PUTTING ENERGY INTO INNOVATION - Rembrandtin
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YOUR True True Colours WORLD November 2020 Publisher: HELIOS Editor in chief: Stories Maša Bantan Marot Editorial board: OUR NEW Hitoshi Nishibayashi, Yasuo Horibe, Dietmar Jost, Hubert Culik SHADES Photos: HELIOS archives, Shutterstock or as written I Design and layout: n the past, stories commonly began with the phrase PM, poslovni mediji, »once upon a time«, but the year 2020 gave a new Tjaša Kastelic meaning to all the narratives. Amid the global CHOOSE YOUR OWN AMONG coronavirus pandemic, the line »in challenging Circulation: 800 pieces times like this« has been the most used opening, 1200 NEW SHADES Contact: HELIOS Corporate written too many times. As well at HELIOS, health and safety of employees and other stakeholders became our primary concern, communications department and responsible behaviour was even more reflected Maša Bantan Marot in all our activities. Even though we have to stand Phone: +386 1 722 4075 physically apart, we have stepped together and built masa.bantan@helios.si even stronger connections. Corona story itself has no silver lining, however it encouraged us to think beyond the health crisis and further strengthen our societal and environmental commitments. Although HELIOS is a coatings and chemicals producer our aim has never been just to make things green. We would like to turn them green with tangible actions reducing the impact on the environment along our entire value chain. With improved environmental performance we are accelerating our transformation to a carbon-neutral business. In this year's issue of True Colours we are proudly presenting our efforts we have put into development of innovative products and processes that present the future of our industry. We are picturing true people, true energy and true stories in the background. Take care, be safe and stay healthy! Hitoshi Nishibayashi CEO of HELIOS WWW.HELIOS-DECO.COM 1
TIME IS NOW CO NTE 06 24 38 62 NT Designing green coating solutions UV/EB curing coatings at a glance “Energy should be aimed in the right direction” A lean and green approach for a better performance 10 34 52 58 Raw materials supply Reusing CO2 to ADHESIVES AND SEALANTS: Building relationships and coatings produce green the perfect match for based on trust formulations products systems 50 Water-borne 42 HELIOS REFINISH: 22 32 Rembrandtin innovation A smart thermal 44 69 Wind energy enhanced ECOPOLIFIX: 78 Donating disinfectant 84 Thinking beyond makeover first impressions powering the electric insulation system with Helios Resins industrial future designed during the coronavirus the immediate of the Sofia Metro from Africa vehicles market on powder traces outbreak crisis 2 3
TIME IS NOW PROGRESS “Without continual growth and progress, such words as improvement, achievement, and success have no meaning.” Benjamin Franklin Scientist and statesman 4 5
PROGRESS Designing green coating solutions Karla Rončević Green coating solutions and systems are designed from the ground up to reduce their environ- mental impact and save resources. Their use will play the main role in the selection of process- es and products, and the need for them generates continuous innovations. I n recent decades, the chemical indus- industry, including coatings, are based on try has made a major step towards the fossil feedstock. That is why alterna- NEWLY DEVELOPED SOLUTIONS environmental footprint reduction. Initially, trends in the paint and coat- tive feedstock, such as biomass, recycled chemicals and carbon dioxide have lately SAVE ENERGY, WHILE REDUCING ings industry were strongly connected with environmental protection. The main goal been gaining importance. Polymers made CARBON DIOXIDE EMISSIONS. from renewables help save fossil resources was pollution prevention or the reduc- and reduce the carbon footprint. Bio-based tion of VOC levels together with the shift solvents, additives and pigments are already towards waterborne coatings, powder, and available as well. In addition to the ecolog- UV curing coatings. Nowadays, besides the ical features, the products based on these environment, the producers would like to raw materials need to excel in performance. take into account the total effect of products on the society and the economy. Solutions protecting things that matter When designing new products, the de- While paint and coatings are commonly velopment of all stages is closely intertwined known for providing aesthetic appeal to the with the circular economy principles and materials they coat, their most important the commitment towards nature and cli- function is to protect and prolong the life of mate. This means that producers reconsider those materials. Coatings provide protec- every stage of the coating’s life cycle from tion from degradation, such as corrosion, raw materials formulation, application and abrasion, high temperatures, chemical curing to disposal at the end. impact, moisture, or UV rays. In order to contribute to sustainability, researches are Renewable raw materials and sourcing developing coatings that are more durable, To ensure sustainable products and formu- thus minimizing the need for maintenance. lations, producers need to develop solutions Newly developed solutions also protect the that will be most appropriate at the end of environment in a more direct way: they save the material's life cycle. That is why the first energy by keeping buildings cooler and they things to be reconsidered are raw materials are an essential part of renewable energy ROOF EXPERT AC, THE NEW ROOF COATING SYSTEM FROM from biological and other renewable sourc- systems, while also helping reduce carbon HELIOS, PROTECTS THE SURFACE AND IS HIGHLY SUNLIGHT es. Most chemicals used in the polymer dioxide emissions. REFLECTIVE. 6 7
PROGRESS Functional coatings of the future provide better heat dispersion in electric THE NEW GENERATION OF ONE-LAYER COATINGS FROM Many efforts have been devoted to the motors and transformers, thus enabling HELIOS SUCCESSFULLY REPLACED THE TRADITIONAL development of new functional coatings higher efficiency, and enhancing the life- MULTILAYER PAINT SYSTEMS. that represent the future of the coatings time of the components. industry. Besides the protection and ap- The fast-growing segment of renew- pearance, coatings provide additional de- able energy solutions needs coatings with sired functions and, in many cases, directly additional functionalities as well. Protec- contribute to sustainability. tive coatings used on wind turbines enable For example, the so-called IR reflective blades to rotate under challenging con- roof coatings offer environmental and ditions, by providing UV and weathering cost-saving benefits for both residential protection together with the protection and commercial roofs. Roofs protected against rain erosion or ice accumulation. with coatings that reflect the IR energy Additionally, the solar energy market from the sun, absorb much less heat than needs efficient coatings for solar panels. By traditional coatings. This process helps to providing special coatings that reduce the reduce the “urban heat island” effect and reflection of sunlight, the energy output of at the same time helps to lower the indoor photovoltaics is increased. temperature. The health and well-being of people are THE ANTIBACTERIAL POWDER COATING FROM Electrical insulation coatings play an also some of the main drivers of sustain- HELIOS IS TESTED ACCORDING TO ISO 22196, important role in lowering the energy able commitments. With low-emitting AND OFFERS ADVANTAGES WHEN USED IN losses during transmission from the gen- interior coatings, the industry is contrib- SPACES LIKE MEDICAL FACILITIES OR SCHOOLS. eration site to distribution centres. They uting to the health and comfort of the PRODUCERS RECONSIDER EVERY STAGE OF THE COATING’S LIFE CYCLE FROM RAW MATERIALS FORMULATION, APPLICATION AND CURING TO DISPOSAL AT THE END. sensitive population, like children, elderly the same or better protection, while people and patients. Specially formulated simplifying the application process and coatings go even further and purify the improving efficiency. air by transforming harmful chemical into unharmful ones. Closing the green circle Surfaces around us presents an ideal Through commitment to sustainability, environment for microorganisms to devel- the coating industry recognized the con- op their colonies and endanger our health cept of Life Cycle thinking. Our attention and well-being. Additionally, microbial is devoted to the recent downstream in- growth can affect the functionality of dustry developments, with efforts focused the product, which leads to degradation, on coatings reformulation, raw materials staining, bad odour and other unwanted or packaging used. Paints with higher life properties. expectancy are developed to protect and One of the most energy consuming prolong the lifetime of environmentally parts of the coating application process costly substrates, such as metal and wood, HELIOS’S HIGHLY DURABLE PE POWDER COATING N194, WITH LOW is oven curing. That is why development or to reduce the demand for energy. Along TEMPERATURE CURING PROPERTIES, SIGNIFICANTLY LOWERS WITH THE REMBRANTIN PROTECTIVE APP CUSTOMERS is focused on coatings that cure on lower with sustainable packaging and recycling, ENERGY CONSUMPTION, WHILE STILL PROVIDING DURABILITY AND CAN SEARCH FOR PROTECTIVE COATING SYSTEMS temperatures or even tries to eliminate the the paint and coatings industry contrib- MECHANICAL PROPERTIES REQUIRED BY ACE PRODUCERS. SUITABLE FOR A VERY LONG DURABILITY PERIOD OF need for oven curing completely. Modern utes to the reduction of waste and product CORROSION PROTECTION. coating systems need less layers to provide loss in general. • 8 9
PROGRESS CORONAVIRUS LESSONS Raw materials supply and coatings R aw materials and logistics are crucial formulations The current globalized raw mate- rials supply and logistics system currently works in a way that production sites in Asia ensure that a wide range of critical products are available in Europe as Hubert Culik cheaply as possible. This system works well if production sites can keep up production and transport flows remain unhampered. 2020 is a year that will go down in history as a year of drastic developments. The rapid spread of the However, the coronavirus pandemic tempo- coronavirus from China all the way across Europe has brought unprecedented challenges to our societies rarily closed borders worldwide and across Europe, posed export restrictions, shut and economies. Within the coatings industry, two factors form its backbone and are crucial for its down factories in China and India which success: the availability of raw materials and the art of coatings formulation. Both were confirmed during significantly affected supply chains and lo- the coronavirus crisis once again. gistics – vital parts of the chemical industry. in-time production around the world. New conditions require new adjust- THE CRISIS REVEALED The crisis revealed the existing system’s vulnerabilities and demonstrated great risk ments. For the coatings industry, this THE EXISTING SYSTEM’S means bringing back development and of overdependence on global supply chains, which was particularly unsettling for the production to Europe. Our own know-how VULNERABILITIES AND and experience in raw materials production pharmaceuticals industry. should be the basis to shift from globalisa- DEMONSTRATED GREAT RISK OF At HELIOS, we mastered raw materials supply during the critical months. Thanks tion to “glocalisation”. For instance, yellow pigments, high quality solvents, or additives OVERDEPENDENCE ON GLOBAL to our well-organised purchasing depart- ment, there were hardly any raw material currently made in China could easily be SUPPLY CHAINS. produced in Europe. shortages during the crisis and production mostly proceeded as usual. An occasional shortage of a raw material is common in Advantages of local production normal times as well, so we are prepared for Local product development and production among local suppliers stimulates research such cases. have many advantages. The biggest is avoid- and development, while direct communica- ing long transport routes. Compliant with tion along a local supply chain makes it easi- “Glocalisation” is the future the framework of the Green Deal of the er to react quickly to a change in demand. To be prepared for a similar crisis in the European Commission, transport efficiency future, we should consider whether is it is also a major step towards reducing CO2 R&D and formulation after the a valuable advantage to import certain emissions. Additionally, locating production coronavirus pandemic chemicals solely from China or India due sites in Europe reduces the risk of interrupt- Research and development as well formu- to a slightly lower cost. Considering the ed operations as the capacities can easily be lation know-how have always been one of time, effort and costs required to organise shifted to another site if needed. the key elements in the coatings business. the necessary logistics, the benefit may not Locally, it is much easier to monitor and The coronavirus pandemic has pointed out always be worth the risk. The pandemic has ensure adherence to quality, environmental, a new direction for innovation which could shown that we have to question global just- and labour standards. Close cooperation significantly contribute to a safer life. 10 11
PROGRESS THE CORONAVIRUS PANDEMIC HAS POINTED OUT A NEW DIRECTION FOR INNOVATION WHICH COULD SIGNIFICANTLY CONTRIBUTE TO A SAFER LIFE. HELIOS RESINS 01 The secret to sustainable raw We need to ensure that we are not com- pletely dependent on overseas suppliers and hence bring some of the raw materials production back to Europe. 02 We have to encourage local research, de- velopment and innovation in cooperation with local suppliers. materials Dr. Martin Ocepek, Dr. Peter Venturini 03 Research has to focus on new formulations and products in the field of antibacterial and antiviral coating materials. A team of 25 dedicated R&D employees at Helios Resins is aiming to reduce environmental impact by developing Since bacteria and viruses are often Consequently, research should also advanced, green, and long-lasting transmitted via surface contact, this crisis focus on exploring other possibilities of materials. We have managed to reduce will put emphasis of research for antibac- surface modification which would not re- terial and antiviral coatings. quire biocides but would remain its antivi- emissions of hazardous organic solvents, Antibacterial coatings have been on ral effects. One alternative are bionics that create a potential for energy savings, and the market for some time and they are provide many fields of application. They known for providing lasting and efficient are very useful in a medical environment incorporate bio-renewable raw materials. protection against bacteria, fungi, and but also public spaces, e.g. door handles, All this while maintaining high-quality mould. There are various mechanisms of cars, public transport and furniture. antibacterial action, e.g. preventing bac- products aligned with the requirements terial attachment, release of antibacterial Lessons we have learned of our most demanding customers. Our agents, or killing bacteria upon surface We have learned several lessons from the contact. Currently, in most products the coronavirus pandemic that will shape re- The value of being able to react quickly efforts are also recognized annually with antibacterial effect is achieved by adding sponses to future crises. Globalisation will was powerfully demonstrated in April the Responsible Care® certificate. biocides to the coating’s formulation. not entirely be reversed but “glocalisation” when HELIOS, among several other However, biocides are governed by the will help us to become more independent, chemical companies, switched production Biocidal Products Directive (98/8/EC), while it will stimulate innovation and promptly from coatings to WHO approved which means that newly developed biocid- contribute to the protection of the climate disinfectants. Such impressive flexibility al coatings have to pass a time-consuming by reducing CO2 emissions due to shorter was possible due to our broad experience in and costly authorisation procedure. transport routes. • the art of formulating. 12 13
PROGRESS INNOVATIVE HELIOS RESINS REDUCE VOCS, BRING ENERGY SAVINGS AND EXTEND COATING LIFETIME. S ustainable car refinish solutions performance Domacryl brand types has solvent. The major challenge is water’s The European Union has adopted been developed to enable our customers incompatibility with traditionally used directives limiting Volatile Organic to stay ahead of their competitors. polymers, which require a very high level Compounds (VOC). Helios Resins, Patented technology has been of expertise. To provide commercially a separate HELIOS unit, has responded to successfully implemented in the market feasible materials, water-based resins must the new set of standards with a range of and has positioned us as a market leader be high quality, stable, and price-efficient. High-solid (HS) resins, which enable final in the segment of FAST-drying acrylic We have developed and scaled more than coatings producers to meet legislation resins for car refinish, general metal and 40 different water-based materials to the limits with their ready-to-use products. industrial wood protective coatings. In industrial level to cover various needs, Within the HS resins segment, we pay addition to reduced VOCs, our innovative especially in the segments of wood and special attention to car refinish products, resins bring energy savings through lower metal coatings. VOCs have been reduced where resins and coatings must meet high curing temperature and an extended by as much as 95%. performance expectations introduced by coating lifetime. Importantly, up to 20% car paint shops. of fossil-based raw materials have been During the past few years, over 30 replaced by bio-renewables and increased R&D EFFORTS ARE FOCUSED different novel acrylic and polyester types material performance. of resins with 70-100% solid content have ON ALTERNATIVES SUCH AS been developed and successfully launched into the market. We have achieved a 30- Alternative water-based resins A significant part of R&D activities is WATER-BASED RESINS, AS WATER HELIOS RESINS IS DEVELOPING ADVANCED, GREEN, 50% decrease in their VOCs compared to related to the development of alternative REPRESENTS THE “GREENEST” AND LONG-LASTING MATERIALS FOR TODAY, TOMORROW standard Medium solid (MS) products. solutions such as water-based resins, Additionally, a set of unique high- as water represents the “greenest” SOLVENT. AND THE DAYS TO COME. A tradition of bio-based materials resins. They represent 7% of produced methacrylic acid was developed to replace WITHIN THE HIGH-SOLID RESINS SEGMENT, WE PAY Recently in the paint and coatings quantities of Helios Resins. Renewable fossil-based standard. Furthermore, Helios SPECIAL ATTENTION TO CAR REFINISH PRODUCTS. industry, many efforts have been oils which in nature derive from Resins is participating in COST Action, devoted to the development of bio-based sunflower, linseed, soybean, castor, the European network of furan-based materials. Bio-based products derive from tall and others, are standard within chemicals and materials for sustainable plants and other renewable agricultural, the coating industry. Due to the VOCs development (FUR4Sustain). The main marine and forestry materials to provide limitations, alkyd water emulsions objective is to catalyze a replacement an alternative to conventional fossil- are gaining greater acceptance than for terephthalic acid, a widely used derived products. The conversion of conventional solvent borne (SB) ones, building block in resins for coatings biomass and bio-based ingredients into replacing up to 85% of fossil-based raw and packaging. Furandicarboxylic acid useful products for paints and coatings materials. (FDCA) and derivatives are considered provides considerable and sustainable a very promising replacement from a growth potential. The demand from Dedicated to a green future renewable origin. Lastly, Helios Resins is customers, as well as the Helios Resins In addition to its established bio-based a member of the Strategic Research and team strategy, is to increase bio-based alkyd production, the Helios Resins team Innovation Partnership for the transition content in produced materials. is constantly working on the development into a circular economy, supported by the The basic and most important of new bio-based products. Close Slovenian Government. Priorities for the bio-based Helios resins, continuously collaboration with the National Institute partnership are to reduce the amount of produced for over 50 years, are alkyds of Chemistry has resulted in a patent production waste and to reuse existing which are natural oil modified polyester pending technology where bio-based waste as raw material for new products. • 14 15
PROGRESS MOBIHEL Energy efficient THE NEW GENERATION OF MOBIHEL PRODUCTS IS A and highly WINNING COMBINATION FOR ENHANCED WORKSHOP PRODUCTIVITY AND ENERGY productive car SAVINGS. refinish products Irena Tavčar M ulti-layered modern car refinish paint system A modern car refinish paint system consists of primer–filler/ in the resins segment, provide various solutions. Among new materials are very reactive polyacrylate binders and polyaspartic binders. Polyacrylate binders In 2019, we launched the first two products of the new generation of highly productive and energy efficient clearcoats and fillers compliant with European basecoat/clearcoat, offering waterborne enable faster curing or lowering the VOC legislation, MOBIHEL 2:1 HS or solvent borne technology. The biggest curing temperatures, while polyaspartic CLEARCOAT FastDry and MOBIHEL HS The latest R&D trends in car refinish prioritize sustainability challenge for car refinish paint producers binders eliminate the need for elevated FILLER AirDry. This year the additional is to reduce drying time of fillers and temperature curing or shorten drying clearcoat MOBIHEL 2:1 HS CLEARCOAT as one of the main quality criteria, underlining the importance clearcoats. Fillers must dry quickly to time at higher curing temperatures. AirDry joined the family of products. of improved coatings durability, next to energy and process enable the process of sanding instantly Polyacrylates in normal conditions after application and overcoating with the increase productivity by 20% and reduce Fast dry clearcoats for perfect end results efficiency. This is also mirrored at Helios Refinish. basecoat afterwards. Clearcoat must be energy consumption by 50%, while Our clearcoats excel in drying regime ready to polish immediately after a short polyaspartics perform even better. flexibility depending on the workshop time drying and cooling down. equipment and conditions. Importantly, A new generation of products we did not compromise the quality of Efficient raw materials solutions The Helios Refinish R&D department polishing or the drying time regime. Thus, Raw materials producers, especially successfully follows industry trends. the final appearance remains perfect. LAYERS OF A REFINISH PAINT SYSTEM FILLER 60–180 µm – surface, stone chip resistance BASECOAT 15–25 µm – colour, metallic effect CLEARCOAT 50–60 µm – transparent protection, gloss 16 17
PROGRESS DRYING TIMES UNDER DIFFERENT TEMPERATURE CONDITIONS TIME EFFICIENT MOBIHEL SYSTEM FastDry CC AirDry CC New development 12 min. super-fast 15 min./60° 5 min./60°C 5 min./60°C 36 min. fast 30 min./40°C 15 min./40°C 10 min./40°C energy efficient 120 min./20°C 60 min./20°C 40 min./20°C 30 min. 30 min. New fillers for a four times smooth and flat surface for the excellent faster drying process basecoat/clearcoat optical features. MOBIHEL HS FILLER AirDry is ready for sanding in approximately Advantages of the fast curing Substrate preparation 20–30 minutes when following the coating system AirDry filler room temperature criteria. The drying The new generation of filler/basecoat/ process is four times faster than with clearcoat are a winning combination for Basecoat other conventional air-drying fillers. enhanced workshop productivity and AirDry clearcoat Different drying regimes can be achieved energy savings. The system also meets by choosing individual hardeners high quality standards and long-term and thinners depending on the size durability. A car bonnet can be repainted of the painted car part and workshop in less than two hours, including Time for the complete repaint of a conditions. After the drying and preparation, sanding, application, flash personal car bonnet with the super sanding process, the filler ensures a very off and drying. • productive MOBIHEL System. Remsolar: coatings for a greener future Mag. Petra Gomez Alfaro-Kalteis Today, photovoltaics continue to be a hot topic on the world stage. Extensive information, literature and research is available in the media and online, while many roofs are already fitted with solar panels. However, applying coatings to solar panels, specifically to the backsheets, is pioneering work. 18 19
PROGRESS REMSOLAR PROVIDES A COST-EFFECTIVE AND SUSTAINABLE SOLUTION FOR RELIABLE SOLAR ENERGY. NEW BACKSHEET COATINGS OFFER THE FUNCTIONALITY OF CURRENTLY USED MULTILAYER FILM TECHNOLOGY, WHILE PROVIDING CAR WITH SOLAR PANELS ON THE ROOF THE SAME LEVEL OF PERFORMANCE AND REVOLUTIONIZING THE PROCESS EFFICIENCY OF BACKSHEET PRODUCERS. global one. With many backsheet and structures to be integrated into Remsolar coatings ensure: module producers based in China, Asia buildings during the construction phase • Long term protection from humidity is clearly a focus. However, Europe (e.g. facades, balconies etc.) as well into • Long term protection from UV shows significant growth rates in this cars. This will lead to new requirements radiation field as well. The European Union of coatings’ color availability, and • Good adhesion to the encapsulant Market Outlook for Solar Power 2019 warranty period. • Thermal and dimensional stability – 2023 estimates + 26% growth in At HELIOS and Rembrandtin, we PHOTOVOLTAIC INTEGRATION IN BUILDINGS • Optical aspects (color) 2020. The biggest growth is expected believe that the right policies will give from Spain, followed by Germany, a push to renewable and green energy. Since this field represents a Netherlands, France, and Poland. The same applies to the growth of the A new market for coatings, a lot of Additionally, emerging markets such photovoltaic sector, where attributes t Rembrandtin Coatings, a sustainable solution for reliable solar time has been invested in defining as India, Saudi Arabia, and Egypt have such as sustainability and low costs company part of the HELIOS, energy. New backsheet coatings offer appropriate test procedures to ensure set very ambitious renewables targets will be the main drivers of the solar a dedicated team together with functionality of currently used multilayer the performance and quality of the which leads to increased demand for energy market. As of now, our aim is external partners and experts film technology, while providing the same backsheet and the photovoltaic module photovoltaic installations. to dive further into this market, visit have taken on the challenge to formulate level of performance for a considerably throughout their entire lifetime of 25+ industry events, connect with potential and develop Remsolar, a new series of lower price. This revolutionizes the process years. The “bright” future of photovoltaic customers, expand our knowledge, and coatings designed to protect backsheets. efficiency of backsheet producers and coatings increase our brand recognition. We are Remsolar provides a cost-effective and significantly reduces the CO2 footprint. The evolution of the global The share of energy from photovoltaics confident that our Remsolar will have a photovoltaic market will grow significantly worldwide. bright and shiny future and we will keep THE STRUCTURE OF A PHOTOVOLTAIC MODULE The photovoltaic market is truly a In the future we expect photovoltaic you updated on our success story. • PARTNERS ON THE PROJECT 20 21
PROGRESS Rembrandtin innovation powering the electric vehicles market Dietmar Jost As technological progress in the electrification of two- and three-wheelers, buses and trucks advances and the market for them grows, electric vehicles are expanding significantly. E lectric cars, which accounted for 2.6% market leader in this sector, we have been of global car sales and about 1% of supplying well-known electrical sheet REMISOL CORE PLATE global car stock in 2019, registered a 40% year-on-year increase. HELIOS producers and generator manufacturers worldwide. VARNISHES ARE is proud to be a frontrunner and key innovator in this segment with its core plate Rembrandtin also has a portfolio of ENVIRONMENTALLY FRIENDLY bonding and C5 varnishes which are already varnishes which increase the efficiency and in use or in the process of homologation for AND CHROMIUM-FREE WITH power of electric engines. Together with the top car making companies, such as Audi, our innovations in the field of wind-energy, BMW, Daimler, Tesla, Toyota, or Volkswagen. LOW EMISSIONS. photovoltaics and hydro power plants, we The focus of current developments in are continuously striving to contribute to a the electric and hybrid vehicles market is sustainable and green future. on thinner steel grades and less dry film Remisol core plate varnishes are thickness of the varnish in order to improve environmentally friendly and chromium- the performance of the electric engine. free with low emissions. Water-based, hot Worldwide volumes are believed to curing varnishes were developed for the increase dramatically as new environmental electrical insulation of electrical steel sheets. policies are being put in place and as Their excellent insulating properties reduce series production of new models begins. eddy current losses during the operation Thanks to our ongoing developments in of electrical machines and thus increase the field of batteries and the rapid build- their efficiency. They improve punchability up of infrastructure for electric vehicles in in the further processing of the sheets and combination with smart grids, we strongly offer other important properties, such as believe in the positive power of this weldability or annealing resistance. As the transformation. • 22 23
PROGRESS UV/EB curing coatings at a glance Mateja Šlibar Since their introduction in the seventies, radiation-cured coatings and inks have been on the rise. They have now become a generally accepted fast-growing sustainable UV/EB CURING COATING FORMULATIONS technology within the industry. RAW MATERIAL USER REQUIREMENTS T he high growth of radiation- Curing with radiation UV/EB-CURABLE COATINGS cured coatings, known also as Radiation-cured (RC) coatings and inks are SIMPLIFY PRODUCTION, UV/EB curing coatings, is due to their several advantages, such formulations of components that contain reactive groups that react with each other ELIMINATE SOLVENT EXTRACTION as performance, productivity and low environmental impact. The use of radiation- after exposure to energy-rich radiation. In general, there is no physical drying involved STEPS, REDUCE COSTS, AND cured coatings can simplify production, in the curing mechanism, while recent eliminate solvent extraction steps and coating formulations tend to be free of HAVE A LOW ENVIRONMENTAL consequently reduce the cost. Moreover, organic solvents. Even though many types FOOTPRINT. UV/EB technology does not produce CO2 and is consequently not subject to any of radiation would theoretically be possible, the industrial application is mainly limited carbon tax. Existing coating units can be to the curing by ultraviolet light (UV) and easily retro-fitted with UV/EB technology electron beam (EB). given the small footprint. Due to the immediate drying mechanism, UV/EB technology reduces lead time and increases the coating throughput. UV CURING VERSUS TRADITIONAL COATING TECHNOLOGY PHYSICAL DRYING CHEMICAL CURING Difference between UV and EB curing of applications use acrylic functional and monomer types then define the final UV LED LAMP In UV curing technology, multifunctional resins cured with a UV photoinitiator. coating properties. UV/EB formulations Solvent evaporation No solvent evaporation Phisycal drying Chemical polymerisation resins are polymerized or cross-linked by In EB curing technology, the same also need 1-10% of photoinitiator in case No crosslinking Crosslinking produces a rigid network exposure to UV light. UV light triggers a multifunctional resins can be used, but no of UV curing and 1-3% of additives to UV photoinitiator in the formulation to photoinitiator is needed. The electrons promote flow, levelling, cratering, slip or generate polymerization initiating species initiate the polymerization and the end other properties. Such coatings or inks which very rapidly convert the liquid UV result is also a highly cross-linked coating. can be pigmented or can contain fillers. resins to a fully cross-linked coating. There In pigmented coatings or inks with UV are two main curing technologies used Formulations of UV/EB curing coatings curing, the photoinitiators and lamps may Heat UV - light in practice. The first is a free radical cure Formulations of coatings appropriate for need to be chosen correctly, not to overlap of mainly acrylic resins, and the second UV/EB curing are usually made up from too much with the absorption spectrum is a cationic cure of mainly epoxide ring oligomers and monomers in a 1-1 ratio of the pigments. Many different types opening curing reactions triggered by a UV depending on the required application of photo initiators exist, with different cationic photoinitiator. The vast majority viscosity. A broad range of different resin absorption spectra. 24 25
PROGRESS Different treatment and application types Radiation-curable water-based, powder, DRIVERS FOR THE IMPLEMENTATION OF UV LED SYSTEMS In most cases, conventional 100% liquid RC and additionally dual-cure formulations Technology features Environmental benefits systems are intended for the treatment of are treated under “Special Systems” and flat surfaces with roller application due to while water-based and powder RC coatings Instant on and off Ready to use or no warmup time, energy savings and some limitations in application viscosity. are already well established, the dual cure positive impact on lifetime With the development of alternative technology is still a niche area. Low electricity consumption Energy savings systems like radiation-curable water-borne UV/EB-curable coatings simplify Low heat output Positive impact for heat-sensitive substrates and powder coatings, spray application production, eliminate solvent extraction HELIORES 3D IS A LIQUID No ozone, no mercury Environmentally friendly and easier integration and processing of profiled elements is steps, reduce costs, and have a low PHOTOPOLYMER FOR 3D PRINTING possible as well. For complex 3D objects environmental footprint. Long lifetime, constant output Lower maintenance costs and better process control INTENDED FOR GENERAL USE WITH where UV light hardly reaches shadow VARIOUS TYPES OF SLA AND DLP areas, so-called dual-cure coatings are Special UV/EB curing equipment PRINTERS. used. Radiation-curable water-borne and Standard UV lamps are mercury lamps and powder coatings combine the flexibility of can be doped with iron or gallium to control the higher molecular oligomers with the emission spectra. The lamps typically have hardness and resistance resulting from the an output of 80-120W/cm² and are available high crosslink density through the acrylate in many lengths. There are 3 main types of groups. Meanwhile, dual cure coatings UV lamps – standard mercury lamps, iron- have two curing mechanisms, where the doped mercury lamps and gallium-doped radiation curing mechanism complements mercury lamps. Recently, LED lamps have the curing of polyisocyanates with polyols. been added to the selection. Fast growing market plastic coatings, resilient flooring, metal for advanced manufacturers of flat The whole segment of RC coatings has coatings, opto-electronics and adhesives. interior furniture, which includes wooden shown significant growth rates in the In graphic arts, UV/EB is mostly used in doors, tables, cupboards, shelves, and recent years. While China remains the lithographic and flexo printing, as well parquet. The systems present an optimal leader in UV/EB technology, there is a fast as in screen printing, letterpress, and ink combination of putties, base coats, top growth of UV/EB in coating application jet printing. In electronics, UV/EB is used lacquers and enamels, processed with in the more mature markets of North in printed circuit boards as a photo resist modern UV curing procedures for the care America and Europe. There, application coating, in displays both on the inside of of wood veneer, solid wood, MDF and segments with a higher market penetration the electronics as well as on the outside different decorative foils. In the future, we of UV/EB, such as furniture and floor as a hard coat. On plastics, the technology will continue to invest in the development coatings, printing inks and overprint works in the form of wear-resistant of innovative products, for example, invest varnishes, show a moderate growth coatings (Gagro, ECJ, May 2020). in UV LED technology for heat-sensitive rate of about 2-4%. In addition to the substrates, extend UV curing coatings industrial coatings application in wood Helios’s UV/EB portfolio and its future also to exterior joinery and try to find and paper coatings segments, UV/EB development interesting fields of using UV coatings on curing technology can be found also in HELIOS UVEHEL/UVEHEL AQUA UV other segments, such as car repair coatings, other emerging areas. It is applicable with curing systems offer a complete solution coatings for metal and plastic. • 26 27
PROGRESS BIOCIDAL PRODUCTS EXERT CONTROLLING EFFECT ON HARMFUL OR UNDESIRED MICRO-ORGANISMS. Biocidal L ately, producers of paints and coatings have come under pressure as regulatory trends for biocides significantly limit options and ways of regulation usage. With new measures, regulators tend to improve the functioning of the internal the European Union Biocidal Products Biocidal protection of wet water-based market through the harmonisation of rules Regulation (BPR) and classified in 22 paint on the production and usage of biocidal Product Types (Pts) depending on their An average water-based paint contains as the driver products. Furthermore, the new regulation function. Only the active substances or about 10 – 15 components, and nearly all of also ensures a higher level of environment their mixtures, which are authorised for them can be a source of bacterial infection. and health protection. Therefore, certain purposes, can be used in biocidal The production equipment is also an formulators are faced with the challenge products, produced and sold by the coatings additional source of bacterial infection. To that ever fewer biocides are available, and industry. Each biocidal product must be destroy all sorts of bacteria and to achieve of continuous biocide concentrations have to be reduced. registered by the responsible body in the EU long term biocidal protection of wet paint, At the same time, the quality of final country where it is sold, while some of these it is necessary to add bactericides. This products shall not be compromised. That is products should be authorised as well. is achieved with a process called in-can why the industry as well as the stakeholders preservation, which serves as a precondition development along the value chain have to develop new Biocides in the paint and coatings industry for safe and high-quality coatings with a sustainable solutions. In the paint and coatings industry, biocides long shelf life. An in-can preservation is a are used in a wide variety of procedures. mixture of 2 to 3 active biocidal substances Understanding biocidal products They can be found in wet water-based with broad pH and T stability and a broad Biocidal products are widely used agents, paint, wood impregnations, fungal or antibacterial activity. The need for in- with an active substance that is intended anti-microbial products, disinfectants and can protection very strongly depends on Cirila Colnar Mikeln, Hubert Culik to destroy, deter, render harmless, hygiene coatings, and are widely used for the components of the paint. The most prevent the action of, or otherwise exert a plant hygiene, too. That is why at HELIOS, susceptible to bacterial infection are wall The paint and coatings industry is closely related to the use of biocides, controlling effect on harmful or undesired we use a wide selection of biocidal products paints, which require a very carefully chosen substances that have undergone stricter regulatory measures in the past years. micro-organisms. They are regulated by and continuously research new possibilities. in-can protection. 28 29
PROGRESS into the paint. Additionally, they are hygiene legislation. Our R&D team at also not suitable for skin disinfection, HELIOS is currently developing the as they are irritative for skin. products for this field too. Disinfectants are not yet submitted to the authorisation, but it can be Regulations – continuous expected in the future. development driver The obligations of paint and Plant hygiene care coatings producers, producing and When it comes to plant hygiene, marketing biocidal products are each plant has its own protocol of not regulated only by the BPR, but disinfection and cleaning, depending also by the Globally Harmonized on the technology specifics and System of Classification and Labelling product quality. This protocol of Chemicals (GHS) and the EU DISINFECTANTS ARE NOT SUITABLE AS AN ADDITIVE TO THE PAINT AS defines in detail the periods and Regulation on Classification, Labelling THEY ACT DIRECTLY ON THE INFECTED SURFACE AND LOSE THEIR ACTIVITY ways of disinfection for each part and Packaging of substances and WHEN MIXED INTO THE PAINT. of the technology. Special care is mixtures (CLP). The latter allows applied to the equipment used for the identification of hazardous for the production of water-based chemicals and the communication paints, where all equipment needs of these hazards to users through to be cleaned properly, disinfected labelling. It also provides the basis and additionally protected by a for safety data sheets regulated bactericide. Plant hygiene is also under the REACH regulation and subjected to special yearly audits that sets requirements for the packaging prove the efficiency of our procedures. of hazardous chemicals. Under this legislation, certain biocidal active Hygienic coatings substances have been reclassified in IN COOPERATION WITH OUR EXTERNAL PARTNER MICROBIUM, WE ARE Impregnations for wood causing the decay of the paint film that In hygiene-sensitive areas, such the last years in a way that they can DEVELOPING SEVERAL FORMULATIONS WHICH DO NOT CONTAIN ANY As wood is a live substrate, influenced results in a poor aesthetic appearance. as healthcare and pharmaceutical no longer be used or that the allowed IN-CAN PRESERVATIVES. by humidity and different mechanical Indoors, harmful micro-organisms can facilities, there is a need for effective quantity should be significantly stress, it needs to be properly protected. also be spread into the air, causing health hygiene coatings. These paints destroy reduced. This applied especially to SPEKTRA INTERIOR WALL PAINTS CONTAINING NEW MIT-FREE IN-CAN To avoid deterioration and extend the problems. This can be prevented by adding dangerous bacteria, viruses, and fungi, our DIY products for which we had to PROTECTION, THANKS TO WHICH NO CHANGE IN THE LABELLING WAS life of wood, impregnations containing fungicides and algicides to the paint, which which are present in the air, walls find new biocidal ways. In addition to MADE. AT THE SAME TIME SLIGHTLY HIGHER LEVELS OF MIT-FREE IN-CAN a well-defined mixture of fungicides, temporarily very effectively decreases the or ceilings, providing easy-to-clean all the necessary tests, the labelling of PROTECTION IN OUR FACADE PAINTS AND LEVELLING COMPOUNDS algicides and insecticides are in use. growth of micro-organisms. Paints with surfaces that comply with the rigorous products had to be changed as well. • RESULTED IN NEW LABELLING. When developing this type of biocidal dry-film protection are not submitted to the formulations, producers need to follow authorisation process of biocidal protection strict regulative requirements and the as their primary function is to protect the formulations have to be authorised as such. substrate. They are defined in the BPR as For this purpose, an extensive dossier has »treated articles«, which is why producers to be prepared, comprising of physical, must label them with a description of chemical, toxicological and efficiency data active substances and a claim that the paint for each individual formulation. Only after contains dry-film protection. the formulation is authorised and approved by all the EU members, it can be produced Disinfectants and sold on EU markets. Any change of the Disinfectants contain one or more active authorised formulation needs be approved substances with a very broad antimicrobial again, as according to BPR, this represents a activity. They destroy fungi, algae, lichens, new biocidal product. bacteria and yeast. Therefore, they are very effective for the disinfection of surfaces Paints containing dry-film protection attacked by any microbial growth. These TO PREVENT WOOD DETERIORATION, WOOD SURFACES NEED TO BE External and internal painted surfaces, products are not suitable as an additive to THE AUSTRIAN COATINGS INDUSTRY HAS LAUNCHED THE NEW INCANPRES PROJECT TO RESEARCH NEW APPROACHES PROTECTED WITH IMPREGNATION THAT CONTAINS A WELL-DEFINED which are exposed to high humidity, are the paint as they act directly on the infected TO IN-CAN PRESERVATION. THE INCANPRES INNOVATION PROJECT WILL INVESTIGATE A BROAD SPECTRUM OF ALL HELIOS RENDERS AND SOME OF OUR FACADE PAINTS, WOOD STAINS, MIXTURE OF FUNGICIDES, ALGICIDES AND INSECTICIDES. usually attacked by fungal and algal growth, surface and lose their activity when mixed POSSIBILITIES TO PREVENT IN-CAN SPOILAGE. ENAMELS AND INTERIOR WALL PAINTS CONTAIN DRY-FILM PROTECTION. 30 31
PROGRESS A smart thermal A healthy and friendly living space eliminates the conditions for mold be sanded. For the top coat we Mold is not only an aesthetic growth. SPEKTRA Termo Top thus recommend SPEKTRA Termo Top, problem; it is primarily a harmful creates a human-friendly living which further helps to reduce the phenomenon. Inhaling mold space with a positive impact on transfer of heat through the wall insulation system spores present in such spaces can health. SPEKTRA interior putty and retain heat. In addition, it also cause inflammation in the lungs, Termo contains less than 1 g/l of helps regulate the room’s humidity coughing, difficulty breathing and volatile substances, so emissions and reflects more than 90% of the can exacerbate asthma. When during application and drying are visible spectrum of light back into such wall surfaces are treated with minimal. Its elasticity also makes the room, creating more light. SPEKTRA interior putty Termo up its suitable for covering small The interior wall paint SPEKTRA Cirila Colnar Mikeln to 4 mm thick, the heat transfer cracks on wall surfaces. Termo Top is available in light through them is significantly Before the final paint, we shades, and the system is also For DIY users, the development of paints for the decorative protection of mineral, wood and metal surfaces has long been reduced. The walls remain warm, recommend a layer of the levelling compatible with any other interior preventing condensation of water compound SPEKTRA Level Fine, wall paint from the SPEKTRA focused on the use of the most people and environmentally friendly raw materials possible. vapor from the air, which in turn which is easy to apply and can family. • D ue to a lack of knowledge in Development is to some extent guided Top in combination with SPEKTRA interior handling coatings, non-professional by legislation, but we also develop products putty Termo form a thermal barrier, users are most exposed to their with added value, with properties that thanks to which the surface is warmer and potential harmful effects. European in various ways contribute to effective, more pleasant to the touch. This is made SPEKTRA TERMO TOP CREATES A HUMAN-FRIENDLY legislation protects non-professional users very well with various regulations and economical, health and nature-friendly solutions for the decorative protection of possible by the hollow fillers found in both products. The system keeps rooms cool in LIVING SPACE WITH A POSITIVE IMPACT ON HEALTH. laws, as it prohibits the use of carcinogenic, wall, wood or metal surfaces. The toolkit of the summer and warm in the winter, which mutagenic and reprotoxic substances in HELIOS' sustainable solutions in the field significantly decreases the cost of energy such paints. Any substance classified as of architectural coatings includes thermal sources for heating and cooling. Using hazardous must be properly labeled on insulation interior wall coatings, which the system of both products effectively the packaging. In addition to H-phrases, combine the coating’s decorative and prevents the formation of condensation which describe the hazards due to certain functional properties at the highest level. and consequently also the formation of substances in the coating, P-phrases on the mould. At the same time, their use avoids packaging represent instructions on how to Thermal insulation interior wall coating the frequent use of disinfectants and protect or act to prevent any harm. The interior wall coating SPEKTRA Termo renovation. REDUCES HEAT TRANSFER THROUGH THE WALLS. REFLECTS MORE THAN 90% OF LIGHT BACK INTO THE ROOM. PARTIAL SAVINGS IN HEATING, COOLING AND LIGHTING COSTS. SPEKTRA TERMO TOP AND SPEKTRA INTERIOR PUTTY TERMO 32 33
PROGRESS Reusing CO2 greenhouse gas emissions, and the increase POSSIBILITIES OF USING CAPTURED CO2 Fuels Food in the energy efficiency of facilities that • Flavours/Fragnances • Decaffeination have obtained a greenhouse gas emissions • Algae permit. Fuel price parities, especially of • Greenhouse gases NT TA to produce coal and natural gas, electricity prices and AC Carbonated beverages TR Carbonates EX demand for it are also important factors. BIOLOGICAL N FO DU IO PR CONVERSION AT Liquid OD CT O LIZ / S ERA fuels N MI • Methanol Objectives and responsibilities of CAPTURED • EOR ENHANCED • Oil • Urea • EGR FUEL • Gas CHEMICALS • CO Fertilizer companies involved in trading CO2 • ECBM green products RECOVERY • Methane Trends in European policy and the economy TICS REFR Secondary PLAS IGER chemicals ANT look at reducing CO2 emissions as much INERTING MI ON SC SI AGENT as possible. These can be a significant PRES EL LA NE Polycarbonate SU OU cost for companies, which have to reduce polymers FI RE S • Refrigeration • Blanket products • Dry Ice their carbon footprint while maintaining • Protection for carbon powder • Shield gas in welding Matija Mencinger production capacity. EU ETS trading leaves it up to companies to assess how • Injected into metal castings Fire extinguishers • Respiratory stimulant (added to medical O2) many emissions they can afford based The European Union has introduced emissions trading system years ago with the aim to on what is financially viable. At the same • Aerosol can propellant • Dry ice pellets used for sand blasting • Red mud carbonation strategically reduce carbon dioxide emissions. Belinka Perkemija is one among more than time, it equates the costs of reducing GHG emissions across the EU by allowing cross- 11,000 companies from all over Europe taking part in the system. Next to emissions reduction, border trade. This minimizes restrictions on Carbon capture and storage technologies companies that choose to capture their the company has identified CO2, formed as by-product in the production of hydrogen peroxide, competition between companies, operators In the coming trading period from 2021 CO2. Through various processes, emissions of facilities that produce GHG emissions onwards, a combination of new carbon caught and stored are then deducted as a product with wide use value. in the European single market. Last but capture and storage (CCS) technologies will from the amount of emissions produced not least, the aim of the system is to help also be available to companies involved in a company. A smaller final amount of reduce GHG emissions in the future and to the EU ETS. This technology captures up emissions allows savings on permits and A reward innovation in reducing emissions. to 90% of CO2 emissions produced from consequently on costs. BY REUSING OR INCORPORATING s part of its climate and energy policy, in October 2014 the contribute to the reduction of GHG emissions. The most cost-effective way Companies must obtain a GHG emissions the use of fossil fuels in industrial processes THE CO2 IN NEW PRODUCTS, European Council has adopted to achieve such goal is through the EU permit before they start operating, and must regularly monitor emissions, produce or electricity production, and prevents CO2 from entering the atmosphere. The Possibilities to incorporate CO2 in green products a binding agreement that the Emissions Trading System (EU ETS). In BELINKA PERKEMIJA European Union will achieve a minimum Slovenia, 49 companies are included in the an annual report and hand over the EU also offers significant subsidies for the At Belinka Perkemija, carbon dioxide, 40% reduction in greenhouse gas (GHG) system. In addition to Belinka Perkemija, a appropriate number of emission allowances. installation of CCS-enabled facilities for which is formed as a by-product in the CONTRIBUTES TO THE CARBON emissions by 2030 compared to 2005. company part of the HELIOS, there are also production of the otherwise green and widely used chemical hydrogen peroxide, FOOTPRINT REDUCTION. All economic sectors are expected to thermal power plants and heating plants, producers of steel, glass, ceramics, cement, has been identified as a product with wide lime and paper, and others. use value. Direct CO2 emissions formed in the companies’ industrial processes can FLUCTUATING MARKET PRICES OF EMISSIONS ALLOWANCES OVER THE TRADING PERIODS The EU Emissions Trading System be captured and processed or liquefied The EU ETS consists of trading permits for using special processes. By reusing or ICE EUA FUTURES REAL PRICE greenhouse gas emissions and entered into incorporating the CO2 in new products, force with the first trading period in 2005; Belinka Perkemija is consequently the third trading period will end in 2020. THE CO2 LIQUEFACTION PROCESS contributing to reducing the carbon The basic trading unit in the EU ETS is the footprint. CO2 enables processing to food emissions allowance, which represents industry purity and use instead of natural 1 tonne of carbon dioxide emitted into the sources, whose emissions are similar GREEN atmosphere. In the event of a deficit or METHANOL to those from synthetically produced surplus of emissions allowances, companies (OR DERIVATIVES) products. At Belinka Perkemija, experts participating in the EU ETS can buy or sell are actively working on the development permits on the exchange. and possibilities of incorporating CO2 in The price of emissions allowances is new green products in addition to further influenced by factors such as the number RENEWABLE POWER supplementing the capacities of the existing OR BYPRODUCT CRI CO2 liquefaction process. • of emission allowances allocated free of HYDROGEN EMISSIONS TO LIQUIDS Source: Wikimedia Commons. charge, the cost of measures to reduce TECHNOLOGY 34 35
PROGRESS SUCCESS “Action is the foundational key to all success.” Pablo Picasso Painter 36 37
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