Preparation for Organic Chemistry - ALEKS
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Preparation for Organic Chemistry This course covers the topics shown below. Students navigate learning paths based on their level of readiness. Institutional users may customize the scope and sequence to meet curricular needs. Curriculum (184 topics + 438 additional topics) General Chemistry Review (122 topics) Electrostatics (5 topics) Understanding that opposite charges attract and like charges repel Understanding net electrical charge Understanding how electrostatic f orces cancel Understanding how electrostatic energy scales with charge and separation Sketching polarization induced by a nearby charge Chemical Elements (4 topics) Understanding periods and groups of the Periodic Table Understanding main-group periodic trends in ionization energy Understanding main-group periodic trends in atomic radius Ranking the oxidizing power of halogens Atoms (6 topics) Identif ying the parts of an atom Counting protons and electrons in atoms and atomic ions Predicting the ions f ormed by common main-group elements Counting valence electrons in a neutral atom Counting valence electrons in an atomic ion Drawing the Lewis dot diagram of a main group atom or common atomic ion Chemical Compounds (4 topics) Counting the number of atoms in a f ormula unit Writing a chemical f ormula given a molecular model Writing a chemical f ormula given a chemical structure Understanding the prefixes used in naming binary compounds Ionic Compounds (3 topics) Predicting the f ormula of binary ionic compounds Identif ying common polyatomic ions Naming ionic compounds with common polyatomic ions Chemical Reactions (7 topics) Writing a chemical equation f rom a molecular movie Writing the net equation f or a sequence of reactions Using a chemical equation to find moles of product f rom moles of reactant Identif ying the limiting reactant in a drawing of a mixture Understanding theoretical, actual, and percent yield Identif ying precipitation, combustion and acid-base reactions Predicting products f rom a general statement about reactivity Solution Chemistry (3 topics) Identif ying the correct sketch of a compound in aqueous solution Writing net ionic equations Applying like dissolves like Acids and Bases (22 topics) Predicting the products of a neutralization reaction Identif ying acids and bases by their reaction with water Understanding the diff erence between strong and weak acids Identif ying Bronsted-Lowry acids and bases Identif ying strong or weak acids and bases f rom a sketch Finding the conjugate of an acid or base Predicting the products of the reaction of a strong acid with water Predicting the reactants of a neutralization reaction Predicting the qualitative acid-base properties of salts Identif ying Lewis acids and bases in reactions Naming inorganic acids Deducing the f ormulae of inorganic acids f rom their names Predicting the relative acidity of binary acids Understanding the eff ect of induction on acidity Page 1 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Calculating the pH of a strong acid solution Calculating the pH of a strong base solution Diluting a strong acid solution to a given pH Preparing a strong base solution with a given pH Writing an acid dissociation constant expression Determining the strength of acids f rom a sketch Calculating the Ka of a weak acid f rom pH Interconverting Ka and pKa Oxidation and Reduction (3 topics) Assigning oxidation numbers Recognizing reduction and oxidation Identif ying oxidizing and reducing agents Reaction Thermodynamics (0 topics) Using the general properties of reaction enthalpy Calculating the heat of reaction f rom bond energies Qualitatively predicting reaction entropy Using the Second Law to predict spontaneous change Using the general properties of Gibbs f ree energy Calculating dG f rom dH and dS Using the conditions of spontaneity to deduce the signs of ΔH and ΔS Recognizing consistency between statements about standard Gibbs f ree energy Quantum Mechanics (1 topics) Recognizing s and p orbitals Electronic Structure of Atoms (12 topics) Deciding the relative energy of electron subshells Calculating the capacity of electron subshells Knowing the subshells of an electron shell Interpreting the electron configuration of a neutral atom Writing the electron configuration of a neutral atom with s and p electrons only Writing the electron configuration of an atom or atomic ion with s and p electrons only Writing the electron configuration of an atom using the Periodic Table Identif ying quantum mechanics errors in electron configurations Identif ying elements with a similar valence electron configuration Predicting the relative ionization energy of elements Understanding periodic trends in atomic size Understanding periodic trends in atomic ionizability Atomic Spectroscopy (5 topics) Understanding the organization of the electromagnetic spectrum Interconverting the wavelength and f requency of electromagnetic radiation Interconverting wavelength, f requency and photon energy Calculating the wavelength of a spectral line f rom an energy diagram Predicting the qualitative f eatures of a line spectrum Lewis Structures (16 topics) Counting bonding and nonbonding electron pairs in a Lewis structure Counting valence electrons in a molecule or polyatomic ion Deciding whether a Lewis structure satisfies the octet rule Writing Lewis structures f or diatomic molecules Calculating f ormal charge Writing Lewis structures f or a molecule with one central atom and no octet-rule exceptions Writing the Lewis structures f or a molecule with resonance Drawing Lewis structures f or simple organic compounds Predicting the relative electronegativities of atoms Predicting relative bond polarity Predicting the relative length and energy of chemical bonds Predicting the arrangement of electron groups around the central atom of a molecule Predicting bond angles in a small organic molecule Predicting whether molecules are polar or nonpolar Naming common chemical groups Identif ying common chemical groups in a Lewis structure Electronic Structure of Molecules (3 topics) Counting sigma and pi bonds in a small molecule Identif ying carbon hybridization in simple organic molecules Recognizing typical LCAO molecular orbitals Intermolecular Forces (4 topics) Identif ying a molecule f rom its electrostatic potential map Predicting the strength of intermolecular f orces f rom an electrostatic potential map Page 2 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Identif ying hydrogen-bonding interactions between molecules Identif ying the intermolecular f orces between atoms, ions and molecules Chemical Kinetics (10 topics) Using a rate law Using reactant reaction order to predict changes in initial rate Calculating the change in concentration af ter a whole number of half -lives of a first-order reaction Interpreting a reaction energy diagram Relating activation energy to reaction rate Drawing the reaction energy diagram of a catalyzed reaction Understanding the qualitative predictions of the Arrhenius equation Identif ying the molecularity of an elementary reaction Identif ying intermediates in a reaction mechanism Writing the rate law of an elementary reaction Chemical Equilibrium (6 topics) Using Le Chatelier's Principle to predict the result of changing temperature Writing a concentration equilibrium constant expression Calculating an equilibrium constant f rom an equilibrium composition Using an equilibrium constant to predict the direction of spontaneous reaction Recognizing equilibrium f rom a sketch Predicting equilibrium composition f rom a sketch Structure and Bonding (39 topics) Drawing Organic Molecules (10 topics) Identif ying carbon atoms in a skeletal structure Interpreting the skeletal structure of a neutral organic molecule Drawing a skeletal structure f rom a simple condensed structure Drawing a skeletal structure f rom a condensed structure Interpreting a skeletal structure with aromatic rings Recognizing diff erent skeletal structures Understanding H atoms in a skeletal structure Comparing skeletal structures related by one f ewer bond Using wedges and dashes in skeletal structures Understanding dash-wedge structures Formal Charge (5 topics) Assigning f ormal charges in simple Lewis structures Correcting f ormal charges in complex Lewis structures Placing lone pairs on simple Lewis structures Correcting lone pair placement in complex Lewis structures Evaluating octet compliance at carbon Interpreting Condensed Formulae (2 topics) Drawing a Lewis structure f rom the condensed f ormula of an unsaturated molecule Drawing a Lewis structure f rom a condensed f ormula with parentheses Principles of Organic Nomenclature (11 topics) Naming normal alkanes Identif ying organic f unctional groups Identif ying common chemical groups in a Lewis structure Using f amily suffixes to name organic compounds Identif ying f unctional groups in organic molecules written in skeletal f ormat Identif ying organic f unctional groups in simple structures Identif ying the main chain of branched alkanes Naming the parent hydrocarbon of branched alkanes Understanding the basic descriptive vocabulary of hydrocarbons Understanding the basic descriptive vocabulary of molecules with f unctional groups Naming and drawing small alkyl substituents Resonance (2 topics) Identif ying isomers and resonance structures Identif ying skeletal resonance structures Electron Movement (6 topics) Determining the product of a curved arrow drawn on a Lewis structure Drawing simple curved arrows on a Lewis structure to show how electrons move Drawing cascading curved arrows on a Lewis structure to show how electrons move Drawing curved arrows on a skeletal structure to show how electrons move Determining the product of curved arrows drawn on a skeletal structure Recalculating f ormal charge when electrons move Molecular Quantum Mechanics (3 topics) Page 3 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Understanding how to make sp hybrid orbitals Understanding how AOs combine to make MOs Using hybridization to predict relative length and strength of chemical bonds Organic Acids and Bases (5 topics) Acid-Base Reactions and Mechanisms (3 topics) Recognizing organic acids and bases Identif ying acidic and basic sites on an organic molecule Drawing the conjugate acid or base of an organic molecule without significant C-H acidity Structure-Acidity Relationships (2 topics) Using a pKa table to rank acids and bases Using pKa to evaluate acid-base equilibria Hydrocarbons (18 topics) Alkanes (6 topics) Classif ying hydrocarbons Naming and drawing normal alkanes. Naming and drawing simple cyclic alkanes Naming and drawing branched alkanes Naming and drawing simple substituted cycloalkanes Identif ying primary, secondary, tertiary, and quaternary carbons Constitutional Isomerism (3 topics) Identif ying constitutional isomers Drawing the condensed structure of a constitutional isomer Drawing the skeletal structure of a constitutional isomer Conf ormation (7 topics) Drawing Newman projections of simple organic molecules Describing the relative positions of substituents in a Newman projection Drawing the Newman projection of a molecule f rom its name Drawing a 6-atom ring in chair perspective Distinguishing axial and equatorial substituents Drawing axial and equatorial substituents Interconverting line structure and chair drawing Unsaturated Hydrocarbons (2 topics) Naming and drawing normal alkynes Naming and drawing alkynes Other Topics Available(*) (438 additional topics) General Chemistry Review (120 topics) Understanding how electrostatic f orce scales with charge and separation Calculating the magnitude of an electrostatic f orce using Coulomb's Law Understanding that electrostatic f orces add as vectors Calculating electrostatic energy using Coulomb's Law Names and symbols of important elements Reading a Periodic Table entry Recognizing element f amilies Predicting the type of bonding in a main-group element Counting the number of protons and electrons in a neutral atom Isotopes Counting the electron shells in a neutral atom Interpreting the symbol f or a nuclide Knowing the properties of the common types of nuclear radiation Understanding the common modes of radioactive decay Understanding radioactive half lif e Understanding the diff erence between a molecular and empirical f ormula Naming binary covalent compounds Naming binary ionic compounds Deducing the ions in a binary ionic compound f rom its empirical f ormula Deducing the empirical f ormula of a binary ionic compound f rom its name Predicting ionic compounds f ormed by two elements Predicting and naming ionic compounds f ormed by two elements Predicting the f ormula of ionic compounds with common polyatomic ions Deducing the ions in a polyatomic ionic compound f rom its empirical f ormula Identif ying oxoanions Naming ionic compounds with common oxoanions Finding molar mass f rom chemical f ormulae Page 4 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Interconverting number of atoms and mass of compound Stoichiometric coefficients Balancing chemical equations with noninterf ering coefficients Balancing chemical equations with interf ering coefficients Writing a chemical equation f rom a description of the reaction Solving f or a reactant using a chemical equation Limiting reactants Theoretical yield of chemical reactions Percent yield of chemical reactions Reaction sequence stoichiometry Calculating molarity using solute moles Using molarity to find solute moles and solution volume Calculating molarity using solute mass Using molarity to find solute mass and solution volume Identif ying acids and bases by their chemical f ormula Determining the volume of base needed to titrate a given mass of acid Determining the molar mass of an acid by titration Standardizing a base solution by titration Predicting acid or base strength f rom the conjugate Predicting the qualitative acid-base properties of metal cations Interconverting pH and hydronium ion concentration Interconverting pH and pOH at 25°C Interconverting hydronium and hydroxide concentration at 25°C Identif ying the major species in weak acid or weak base equilibria Calculating the pH of a buff er Calculating the composition of a buff er of a given pH Writing the dissociation reactions of a polyprotic acid Identif ying oxidized and reduced reactants in a metal-nonmetal reaction Identif ying oxidized and reduced reactants in a single-displacement reaction Predicting whether simple electrochemical reactions happen Solving a redox titration problem Calculating the heat of reaction f rom molar reaction enthalpy and the mass of a reactant Using Hess's Law to calculate net reaction enthalpy Writing a standard f ormation reaction Calculating a molar heat of reaction f rom f ormation enthalpies Solving combustion thermochemistry problems Calculating the heat of reaction f rom bond energies and Lewis structures Calculating entropy change f rom reversible heat flow Calculating absolute entropy using the Boltzmann hypothesis Calculating entropy change using the Boltzmann hypothesis Predicting qualitatively how entropy changes with temperature and volume Predicting qualitatively how entropy changes with mixing and separation Calculating reaction entropy using the standard molar entropies of reactants Calculating standard reaction f ree energy f rom standard f ree energies of f ormation Interconverting standard Gibbs f ree energy and K Using thermodynamic data to calculate K Interpreting the radial probability distribution of an orbital Interpreting the angular probability distribution of an orbital Deducing n and l f rom a subshell label Drawing a box diagram of the electron configuration of an atom Deducing the allowed quantum numbers of an atomic electron Interpreting the electron configuration of a neutral atom in noble-gas notation Writing the electron configuration of a neutral atom with a filled d subshell Interpreting the electron configuration of an atom or atomic ion Interpreting the electron configuration of an atom or atomic ion in noble-gas notation Identif ying the electron added or removed to f orm an ion f rom an s or p block atom Identif ying the electron added or removed to f orm an ion Identif ying s, p, d and f block elements Understanding the definitions of ionization energy and electron affinity Deducing valence electron configuration f rom trends in successive ionization energies Ranking the screening efficacy of atomic orbitals Understanding periodic trends in eff ective nuclear charge Deducing the block of an element f rom an electron configuration Calculating the wavelength of a line in the spectrum of hydrogen Counting electron pairs in a Lewis structure with double or triple bonds Predicting the single-bonded molecular compounds f ormed by two elements Recognizing exceptions to the octet rule Identif ying hybridization in a small molecule Drawing the MO energy diagram f or a Period 2 homodiatom Using the MO model to predict bond order and paramagnetism Identif ying the important intermolecular f orces in pure compounds Predicting the relative strength of the dispersion f orce between molecules Predicting the relative boiling points of pure substances Predicting how reaction rate varies with pressure, concentration and temperature Page 5 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Calculating the reaction rate of one reactant f rom that of another Calculating average and instantaneous reaction rate f rom a graph of concentration versus time Deducing a rate law f rom initial reaction rate data Using a zero order integrated rate law to find concentration change Using an integrated rate law f or a first-order reaction Using a second-order integrated rate law to find concentration change Using first- and second-order integrated rate laws Finding half lif e and rate constant f rom a graph of concentration versus time Solving applied problems with first-order kinetics Using the Arrhenius equation to calculate k at one temperature f rom k at another Using the Arrhenius equation to calculate Ea f rom k versus T data Writing a plausible missing step f or a simple reaction mechanism Deducing inf ormation about reaction mechanisms f rom a reaction energy diagram Predicting relative f orward and reverse rates of reaction in a dynamic equilibrium Using Le Chatelier's Principle to predict the result of changing concentration Writing the concentration equilibrium expression f or a heterogeneous equilibrium Calculating an equilibrium constant f rom a heterogeneous equilibrium composition Using the general properties of equilibrium constants Writing an equilibrium constant f or a reaction sequence Structure and Bonding (21 topics) Interpreting a flipped or rotated dash-wedge skeletal structure Understanding the 3D shape of molecules with pi bonds Drawing a Lewis structure f or a simple organic molecule f rom a description Completing the Lewis structure f or an organic molecule with non-zero f ormal charges Identif ying hydrogen atoms in a skeletal structure Expanding a chemical group and drawing in lone pairs on a skeletal structure Converting a skeletal structure to a Lewis structure Drawing a skeletal structure f rom a Lewis structure Interpreting condensed chemical structures Drawing a Lewis structure f rom a condensed f ormula with N and O Drawing a Lewis structure f rom a condensed f ormula with a carbonyl-containing f unctional group Numbering the main chain of branched alkanes Naming and drawing alkyl and alkoxy substituents Drawing resonance structures with complete octets Ranking resonance structures Drawing the second best resonance structure Ranking the stability of carbocation intermediates Predicting simple carbocation rearrangements Drawing the mechanism f or a carbocation rearrangement in a skeletal structure Determining the electron group geometry and hybridization state of atoms in a skeletal structure Recognizing orbital representations Organic Acids and Bases (22 topics) Understanding organic acids and bases Drawing the conjugate of a carbon acid or base Drawing organic conjugate acids and bases Drawing the products of an organic acid-base reaction shown in condensed Lewis f ormat Drawing the products of an organic acid-base reaction shown in skeletal f ormat Drawing the structure of a missing acid or base in an equilibrium reaction Identif ying an organic acid-base reaction f rom its mechanism Drawing the mechanism of an organic acid-base reaction Finding ionization f raction f rom pKa f or an organic acid or base Predicting an organic acid-base equilibrium using structural similarity and a pKa table Understanding the influence of element identity on site acidity Using a pKa table to estimate site acidities in complex molecules Understanding the solvent leveling eff ect Using periodic trends to identif y an organic molecule's most acidic or basic site Understanding the influence of resonance on site acidity Understanding how resonance aff ects organic acid and base strength Understanding the influence of induction on site acidity Understanding how induction aff ects organic acid and base strength Understanding the influence of hybridization on site acidity Understanding how hybridization aff ects organic acid and base strength Identif ying the stronger base f rom its structure Identif ying Lewis acids and bases f rom their structures Hydrocarbons (16 topics) Using multiplying affixes in the names of branched alkanes Identif ying degree of carbon substitution Understanding partial charge notation and comparing relative bond polarities Identif ying isomers Drawing constitutional isomers Matching Lewis structures to a 3D model Page 6 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Identif ying bond rotations in dash-wedge skeletal structures Understanding how strain aff ects the energy of a conf ormation Understanding the relative energy of rotational conf ormations Drawing a molecule in chair perspective af ter a chair flip Identif ying the more stable chair conf ormation of a 6-atom ring Understanding the stereochemical relationship between pairs of substituted cyclohexanes Naming and drawing linear alkenes with one double bond Interpreting condensed chemical structures with benzene rings Naming benzene derivatives Naming and drawing enynes and dienes (no E or Z required) Functional Groups (22 topics) Naming and drawing alcohols without alkyl side groups Naming and drawing alcohols Naming and drawing thiols without alkyl side groups Identif ying primary, secondary, and tertiary alcohols Identif ying common alcohols f rom a description Understanding the common names of simple ethers Understanding the common names of simple ketones Naming and drawing ketones Naming and drawing aldehydes Identif ying and drawing hemiacetals and acetals Understanding the common names of simple amines Identif ying primary, secondary, and tertiary amines Naming and drawing primary amines without alkyl side groups Naming and drawing secondary and tertiary amines Naming and drawing carboxylic acids Understanding the names of carboxylate salts Naming and drawing unsubstituted esters Identif ying primary, secondary, and tertiary amides Naming and drawing unsubstituted amides Understanding common names of carboxylic acids and derivatives Identif ying positions labeled with Greek letters in acids and derivatives Knowing the common names of small diacids Stereochemistry (16 topics) Identif ying rigid parts of an acyclic organic molecule Identif ying bonds with restricted rotation Identif ying cis/trans isomerism in a small condensed structure Identif ying cis/trans isomerism in a skeletal structure Drawing the cis or trans isomer of a small alkene Using Cahn-Ingold-Prelog priority rules f or alkenes Assigning E and Z labels to simple alkenes Naming and drawing cis- and trans-disubstituted cycloalkanes Identif ying a chiral molecule f rom its condensed structure Identif ying chiral centers in an acyclic organic molecule Identif ying chiral centers in a cyclic molecule Drawing the mirror image of a simple organic molecule Identif ying the enantiomer of a simple organic molecule Using Cahn-Ingold-Prelog priority rules f or small organic molecules Assigning R and S labels to small acyclic molecules Assigning R and S labels to small cyclic molecules Spectroscopy (5 topics) Understanding terms used to describe NMR spectra Converting chemical shif t to absorption f requency Identif ying the protons with unique NMR signals in a simple molecule Identif ying the protons with unique NMR signals in a molecule with a double bond Identif ying the protons with unique NMR signals in a molecule with a ring Organic Reactions and Mechanisms (15 topics) Classif ying organic reactions Recognizing substitution, addition, elimination, reduction, and oxidation in organic reactions Interpreting the components of organic reaction equations Identif ying nucleophiles and electrophiles in a reaction mechanism Using a model reaction to predict the product f or a similar reaction Using the Hammond Postulate to predict the starting material or products of a reaction Identif ying possible mechanisms f or a reaction using a reaction coordinate diagram Identif ying bond changes in Lewis structures f or an organic reaction Identif ying bond changes in skeletal structures f or an organic reaction Determining the product of a reaction mechanism that shows a sigma bond change at an explicit atom Drawing the mechanism f or a reaction that shows a sigma bonding change with partially condensed Lewis structures Drawing the mechanism f or a reaction that shows multiple bonding changes with partially condensed Lewis structures Determining the product of a reaction mechanism drawn with skeletal structures Page 7 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Drawing a mechanism on skeletal structures f or a reaction with no implicit bond changes Drawing the mechanism f or an acid base reaction involving an implicit hydrogen atom Substitution Reactions (15 topics) Naming and drawing alkyl halides Identif ying primary, secondary, and tertiary alkyl halides Identif ying electrophilic carbons in an alkyl halide Identif ying the important roles in a nucleophilic substitution reaction Predicting the product of a nucleophilic substitution reaction Comparing leaving group ability and nucleophilicity in substitution reactions Drawing the steps f or an SN2 or SN1 mechanism Drawing an SN1 mechanism including deprotonation Understanding the stereoselectivity of a nucleophilic substitution reaction Understanding how nucleophile strength impacts the mechanism in a substitution reaction Understanding how the degree of substrate substitution influences the mechanism of substitution Identif ying resonance stabilized carbocation intermediates in substitution reactions Predicting the eff ect of carbocation stability on the rate of reactivity Predicting the correct substitution products f or the reaction conditions. Drawing the correct substitution mechanism f or the reaction conditions. Elimination Reactions (12 topics) Identif ying beta hydrogens Identif ying the important roles in an elimination reaction Predicting the product of an elimination reaction Recognizing regiochemistry in elimination reactions Predicting major and minor elimination products Drawing the steps f or an E2 or E1 mechanism Understanding how the degree of substrate substitution influences the mechanism of elimination Understanding how the base influences the mechanism and products of elimination Recognizing the anti-periplanar requirement f or E2 elimination Predicting the correct elimination products f or the reaction conditions. Drawing the correct elimination mechanism f or the reaction conditions Predicting the major products when both substitution and elimination are possible Applications of Substitution and Elimination (10 topics) Predicting the products of symmetric alcohol dehydration Drawing the mechanism of the reaction of HX and an alcohol Drawing the mechanism of HX addition to an alcohol with a shif t Drawing the mechanism of acid-catalyzed alcohol dehydration Using alcohol dehydration to synthesize an alkene Preparing an alkyl halide f rom an alcohol in one step Using substitution and elimination on alcohols via tosylates Preparing an acyclic ether f rom an alcohol in two steps Predicting the products of nucleophilic epoxide ring opening Predicting the products of acetylide ion additions Electrophilic Addition Reactions (21 topics) Recognizing common alkene addition reactions Recognizing regiochemistry in HX or H2O alkene addition Inf erring an HX or H2O alkene addition f rom its products Recognizing when alkene addition creates chiral centers Recognizing syn and anti alkene addition Drawing the first step in the mechanism f or acid-catalyzed alkene addition Drawing the ionic mechanism f or HX alkene addition Drawing the mechanism f or acid-catalyzed alkene hydration Drawing the mechanism f or H2O or HX alkene addition with a shif t Predicting the products of HX alkene addition with stereochemistry Predicting the products of alkene hydration via acid catalysis or hydroboration-oxidation Fixing mistakes in an H2O or HX alkene addition reaction Predicting the products of alkene hydration via oxymercuration-demercuration Predicting the products of alkene halogenation with stereochemistry Predicting the products of alkene halohydrin f ormation with stereochemistry Predicting the reactants or products of alkene hydration Designing two-step syntheses using addition, elimination, and substitution reactions Predicting the products of alkyne halogenation or hydrohalogenation Recognizing keto-enol tautomerization Drawing the mechanism f or keto-enol tautomerization Predicting the products of alkyne hydration Organic Oxidation and Reduction (16 topics) Deducing oxidation state f rom a Lewis structure Identif ying oxidation and reduction in organic reactions Ranking relative oxidation or reduction f or a set organic molecules Predicting the reactants or products of alkene hydrogenation Page 8 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Predicting the reactants or products of carbonyl reduction Predicting the products of alkene hydrogenation with stereochemistry Predicting the products of alkyne hydrogenation Choosing reagents f or the reduction of ketones and aldehydes Predicting the reactants or products of carbonyl reduction using metal hydride reagents Predicting the reactants or products of nitrile reduction Predicting the products of alkene dihydroxylation Predicting the products of alkene ozonolysis Predicting the reactants or products of alcohol oxidation Predicting the reactants or products of alcohol and aldehyde oxidation Choosing reagents f or the oxidation of an alcohol Predicting the products of alkene epoxidation Radical Reactions (4 topics) Ranking the stability of hydrocarbon radicals Predicting the mechanism and products of a radical reaction step Predicting the products of alkane halogenation Predicting the products of allylic bromination Conjugated Pi Systems (14 topics) Identif ying conjugated double bonds Identif ying where a conjugated alkene may be protonated Predicting the products of electrophilic addition to conjugated alkenes Predicting the products of simple Diels-Alder reactions Predicting the products of a Diels-Alder reaction with a cyclic diene Deducing the reactants of a Diels-Alder reaction Using the Huckel Rule to Identif y Aromaticity Predicting the products of benzene halogenation, nitration, and sulf onation Predicting the products of Friedel‑Craf ts alkylation or acylation Using Friedel-Craf ts reactions f or synthesis Identif ying electron-donating and electron-withdrawing eff ects on benzene Understanding how substituents activate or deactivate a benzene ring Understanding directing eff ects in electrophilic aromatic substitution Predicting the products of electrophilic aromatic substitution with multiple directing groups Carbonyl Chemistry (39 topics) Drawing the mechanism of aldehyde or ketone hydration Predicting the reactants or products of hemiacetal and acetal f ormation Drawing the mechanism of hemiacetal f ormation Drawing the mechanism of acetal f ormation Predicting the reactants or products of acetal hydrolysis Drawing the mechanism of acetal or hemiacetal hydrolysis Predicting the products of cyclic acetal and hemiacetal f ormation or hydrolysis Choosing reagents and conditions f or acetal f ormation or hydrolysis Predicting the reactants or products of an imine or enamine f ormation reaction Choosing reagants f or a Wittig reaction Predicting the reactants or products of reductive amination. Predicting the products of organometallic additions to aldehydes and ketones Predicting the products of organometallic substitution with carboxylic acid derivatives Determining how mild and strong organometallic reagents react with carbonyl compounds Predicting the reactants or products of esterification Predicting the reactants or products of ester hydrolysis Predicting the products of ester saponification Predicting the reactants or products of amidation Predicting the products of amide hydrolysis Drawing the mechanism f or Fischer esterification Predicting the relative rates of generic nucleophilic acyl substitution reactions Predicting the products or reactants f or the nucleophilic acyl substitution of an acid chloride Drawing the mechanism f or the nucleophilic acyl substitution of an acid chloride Choosing conditions f or the transf ormation of a carboxylic acid to a carboxylic acid derivative Predicting the reactants or products of nitrile hydrolysis Identif ying acidic alpha H atoms in ketones, aldehydes, and esters Identif ying acidic alpha H atoms in 1,3-dicarbonyl and related compounds Drawing the mechanism of enol halogenation Predicting the products of enolate alkylation Understanding the steps of an acetoacetic ester synthesis Understanding the steps of a malonic ester synthesis Drawing the mechanism f or an aldol addition Predicting the products or reactants of an aldol condensation Predicting the product or reactant of an intramolecular aldol condensation Drawing the mechanism f or the first step of a Claisen condensation Predicting the products or reactants of a Claisen condensation Predicting the product or reactant of a Dieckmann condensation Predicting whether a carbon nucleophile adds 1,2 or 1,4 to a carbonyl or nitrile Page 9 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Predicting the products or reactants of a Michael addition Carbohydrates (19 topics) Understanding the descriptive vocabulary of monosaccharides Drawing the Fischer projection of the enantiomer of a monosaccharide Drawing the Haworth projection of an aldose f rom its Fischer projection Drawing the Haworth projection of a ketose f rom its Fischer projection Naming and drawing cyclic monosaccharides Identif ying a given carbon in a cyclic monosaccharide Naming and drawing the products of aldose oxidation and reduction Identif ying the parts of a disaccharide Knowing the names and properties of common sugars Identif ying common polysaccharides Understanding the glycosidic links in common polysaccharides Knowing inputs and outputs of glycolysis Completing a simplified diagram of glycolysis Completing a simplified diagram of glucose catabolism Solving carbohydrate catabolic stoichiometry problems Understanding the biochemistry of digestion Knowing inputs and outputs of the citric acid cycle Understanding the general mechanism of oxidative phosphorylation Solving citric acid cycle ATP stoichiometry problems Lipids (17 topics) Understanding the basic descriptive vocabulary of f atty acids Understanding lipid number notation Understanding melting points trends of f atty acids Identif ying the components of wax esters Identif ying the parts of a triacylglycerol Identif ying the parts of a glycerophospholipid Identif ying the parts of a sphingomyelin Identif ying molecules that could be in a cell membrane Recognizing the steroid nucleus Classif ying lipids derived f rom f atty acids Matching structure and f unction of common lipids Predicting the products or reactants of triacylglycerol hydrogenation Predicting the products or reactants of triacylglycerol hydrolysis or saponification Knowing the steps of beta oxidation Predicting the product of beta oxidation activation Knowing inputs and outputs of beta oxidation Solving f atty acid catabolic stoichiometry problems Proteins (22 topics) Recognizing alpha amino acids Classif ying amino acids Identif ying the stereochemistry of natural amino acids Understanding the general acid-base properties of amino acids Identif ying and drawing peptide bonds Describing peptides with 3-letter codes Identif ying specific interactions between residues in a protein Predicting the location in a protein of a residue sequence Naming an element of protein secondary structure f rom a description Identif ying changes at diff erent levels of protein structure Predicting reactants or products of phosphorylation Predicting the products of phosphoester or phosphoanhydride hydrolysis Understanding major biochemical energy storage and release reactions Understanding the f ormation and hydrolysis of acyl-CoA Knowing basic f acts about enzymes Classif ying enzymes Identif ying common redox coenzymes by their roles in a reaction Identif ying reactants and products f rom an enzyme name Understanding basic models of competitive and noncompetitive inhibition Predicting the eff ect of temperature or pH on enzyme activity Predicting the products of catabolic amino acid transamination Completing a diagram of protein catabolism Nucleic Acids (12 topics) Recognizing nucleotides Numbering the carbons in nucleotides Naming and drawing nucleosides Naming and drawing nucleotides Understanding the arrangement of hydrogen bonds in DNA base pairs Understanding the structure of nucleic acid strands Writing complementary DNA sequences Page 10 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
Understanding that DNA replication is semiconservative Identif ying the major types of RNA f rom a description Understanding the relationship between DNA and mRNA base sequences Using the genetic code Classif ying mutations *Other Topics Available By def ault, these topics are NOT included in the course, but can be added using the content editor in the Teacher Module. Page 11 / 11 Copyright © 2024 McGraw Hill - ALEKS® is a registered trademark of ALEKS Corporation
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