and Fuji Heavy Industries amongst others. As the need                       parts, not only in its Japanese production facilities but
     To that end, the American Chemistry Council published                           the Automotive Composites Alliance, established                        to develop new methods of mass production and lower                         also in its facilities in the US, France and South Korea.
     the “Plastics and Polymer Composites Technology                                 in 1988 to promote the use of composites, have                         costs became apparent, the National Composites                              In fact, it is notable that Japanese manufacturers are
     Roadmap for Automotive Markets” in March 2014. It                               members such as Huntsman and Owen Cornings and                         Center was established at Nagoya University in 2013                         turning increasingly to foreign collaborations, joint
     outlined nine priority actions to establish composites                          represent industry interest and potential participation                as a triple helix research institute. It aims to develop and                ventures and takeovers to bolster their own capacities.
     as the preferred automotive material by 2030, bringing                          in such policies.                                                      commercialise new processes of CFR thermoplastic                            Besides the aforementioned investment, Toray took
     together the automotive, plastics and composites                                                                                                       components.                                                                 over Zoltek Inc for €468 million to be ready for the
                                                                                                                                                                                                                                        surge in demand for low-cost carbon fibre precursors.
                                                                                                                                                            Japanese chemical companies have also been actively
     Fig. 6 – ACC Roadmap                                                                                                                                                                                                               Teijin has also invested millions in Michigan to develop
                                                                                                                                                            expanding domestically and abroad. The Toray group
                                                                                                                                                                                                                                        new carbon fibre technologies in partnership with GM.

          Industry-Wide Demonstrations                     4	Establish design guidelines (e.g., for wall     Continued Materials Development
                                                              thickness, radii) and tools for typical plas-
            Establish an independent, pre-compet-
          1	
            itive technology development center
                                                              tic and polymer composite structures that         Support development of engineered
                                                                                                              8	
                                                                                                                plastics and polymer composites with
                                                                                                                                                               2.3 Market demand: CRP/GRP trends
                                                              are intended to be used by design engi-
            where OEMs and suppliers can conduct              neers                                             improved properties (e.g., stiffness,
            laboratory work and test concepts at                                                                strength, fatigue, environmental resis-
            small volumes while collecting standard-       5	Develop models that can simulate the be-          tance, creep, energy management, tem-       Fig. 7 – Global FRP shipments by market segments. (Source: Lucintel)
            ized data                                         havior of plastic and polymer composite           perature capability), and develop per-
                                                              materials and components during and               formance standards to characterize the
          2	Develop generic cost models to demon-            after impact events                               properties for designers                       Global composite materials distribution         Global composite materials shipment
             strate the cost and benefit of plastics and
                                                                                                                                                               ($ mil) by market segments in 2017              ($ mil) by market segments in 2017
             polymer composites compared to alter-         Manufacturing & Assembly                           Supporting Initiatives
             native materials as examples to provide
                                                           6	Develop a manufacturing center or con-         9	Advocate for plastics and polymer com-
                                                                                                                                                                                                                                               29,928                           Transportation
             mass reduction possibilities
                                                               sortium to advance high-speed polymer             posites training classes and degree pro-
          Material Selection & Part Design                     composites processing                             grams at all major universities                                                                                                       4,284                    Marine
            Define a standard package of material
          3	                                              7	Develop technically and economically vi-
            properties desired for automotive appli-           able techniques to join plastics and poly-                                                                  7% 3 %       14 %                                                           851                      Wind energy
            cations, and then test the data through            mer composites to similar or dissimilar
            simulation for a specific automotive sys-          materials and study service, repair, and                                                                                         3%                                  19,650             4,056                    Aerospace
            tem (e.g., engine mounts, instrument pan-          disassembly                                                                                        17%
            el, cross-car beams)                                                                                                                                                                                                2,804
                                                                                                                                                                                                 14 %                                                  4,432                    Pipe & tank
                                                                                                                                                                                                                                 521
                                                                                                                                                                                                                                2,398                  3,631                    Construction
                                                                                                                                                                   16 %                                                         2,318
                                                                                                                                                                                             15 %                                                      4,775                    E&E
                                                                                                                                                                                                                                2,642
                                                                                                                                                                               12 %

                                                                                                                                                                                                             Shipment ($ mil)
                                                                                                                                                                                                                                3,366                  4,956                    Consumer goods
                                                                                                                                                                                                                                3,689
                                                                                                                                                                                                                                                       2,145                    Others
                                                                                                                                                                                                                                1,322
                                                                                                                                                                                                                                 591                   798
                                                                                                                                                                                                                                        2011    2017

     13 — Environmental Protection Agency and Department of Transportation, 2017 and Later Model Year Light-Duty Vehicle Greenhouse Gas
           Emissions and Corporate Average Fuel Economy Standards; Final Rule, 77 Fed. Reg. 62623 (Oct. 15, 2012).                                          14 — http://www.rmi.org/autocomposites
26    2             Polymer composites for automotive sustainability
                    The market and opportunities
                                                                                                                                                                                                                                                                                              27

     The global automotive composite materials sector is                       market segments with the lowest composites                           Fig. 9 – Left: Carbon composite revenues in US$ billion by matrix material (2013).
     expected to reach US$4.3Bn (€3.7Bn) by 2017, up                           penetration (3.6%) in comparison to competing                                  Right: CFRP market share in US$ million by manufacturing process (2013).
     from US$2.8Bn (€2.41Bn) in 2011, at a compound                            materials such as aluminium or steel (see Fig. 8). The                         (Source: AVK – CceV, 2014).
     annual growth rate (CAGR) of about 7%15.                                  above numbers state clearly the great opportunity
                                                                               that lies in the mass application of composites in the
     This is partly due to the fact that today, transportation                                                                                                           Total: US$ 14.7 billion                                         Total: US$ 9.408 billion
                                                                               automotive sector.                                                                                                                                                                                   3810
     and specifically automotive stand as one of the largest                                                                                                                                                                                                                Pultrusion and
                                                                                                                                                        9.41                                                                                                                       winding
                                                                                                                                                      Polymer
     Fig. 8 – Composites penetration in different market segments, compared to competing materials (St, Al). (Source: Lucintel).                                               5%                                                                  4%
                                                                                                                                                                         8%                                                                 7%                                      3434
                                                                                                                                                       1.98                                                                                                                  Prepreg layup
                                                                                                                                                      Carbon                                                                                                                      process
                                                                                                                                                                                                                                    12 %
                                                           Structural                                                                                             10 %                                    24 %                                                                with/without
                                                                                                                                                                                                                                                                                 autoclave
                                  Composite                Materials Market    Composites            Performance                                                                                                                                                     40 %
           Market Segment                                                                                                      Price Gap                1.47
                                  Materials Market         (Steel, Al &        Penetration           Gap
                                                                                                                                                     Ceramic                                                                                                                        1176
                                                           Composites)
                                                                                                                                                                  13 %                                                                                                       wet lamination
           Transportation         $2.8 B                   $77.8 B             3.6%
                                                                                                                                                                                                   64 %                                                                          & infusion
                                                                                                                                                        1.10                                                                                                                    processes
                                                                                                                                                        Metal
                                                                                                                                                                                                                   76 %
           Marine                 $0.5 B                   $0.8 B              68%
                                                                                                                                                                                                                                          37 %                                       612
                                                                                                                                                                                                              7.15                                                               Pressing
           Aerospace              $2.3 B                   $23.2 B             10%                                                                      0.74                                                                                                                    & injection
                                                                                                                                                                                                              Thermosets
                                                                                                                                                       Hybrid                                                                                                                   processes
           Pipe & tank B          $2.6 B                   $37.8 8             7%                                                                                                                             2.258
                                                                                                                                                                                                              Thermoplastic                                                           376
           Construction           $3.4 B                   $85.1 B             4%                                                                                                                                                                                                  Others

           Wind Energy            $2.4 B                   $6.4 B              38%

           Consumer Goods         $1.3 B                   $9.4 B              14%                                                                  As far as automotive and transportation applications are              construction and industry is a key factor driving
                                                                                                                                                    concerned (excluding aerospace and defence), these                    the market. In the automotive sector, revenues are
          Consumer Goods                                                                                                                            are increasingly important to the carbon composites                   expected to grow by 7% annually until 2018. By 2022,
          Wind Energy                                                                                                                               market with US$2.2Bn (€1.89Bn) in revenues in 2013.                   annual global carbon composite revenues are forecast
          Construction
                                                                                                                                                    Cars are the main sub-segment (46%, US$1.014Bn,                       to reach US$4.9Bn (€4.21Bn) corresponding to 20
                                                                                                                                                    €0.87Bn), where their use is now restricted primarily to              000 tonnes of carbon fibre. Automotive applications
          Pipe & tank
                                                                                         Total Market Potentia ($ B) Composite                      luxury cars due to the high cost of carbon composite                  are set to rise to second place ahead of wind turbines
          Aerospace                                                                                                                                 components. The growing use of CFRP in automotive,                    in the table of market segments.
                                                                                         Materials Market Size ($ B)
          Marine
          Transportation                                                                                                                            Fig. 10 – Left: Carbon composite revenues in US$ million in the automotive sector according to sub-segment (2013).
                                                                                                                                                               Right: Carbon composites revenues outlook in the automotive market segment (US$ million).
          US$ Billion         0.00         10.00         20.00         30.00   40.00         50.00     60.00           70.00        80.00   90.00              (Source: AVK – CceV, 2014).

     This chapter analyses trends within the carbon and glass-fibre reinforced market.
                                                                                                                                                                                                                                                                               4884
                                                                                                                                                                                                          1014
     2.3.1 Carbon composites and the CFRP market                                                                                                                                                          Cars
                                                                                                                                                                    8%                                                                                                3874
     In 2013, global demand for CFRP was around 72                             Two manufacturing categories make up the majority of
                                                                                                                                                           13 %                                           397
     000 tonnes, generating revenues of US$7.56Bn                              the CFRP market, with pultrusion and filament-winding                                                                      Trucks                                              3070
     (€6.5Bn). CFRP represented 64% of the total carbon                        accounting for 40% of the market and prepreg layup                                                                                                                   2689
     composites market, accounting for US$14.7Bn                               process with and without autoclave accounting for                                                        46 %              331                     2205 2357
     (€12.64Bn). Growth in CFRP consumption is forecast                        37%. North America has a 34% share (US$5.07Bn,                           15 %
                                                                                                                                                                                                          Motorsport
     to continue at 10.6% until 2020 to reach a demand                         €4.36Bn) of the CFRP market, closely followed
     of 146 000t and revenue of US$16Bn (13.75Bn).                             by Western Europe with a 32% share (US$4.7Bn,                                                                              287
     Within CFRP, thermosetting plastics have a more                           €4.04Bn) and Japan with a 15% share (US$2.21Bn,                                                                            Passenger trains

     established market position, accounting for 76% of the                    €1.9Bn).                                                                           18 %
     revenues (US$7.15Bn, 6.15B), with the remaining 24%                                                                                                                                                  176
                                                                                                                                                                                                          Others                  2013      2014     2016     2018    2020      2022
     accounting for thermoplastics (US$2.258B, €1.94Bn),
     with polypropylene, polyurethane and polyamide
     thermoplastics accounting for a large part of this.

     15 — http://www.lucintel.com/lucintel-globalcompositemarketanalysis-acma2012-educationalsession.pdf
28    2            Polymer composites for automotive sustainability
                   The market and opportunities
                                                                                                                                          29

     2.3.2 Glass fibre composites and the GRP market
     EU production of GFRP in 2014 is estimated at                              sector), production and consumption is also shifting to
     2.2Mn tonnes (1.043Mn t if short fibre thermoplastics                      the BRIC countries.
     are disregarded)8, corresponding to a total value of
                                                                                Regarding GFRP distribution per application industry,
     US$5.093Bn (€4.4Bn)16.This value matches the
                                                                                the transport sector consumes one-third of total
     absolute level of 2004, illustrating that the level
                                                                                production (35%, about 357 000 t). The transport
     achieved before the economic crisis (1.195M t in
                                                                                sector includes road vehicles, railway locomotives
     2007) has not yet been regained. Focusing on that
                                                                                and rolling stock and boats and aircraft. Lightweight
     1.043M t, the vast majority (>85%) accounts for
                                                                                construction solutions, required to meet official CO2
     thermosetting materials, whereas a small share (11%)
                                                                                emissions standards, continue to be the principal
     represents other thermoplastic materials such as glass-
                                                                                market driver in vehicle construction. For automotive,
     mat reinforced thermoplastics (GMTs) and long fibre
                                                                                the worldwide suppliers of GFRP for the automotive
     reinforced thermoplastics (LFTs). Whereas relative
                                                                                market include Owens Corning, Millfield Group,
     growth is above average in some EU countries such as
                                                                                Vetrotex, Lanxess and Ahlstrom.
     Germany (automotive industry) and UK (construction

     Fig. 11 – L
                eft: GFRP production by volume in EU since 2004 (in ‘000 tones, SFT disregarded).
               Right: GFRP production in EU for different application industries (year 2013).
               (Source: AVK – CceV, 2014).

                                                                         1.132 1.195
                            1%                          1.041 1.065                    1.058          1.015 1.049 1.010 1.043 1.020
                15 %
                                                                                               815
                                           35 %

            34 %

                                    15 %
                                                         2004     2005   2006   2007   2008    2009   2010   2011   2012   2013 2014*

                                                                                                                             * estimate
               Transport
               Electro/Electronic
               Construction
               Sports & Leisure
               Others

     16 — Using the maximum price of €2/kg from Ignaas Verpoest for SusChem “Composites Materials Research Challenges”
31

                 Growth in the automotive composites market used                                                    and visual appearances in their vehicles. One example
                 to be driven by the need to reduce corrosion in metal                                              is the BMW M3. Especially in small series production,

The motivation
                 parts. However, metallic parts started to be coated in                                             composites have been a viable option due to the low
                 zinc to prevent rusting. Automotive manufacturers then                                             cost tooling and machinery needed to produce the
                 used composites for aesthetic reasons. Composite                                                   required composite parts. The premium price that
                 materials gave automotive manufacturers the                                                        these vehicles demand also allows manufacturers to
                 possibility to build parts with distinct shapes, textures                                          incorporate more expensive composite parts.

and drivers         3.1 Lightweighting
                 Fig. 12 – Automotive material mix (1975-2010)
                            (Source: Lucintel)

             3
                        Automotive Material Mix from 1975 to 2010                                                      Change in Materials Usage Per Vehicle
                        (Average Vehicle Weight in lbs)                                                                from 1975 to 2010 (in lbs)

                                                                                                                                                               Steel
                                                         3,900           3,694           3,924           4,040                  -598
                                                                                                                                                               High Strength
                                                                                                                                       419

                                                    57.6 %          46.8 %          44.4 %          40.8 %                      -348                           Iron

                    Average Vehicle Weight in lbs
                                                                                                                                       258                     Aluminium
                                                                     8.8 %          11.3 %          13.8 %
                                                     3.6 %                                           5.9 %                                                     Other Metals
                                                                    12.6 %           9.0 %
                                                    15.0 %                                           8.5 %                              57
                                                                     6.3 %           7.5 %
                                                                                     3.9 %           4.3 %
                                                     2.2 %           3.8 %                                                                                     Plastics & Composites
                                                     3.0 %                           7.8 %           9.4 %                                 199
                                                                     6.5 %
                                                     4.6 %
                                                    14.0 %          15.3 %          16.1 %          17.3 %                                154                  Other Materials

                                                             1975            1995            2002            2010

                 Today, lightweighting is a crucial factor leading to the                                           plastic composites are increasingly used. Due to
                 rapid expansion of the global automotive composite                                                 their lightness and stiffness, plastic composites are
                 market. Different lightweight materials have always                                                a feasible option to reduce vehicle weight. Reducing
                 been part of the automotive materials mix, but as shown                                            the weight of vehicles is gaining more and more
                 in Fig 12, high strength steel, aluminium and                                                      prominence due to the factors explained below.

                    3.2 CO2 Regulations
                 Firstly, European carbon emissions regulations will                                                method would be to reduce the vehicle’s weight
                 be lowering the permitted amount of emissions per                                                  using composite components. However, certain
                 kilometre, from below 130g/km CO2 in 2015 to                                                       OEMs have expressed their concerns at the planned
                 95g/km CO2 in 2021. A level of 68-75g/km CO2 is                                                    regulations as they are more stringent compared to
                 proposed beyond that, possibly by 2025 or 2030. This                                               other regions in the world, potentially leading to added
                 will be confirmed in 201517. This encourages OEMs to                                               costs in product or technology development.
                 improve the fuel economy of their car fleet. One possible

                 17 — http://ec.europa.eu/clima/policies/transport/vehicles/index_en.htm
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