Weed Control Recommendations for Kentucky Grain Crops

Page created by Matthew Bowers
 
CONTINUE READING
AGR-6                                                                                                                              University
                                                                                                                                     University of
                                                                                                                                                of Kentucky
                                                                                                                                                   Kentucky
                                                     2021                                                                            College
                                                                                                                                     College of
                                                                                                                                     Food
                                                                                                                                     Food and
                                                                                                                                             of Agriculture,
                                                                                                                                                Agriculture,
                                                                                                                                          and Environment
                                                                                                                                               Environment
                                                                                                                                     Cooperative
                                                                                                                                     Cooperative Extension
                                                                                                                                                 Extension Service
                                                                                                                                                           Service

       Weed Control
     Recommendations
 for Kentucky Grain Crops

Cooperative
Cooperative Extension
            Extension Service
                      Service || Agriculture
                                 Agriculture and
                                             and Natural
                                                 Natural Resources
                                                         Resources || Family
                                                                      Family and
                                                                             and Consumer
                                                                                 Consumer Sciences
                                                                                          Sciences || 4-H
                                                                                                      4-H Youth
                                                                                                          Youth Development
                                                                                                                Development || Community
                                                                                                                               Community and
                                                                                                                                         and Economic
                                                                                                                                             Economic Development
                                                                                                                                                      Development
NOTICE
                       Kentucky Agriculture Water Quality Act
In 1994, the Kentucky General Assembly passed The Kentucky Agriculture Water Quality Act
(AWQA). The AWQA (KRS 224.71-100 through 224.71-140) states that landowners of 10 acres or
more that conduct or allow agriculture or silviculture (forestry) production on their land were
required to develop and implement a water quality plan by October 23, 2001.

These individual water quality plans will be based upon the guidance found in the Kentucky
Agriculture Water Quality Plan. One of the six sections that make up the Kentucky Agriculture
Water Quality Plan is Pesticides and Fertilizer (Section 2). Therefore, if your agriculture operation,
of 10 acres or more, involves the use and storage of agriculture chemicals, then your water quality
plan must include information about those pesticide and fertilizer activities.

In an effort to help landowners/producers more effectively develop and implement the Pesticides
and Fertilizer section of their water quality plan, the Extension publication Agricultural Chemical
Storage and Handling (IP-41) is available at your local County Extension Offices. This publication
is one of several that make up the Kentucky Assessment System or KY.A.Syst.

For further information about the Kentucky Agriculture Water Quality Act, the sections of the Plan
and the KY.A.Syst publications that apply to your situation, contact your local:

    •   University of Kentucky Cooperative Extension Service County Office
    •   Division of Conservation
    •   Division of Water Regional Office
    •   USDA Natural Resource Conservation Service
    •   USDA Farm Service Agency
    •   Division of Forestry District Office
    •   Local Conservation District Office
    •   County Health Department
    •   Kentucky Farm Bureau Federation

                                    Conversion Factors
  Liquid Measure                                                      Dry Measure
  3 teaspoons = 1 tablespoon = 14.8 ml                                1 pound=16 ounces=454 grams
  1 fluid ounce = 2 tablespoons = 29.6 ml                             1 short ton = 2000 pounds = 908 kg
  1 pint = 2 cups = 16 fluid ounces = 473.2 ml                        1 long ton = 2240 pounds = 1017 kg
  1 quart = 2 pints = 4 cups = 32 fl. oz. = 946.4 ml
  1 gallon = 4 quarts = 8 pints = 16 cups =128 fl. oz = 3786 ml       Linear Measure
  1 gallon = 3.79 liters = 8.355 pounds                               12 inches = 1 foot = 30.5 cm
  1 cubic foot of water = 62.43 pounds = 7.48 gallons                 36 inches = 3 feet = 1 yard = 0.9 meters
                                                                      1 rod = 16.5 feet
  Area Measure                                                        1 mile = 5280 feet = 1760 yards =1.6 km
  1 acre = 43,560 sq ft = 160 sq rods = 4840 sq yd = 0.4ha

    The information provided in this publication is for general guidance in selection of herbicide products.
    Always consult the product labels for proper application of herbicides, precautions and any restrictions.

  Listing of pesticide products implies no endorsement by the University of Kentucky or its representatives.
                         Criticism of products not listed is neither implied nor intended.
TABLE OF CONTENTS
INTRODUCTION ............................................................. 4            GRAIN SORGHUM .......................................................65
 Method and Time of Herbicide Treatment .................... 4                           Preemergence ............................................................. 65
 Incorporation ................................................................. 4       Preplant or Preemergence ..........................................66
 Cultivation ...................................................................... 4    No Tillage .................................................................... 67
 Types of Herbicide Formulations .................................. 5                    Postemergence ...........................................................68
 Restricted Use Herbicides ............................................. 5
 Environmental & Safety Precautions (WPS) ................. 5
 Water Quality Statements ............................................. 5               SOYBEANS .................................................................. 70
 Herbicide Classification ................................................. 6            Preplant “Burndown” Herbicides for No-Till Soybean .70
 Herbicide Resistance .................................................... 6             Preplant Foliar “Burndown” plus Residual Herbicides.75
 Tank Mixtures & Sequential Applications ...................... 6                        Relative Response of Cover Crops and Weeds to
 Herbicide Mode of Action Groups ................................. 7                        Burndown Herbicides (Table) .................................81
 Relative Risk of Developing Herbicide Resistance ....... 8                              Guide to Weed and Crop Response to Soil
 Adjuvants and Additives ................................................ 9                 Applied Herbicides (Table) .....................................82
 Weed Sprayers.............................................................. 9           Soil Applied Herbicides ...............................................83
 Sprayer Calibration ....................................................... 9           Guide to Weed and Crop Response to
 Sprayer Cleanup ........................................................... 9              Postemergence Herbicides (Table) ........................95
 Nozzles ........................................................................ 10     Guide for Maximum Weed Size Labeled for
 Nozzle Calibration Chart ............................................. 10                  Postemergence Herbicide Applications (Table) .....96
 Herbicides, Formulations and Manufacturers ............. 11                             Postemergence Soybean Herbicides, Adjuvants,
 Glyphosate Products ................................................... 21                 Crop Growth Stage, and Rain-Free Periods ..........98
                                                                                         Response of Perennial Broadleaf Weeds to
CORN ........................................................................... 22         Postemergence Soybean Herbicides (Table) ......100
 Precautions on Use of Herbicides Containing Atrazine                                    Postemergence Herbicides .......................................101
    and Simazine Near Ground and Surface Water .... 22                                   Spot Treatments ........................................................113
 Crop Replanting and Volunteer Corn .......................... 23                        Preharvest ................................................................. 114
 Preplant “Burndown” Herbicides for No-Till Corn ........ 24
 Preplant Foliar “Burndown” plus Residual Herbicides 27
 Relative Response of Cover Crops and Weeds to                                          SMALL GRAINS .........................................................115
    Burndown Herbicides (Table)................................. 32                      Preplant “Burndown” Herbicides for No-Till Wheat ...115
 Guide to Weed and Crop Response to Soil                                                 Preplant Soil-Residual Herbicides for No-Till Wheat.116
    Applied Herbicides (Table) ..................................... 33                  Preemegence Herbicides for Ryegrass ....................117
 Soil Applied Herbicides ............................................... 34              Guide to Weed and Crop Response to Herbicides ...118
 Guide to Weed and Crop Response to                                                      Timing of Postemergence Herbicides Relative to
    Postemergence Herbicides (Table) ....................... 43                            Wheat Growth Stages (Figure)..............................118
 Guide for Maximum Weed Size Labeled for                                                 Postemergence .........................................................119
    Postemergence Corn Herbicides ........................... 44                         Preharvest ................................................................. 124
 Corn Growth Stages, Adjuvants, and
   Rain-Free Periods (Table)....................................... 46
 Response of Perennial Broadleaf Weeds to
    Postemergence Corn Herbicides (Table) ............... 47                            Waiting Period Before Utilizing Corn for Grazing
 Postemergence Herbicides ......................................... 48                      or Forage Feed .....................................................125
 Preharvest or Harvest Aid .......................................... 63                Waiting Period Before Utilizing Soybeans for
 Postharvest Applications ............................................. 64                  Harvested Grain or Forage Feed ........................126
                                                                                        Crop Replanting and Rotation Guidelines ...................127
                                                                                        Pesticide Application Records .....................................138
                                                                                        Pesticide Emergency Information................................140
4

    2021 Weed Control Recommendations for Kentucky Grain Crops
                                            Travis Legleiter and J.D. Green

                Introduction                                               1) Before Planting-- preplant soil incorporated,
                                                                  preplant surface applied, preplant foliar as a “burndown”
                                                                  of existing vegetation, or early preplant (usually 7 to 30
          The use of herbicides suggested in this publication     days before planting)
is based on research at the Kentucky Agricultural                          2) After Planting (before crop and weed
Experiment Station and elsewhere. We have given what we           emergence) -- preemergence onto the soil surface;
believe to be the most effective herbicides, with the most                 3) After Crop and Weed Emergence -- cracking
suitable rates and times of application. Use of trade or          stage (at crop emergence), postemergence, directed or
brand names in this publication does not imply approval of        semi-directed between the rows of taller crops on small
the product to the exclusion of others which may be of            weeds, or layby before crop canopy.
similar or suitable composition.                                           Herbicides used in no-tillage crop production
          Herbicide registrations and labels are constantly       generally consist of a foliar "burndown" herbicide plus a soil
being revised and changed; therefore, herbicides                  residual. A non-selective foliar herbicide is applied before or
recommended in this publication were registered for the           at planting, but before crop emerges to kill all existing
prescribed uses when the publication was printed. If the          vegetation. Soil residual herbicides provide additional weed
registration of a herbicide product listed has been canceled,     control throughout the growing season.
it would no longer be recommended by the University of
Kentucky.                                                                             Incorporation
          Read and follow label directions carefully
before you buy, store, mix, apply, or dispose of a pesticide.               Proper application of any preplant and
Follow carefully the precautions stated on the label of the       incorporated herbicide is extremely important. A well-
bag or container. It is hazardous to use herbicides for           prepared seedbed prior to application of the herbicide is
purposes other than those specified on the approved label.        necessary to obtain thorough mixing (incorporation) of the
Use herbicides only on crops for which they are approved          chemical into the soil. It is advisable to incorporate
and recommended. Use only recommended amounts.                    thoroughly immediately after spraying, preferably in the
Besides wasting money, using too much material may                same operation. Delayed incorporation could result in poor
damage the crop and make it unsafe for food or feed. The          weed control.
seizure of any raw agricultural commodity, moving in                        Incorporation into the top 2 to 3 inches of soil
interstate commerce, which carries a pesticide residue in         following seedbed preparation is necessary to ensure
excess of the established tolerance, is authorized by the         effective weed control regardless of weather conditions.
Environmental Protection Agency.                                  Incorporation should be made using power-driven
          Apply herbicides only at time specified on the label,   cultivation equipment set to cut to a depth of 2 to 3 inches,
and observe the recommended intervals between the time            or a tandem disc set to cut to a depth of 4 to 6 inches,
of treatment and time of planting, pasturing or harvesting        operated at 4 to 6 mph. This should be followed by a spike-
the crop.      Guard against possible injury to nearby            tooth harrow or some other leveling tillage equipment which
susceptible crops or plants.                                      extends beyond the ends of the disc. Incorporation to a
          In general, the use of herbicides should                depth below 3 inches will reduce effectiveness of the
supplement good agricultural practices which include:             herbicide by one-third or more.
1) the use of high quality crop seed free of weed seed;                     For thorough mixing, disc in two different directions
2) proper planting methods with good seed to soil contact;        (cross disc). Thorough incorporation to a depth of not more
3) high soil fertility and good crop rotation; and                than 2 to 3 inches of a preplant-incorporated herbicide may
4) practices that prevent weeds from producing mature             be the most important part of a management program.
seeds.
                                                                                         Cultivation
      Method and Time of Herbicide                                          Timely, shallow cultivation may be necessary
               Treatment                                          following herbicide treatment.       When cultivating, the
                                                                  cultivator should be set as shallow as possible. This will
         Herbicides are generally considered to be either
                                                                  prevent bringing new weed seeds from below the herbicide
soil active or foliar active. Soil active herbicides are
                                                                  layer to the soil surface.
generally applied to the soil surface since they are most
                                                                            If rainfall does not occur within 7 to 10 days
effective when weeds are germinating. Foliar active
                                                                  following application of a preemergence herbicide, a
herbicides control weeds after they have emerged from the
                                                                  shallow incorporation such as with a rotary hoe may be
soil.
                                                                  necessary for maximum weed control.
         Herbicides can also be applied at different times for
                                                                            Cultivation following a preplant-incorporated
weed control. They are applied either before or after crop
                                                                  herbicide application should also be shallow, or less than
planting. The timing of the application is dependent on: a)
                                                                  one half the depth that the herbicide was incorporated.
the herbicide characteristics; b) weed(s) to be controlled;
and c) crop being grown. The following terms are often
used that refer to the time of herbicide application:
5

    Types of Herbicide Formulations                               practices. WPS requires pesticide safety training for
                                                                  workers and handlers, display of safety posters, and access
          Herbicides are formulated as water solutions (S),       to labeling and other specific information at a central
liquids (L), emulsifiable concentrates (EC), dry flowables        location. Further protection is ensured by excluding
(DF), soluable granules (SG), water dispersible granules          workers from areas being treated with a pesticide, REI
(WDG), wettable powders (WP), flowables (F), or micro-            (Restricted-Entry     Intervals)  following   a    pesticide
encapuslated (MT, ME),. They are usually added to water           application, and proper use of PPE (Personal Protective
and applied as a spray solution. Most spray mixtures              Equipment). REI's and protective clothing requirements are
require constant agitation to prevent the herbicides from         listed on the pesticide label.
settling to the bottom of the tank. Granular (G) herbicides
are applied dry. Do not mix granular herbicides with                        Water Quality Statements
different granular pesticides or fertilizers.
                                                                  The potential for contamination of surface and/or ground
          Restricted Use Herbicides                               water has become an important consideration when
                                                                  choosing herbicides. Several products have groundwater
         Some herbicide products are classified as                advisory statements on their label. Such statements advise
Restricted Use Pesticides because they have a higher              not to apply these herbicides where the water table
potential for affecting the environment, human health, or         (groundwater) is close to the surface and where the soils
animals. Herbicides currently classified as Restricted Use        are very permeable (i.e. well drained soils such as sands,
appear below.        Pesticide certification is required to       sandy loams, or loamy sands). Refer to these statements
purchase and use these products.                                  and observe all precautions on the label when using these
 AAtrex               Degree Xtra          Marksman               products. Listed below are examples of herbicide products
 Atrazine             Engenia              Metal II AT            with active ingredients which have been identified as
 Acuron               Expert               Milo-Pro
 Balance Flexx        FeXapan              Parallel Plus
                                                                  seeping or leaching through soil and can enter
 Anthem ATZ           Firestorm            Parazone               groundwater.
 Authority MTZ        FulTime              Prequel                 *AAtrex             Dimetric Charge     Panther Pro
 Brawl II ATZ         Gramoxone            Radius                  *Atrazine           Dual II Magnum      *Parallel Plus
 Breakfree            Guardsman Max        Simazat                 *Acuron             *Expert             Perpetuo
 Breakfree ATZ        Harness Xtra         Tavium                  Alite 27            Extreme             Prequel
 Callisto Xtra        Impact Z             Trizmet II              Anthem              Fierce              Prefix
 Charger Max ATZ      Keystone             Volley                  *Anthem ATZ         Fierce MTZ          *Princep
 Cinch ATZ            Lexar EZ             Volley ATZ              Anthem Maxx         Fierce XLT          Pursuit
 Callisto Xtra        Lumax EZ             Xtendimax               Authority Assist    FirstRate           Python
 Corvus               Keystone                                     Authority Edge      Flexstar            Realm Q
         Current regulations require that accurate records         Authority Elite     *FulTime            Resicore
                                                                   Authority First     Glory               Sequence
be kept for all pesticides which include Restricted Use            Authority MTZ       *Guardsman Max      Sharpen
Pesticides as well as those classified as General Use              Authority Supreme   Halex Gt            *Simazat
Pesticides. An applicator must make a written record within        Authority XL        Harness             Status
30 days after the application. Records to keep include             Balance Flexx       Harness MAX         Sonic
product name and EPA registration number, total amount             *Bicep II Magnum    *Harness Xtra       SureStart
                                                                   Boundary            Hornet WDG          Surveil
applied, location, crop or site of application, size of treated    *Brawl II ATZ       Impact Core         TopNotch
area, name and certification number of applicator or               Breakfree           *Impact Z           TriCor
supervisor, and date of application.                               *Breakfree ATZ      Instigate           Trivence
                                                                   Broadaxe XC         Intimidator         TripleFLEX
            Environmental & Safety                                  Callisto           *Keystone           Tripzin ZC
                                                                   *Callisto Xtra      Kyber               *Trizmet II
              Precautions (WPS)                                    Canopy              Laudis              UltraBlazer
                                                                   Charger Max         *Lexar EZ           Valor
         Proper use of herbicides and other pesticides is          *Charger Max ATZ    *Lumax EZ           Valor XLT
important to the safety of humans and the environment.             Cinch               *Marksman           Verdict
Pesticide labels contain precautionary statements to inform        *Cinch ATZ          Matador-S           Volley
                                                                   Confidence          *Medal II AT        *Volley ATZ
people of the potential hazards and safeguards associated
                                                                   *Confidence Xtra    Metribuzin          Warrant
with pesticides. The types of precautionary statements may         Corvus              OpTill              Warrant Ulta
vary depending on particular product and its use. Examples         *Degree Xtra        Outlook             Zidua
of issues that may require precautionary statements are: 1)       *Manufacturers of atrazine and simazine containing products
use of protective clothing, 2) exposure to domestic animals,      have developed strategies for limiting their movement to both
3) storage, 4) disposal of excess pesticides, rinsates and        ground and surface water. The maximum rate of these
containers, 5) toxicity to fish and wildlife, 6) groundwater,     products for early preplant, preplant incorporated, or
and 7) endangered species. To assure the pesticide is used        preemergence applications depends on soil erodibility, as
in a safe manner, it is important to read and follow the label    defined by the Natural Resources Conservation Service, and
directions.                                                       percent of ground covered with plant residue. A summary of
         Worker Protection Standards (WPS) were                   the label precautions and restrictions can be found at the
established to protect pesticide handlers and agricultural        beginning of the corn section in this publication.
workers.     This federal EPA regulation requires that
employees are informed about pesticide use and protection
6

         Tank Mixtures & Sequential                                             Herbicide Resistance
               Applications                                                  In recent years herbicide resistance has become
                                                                  an important issue to consider when making weed
          For broad spectrum weed control, more than one
                                                                  management decisions. Crops traditionally susceptible to
herbicide may be necessary. In this publication we have
                                                                  some herbicides are being developed which are tolerant
included only formulations or tank mixtures registered with
                                                                  (i.e. resistant) to specific herbicides. For example, soybean
the EPA by the manufacturer.
                                                                  varieties and corn hybrids resistant to glyphosate products
          When tank mixing two or more herbicide products
                                                                  are now available to producers.
it is important to consult the product(s) label to determine if
                                                                             On the other hand, herbicide resistance can occur
potential problems may occur. Often a jar test may be
                                                                  and develop from natural weed populations. For example,
required to determine if the products are compatible in the
                                                                  resistance of smooth pigweed to triazine type herbicides
spray tank. Some tank mixtures or herbicide combinations
                                                                  (i.e. Atrazine and Princep) has been found and documented
can reduce weed control activity (i.e. they are
                                                                  in some localized areas of Kentucky where corn is grown in
antagonistic); whereas, other tank mixes will increase the
                                                                  consecutive years. Other states have also reported weed
weed control activity (i.e. synergistic). The potential for
                                                                  resistance in field crops following the continuous use of
crop injury is sometimes increased by applying two or more
                                                                  certain herbicides. The potential for weed resistance to
herbicides to the same crop.
                                                                  develop increases with continuous use of herbicides that
          In addition to combining herbicides, sequential
                                                                  have the same mode of action (i.e. similar chemistry).
herbicide applications are used to provide season-long
                                                                  Therefore, herbicide use should be monitored and
weed control. These applications may consist of an early
                                                                  production practices implemented to prevent and reduce
pre-plant herbicide treatment followed by an application of
                                                                  the potential for weed resistance to occur.
a soil-applied herbicide at planting or a herbicide treatment
                                                                             A key to avoiding development of herbicide
before or at planting followed by a postemergence herbicide
                                                                  resistant weed populations is prevention. Listed below are
application later in the season after the crop has emerged.
                                                                  management strategies to consider in preventing and
When using herbicides in sequential treatments, extreme
                                                                  dealing with herbicide resistant weeds.
care should be taken to keep within the recommended rates
for each herbicide. In addition, rotational crop options may            • Scout fields regularly and identify weeds present.
be reduced when herbicides with similar modes of action                      Respond quickly to shifts in weed populations to
are applied the same crop season.                                            restrict spread of weeds.
                                                                        • Select a herbicide based on weeds present and
            Herbicide Classification                                         use a herbicide only when necessary.
                                                                        • Rotate crops. Crop rotation helps disrupt weed
          Herbicide mode of action can be defined as the                     cycles and some weed problems are more easily
mechanism whereby a herbicide interferes with plant                          managed in some crops than others.
metabolism or function that inhibits plant growth or leads to           • Rotate herbicides.             Avoid using the same
plant death. Herbicides are often classified according to                    herbicide or another herbicide with the same mode
their mode of action, since herbicides within the same mode                  of action (i.e. herbicides that inhibit the same
of action class will typically produce similar symptoms on                   process in target weeds) for two consecutive years
susceptible plants. The major mode of action categories                      in a field. It is possible for a herbicide used in one
include: ACCase inhibitors, ALS inhibitors of amino acids,                   crop to have the same mode of action as a different
synthetic auxins (growth regulators), photosynthesis                         herbicide used in another crop. For example:
inhibitors (photosystem II), EPSP synthetase enzyme                          Accent, Classic, Harmony Extra, Harmony SG,
inhibitors, glutamine sythetase inhibitors, pigment inhibitors               Lightning, Scepter, Option, Osprey, Permit,
(carotenoid biosynthesis and 4-HPPDs), cell membrane                         Pursuit, Spirit, Python, Resolve, Steadfast, Stout,
disruptors (photosystem I and PPO inhibitiors), microtubule                  and Synchrony “STS” contain active ingredients
assembly inhibitors (root growth inhibition), and cell division              with the same mode of activity in plants (i.e. these
(seedling shoot growth inhibitors). The following tables list                herbicides are ALS/AHAS inhibitors).
these herbicide groups with representative examples of                  • Apply herbicides with different modes of action
herbicide products within each classification and general                    as a tank mixture or sequential application during
information on how they function to interfere with plant                     the same season.
growth.                                                                 • Combine other weed control practices such as
                                                                             cultivation with herbicide treatments where soil
                                                                             erosion potential is minimized.
                                                                        • Clean tillage and harvest equipment to avoid
                                                                             moving weed problems from one field to the next.
Herbicide Classification By Mode of Action Groups
Group                                                      Herbicide               Site of           Plant
CODE            Herbicide Classification                   Examples                Uptake          Selectivity          Translocation            Symptomology
          ACCase Inhibitors (lipid synthesis)                                                                                                Growing point rots at the
                                                                                                                         phloem mobile
  1       *Aryloxyphenoxy propionates               Axial XL, Assure II, Fusion,   foliage           grasses                                 nodes, new leaves pull
                                                                                                                          (with sugars)
          *Cyclohexanediones                               Select, Poast                                                                     out easily
          ALS Inhibitors                                                                                                                   Chlorotic new growth,
                                                                                                                        phloem mobile
            (amino acid synthesis)                                                                                                         shortened internodes,
                                                        Scepter, Pursuit,            soil      selected broadleaves      (with sugars);
  2        * Imidazolinones                                                                                                                reddened veins on
                                                    Accent, Classic, Harmony          or            or grasses        xylem mobile in soil
           * Sulfonylureas                                                                                                                 soybeans, yellow flash in
                                                       FirstRate, Python           foliage                                   uptake
           * Sulfonamides                                                                                                                  corn, bottle brush roots
          Microtubule Assembly Inhibitors
                                                                                                grasses more than            minimal         Stunting and clubbed root
  3          (root growth inhibitor)                      Prowl, Treflan             soil
                                                                                                   broadleaves              transport        tips
              * Dinitroanalines
          Synthetic Auxins (Growth Regulator)                                                                                                Distorted growth of new
   4      • Phenoxy acids                                      2,4-D                foliage                              phloem mobile
                                                                                                   broadleaves                               leaves, callus growth on
          • Benzoic acids                              dicamba [Clarity, etc]      primarily                              (with sugars)
          • Pyridine carboxylic acids                     Starane, Vista                                                                     stems
          Photosynthesis Inhibitors [PS II]               Binding Site A
  5           * Triazines                                Atrazine, Princep
              * Triazinones                                   Sencor                                                                         Contact burn of existing
                                                                                      soil
                                                          Binding Site B                        broadleaves more         xylem mobile        leaves, chlorosis of oldest
                                                                                       or
  6         * Benzothiadiazinones                            Basagran                             than grasses         (moves with water)    leaf margins of seedlings
                                                                                    foliage
            * Nitriles                                        Buctril                                                                        if soil uptake
                                                          Binding Site C
  7
             * Phenylureas                                     Lorox
          EPSP Synthetase Inhibitor                                                                                                          Chlorotic new growth to
                                                                                                    generally            phloem mobile
  9        (amino acid synthesis)                     glyphosate [Durango,          foliage                                                  death depending on rate,
                                                                                                  non-selective           (with sugars)
           * Glycines                               Roundup, Touchdown, etc.]                                                                occassionally white flash
          Glutamine Synthetase Inhibitor                                                                                                     Chlorosis of entire plant in
  10                                                      Ignite, Liberty           foliage       non-selective         primarily contact
           (nitrogen metabolism)                                                                                                             4 - 5 days
          Carotenoid Biosynthesis                                                    soil or   grasses and selected      xylem mobile        Bleaching (whitening) of
  13                                                        Command
           (pigment inhibitor)                                                      foliage        broadleaves         (moves with water)    leaves
          PPO Inhibitors
           (cell membrane disruptors)                                                                                 xylem mobile (moves
                                                                                    foliage                                                  Contact burn of existing
             * Diphenylethers                         Blazer, Cobra, Flexstar                   broadleaves more      with water), acts as a
  14                                                                                   or                                                    leaves, chlorosis of veins
             * Triazolinones                          Aim, Authority, Spartan                     than grasses        contact when applied
             * N-phenylphthalamides                      Resource, Valor              soil                                   POST            if soil uptake
             * Pyrimidinedione                               Sharpen
          Cell Division Inhibitors                                                                                                           Leafing out under-ground,
           (seedling shoot growth inhibitors)          Harness, Surpass,                        grasses more than        xylem mobile        wrapped leaves of
  15                                                                                 soil
            * Chloroacetamides                        Warrant, Dual, Outlook,                      broadleaves         (minimal transport)   grasses, bugging
            * Oxyacetamides                               Define, Zidua                                                                      whipping
  19      Auxin Transport Inhibitor                    diflufenzopyr [Status]       foliage        broadleaves           phloem mobile                 -------
          Cell Membrane Disruptors [PS I]                                                                                    contact         Rapid water soaking of
  22                                                                               foliage        non-selective
           * Bipyridyliums                            paraquat [Gramoxone]                                                   activity        existing leaves
          4-HPPDs                                   Armezon, Balance, Callisto,    soil or     selected broadleaves xylem mobile (moves Bleaching (whitening) of
27 (28)
           (pigment inhibitors)                           Impact, Laudis           foliage          or grasses          with water)     existing leaves

                                                                                                                                                                            7
8
    Relative Risk of Developing Resistance to Herbicides Based on their Mode
                                    of Action

              HIGH RISK                                  MEDIUM RISK                                LOW RISK
ACCase Inhibitors [Group 1]                    Photosythesis Inhibitors – PS II         Microtubule Assembly Inhibitors
(Lipid Synthesis)                              (Binding Site A)     [Group 5]           (Root Growth Inhibitors) [Group 3]
  Achieve (tralkoxydim)                          AAtrex (atrazine)                        Prowl (pendimethalin)
  Arrow (clethodim)                              Glory (metribuzin)                       Treflan (trifluralin)
  Assure II (quizalofop)                         Milo-Pro (propazine)
  Axial (pinoxaden)                              Metri (metribuzin)                     Synthetic Auxins        [Group 4]
  Fusilade DX (fluazifop)                        Princep (simazine)                     (Growth Regulators)
  Fusion (fluazifop + fenoxaprop)                Sencor (metribuzin)                      Banvel (dicamba)
  Poast, Poast Plus (sethoxydim)                 Simazat (atazine + simazine)             Butoxone 175 (2,4-DB)
  Section, Volunteer (clethodim)               (Binding Site B)     [Group 6]             Butyrac 200 (2,4-DB)
  Select, Select MAX (clethodim)                 Basagran (bentazon)                      Clarity, Clash (dicamba)
                                                 Buctril (bromoxynil)                     2,4-D [various products]
ALS Inhibitors       [Group 2]                   Maestro (bromoxynil)                     DiFlexx (dicamba)
(Amino Acid Synthesis)                         (Binding Site C)     [Group 7]             Engenia (dicamba)
  Accent Q (nicosulfuron)                        Lorox (linuron)                          Enlist One (2,4-D choline salt)
  Accolade (flumetsulam)                                                                  FeXapan (dicamba)
  Audit (thifensulfuron + tribenuron)           Cell Membrane Disruptors                  Oracle, Sterling (dicamba)
  Basis (rimsulfuron + thifensulfuron)          (PPO Inhibitors)       [Group 14]         Spitfire (dicamba + 2,4-D)
  Basis Blend (rimsulfuron + thifensulfuron)      Aim (carfentrazone)                     Vista (fluroxypyr)
  Beacon (primisulfuron)                          Authority, Spartan (sulfentrazone)      Weedmaster (dicamba + 2,4-D)
  Bestow (rimsulfuron)                            Battle Star (fomesafen)                 XtendiMax (dicamba)
  Canopy EX (chlorimuron + tribenuron)            Cadet (fluthiacet-methyl)
  Classic (chlorimuron)                           Cobra (lactofen)                      EPSP Synthetase Inhibitors
  Cloak EX (chlorimuron+tribenuron)               Flexstar (fomesafen)                  (Amino Acid Synthesis) [Group 9]
  Crusher (rimsulfuron + thifensulfuron)          Marvel (fluthiacet+fomesafen)           Glyphosate [various products]
  Everest (flucarbozone)                          Outflank (flumioxazin)                  Roundup, Touchdown (glyphosate)
  Exceed (primisulfuron + prosulfuron)            Panther (flumioxazin)
  Express (tribenuron-methyl)                     Phoenix (lactofen)                             LOWEST RISK
  Finesse (chlorsulfuron + metsulfuron)           Reflex (fomesafen)
  FirstRate (cloransulam)                         Resource (flumicloric)                Glutamine Synthetase Inhibitors
  FirstShot SG (thifensulforon+tribenuron)        Ringside, Rumble (fomesafen)          (Nitrogren Metabolism) [Group 10]
  HarmonyExtra(thifensulforon+tribenuron)         Rowel (flumioxazin)                     Cheetah (glufosinate-ammonium)
  Harmony SG (thifensulfuron)                     Shafen, Shafen Star (fomesafen)         Forfeit 280 (glufosinate-ammonium)
  LeadOff (rimsulfuron + thifensulfuron)          Sharpen (salflufenacil)                 Ignite (glufosinate-ammonium)
  Osprey (mesosulfuron)                           Spartan Charge                          Interline (glufosinate-ammonium)
  Panoflex (tribenuron + thifensulfuron)                (sulfentrazone+carfentrazone)     Liberty (glufosinate-ammonium)
  Permit (halosulfuron)                           Stellar (lactofen + flumicloric)        Surmise (glufosinate-ammonium)
  PowerFlex (pyroxsulam)                          Top Gun (fomesafen)
  Pursuit (imazethapyr)                           Ultra Blazer (aciflurofen)            Cell Division Inhibitors [Group 15]
  Python (flumetsulam)                            Valor, Emcompass (flumioxazin)        (Seedling Shoot Growth)
  Raptor (imazamox)                               Vida (pyraflufen)                       Breakfree (acetochlor)
  Resolve SG (rimsulfuron)                     (Photosystem I)          [Group 22]        Harness (acetochlor)
  Resolve Q (rimsulfuron + thifensulfuron)        Firestorm (paraquat)                    Surpass, Topnotch (acetochlor)
  Sandea (halosulfuron)                           Gramoxone (paraquat)                    Warrant (acetochlor)
  Scepter (imazaquin)                             Helmquat (paraquat)                     Dual, Parallel (metolachlor)
  Solida (rimsulfron)                                                                     Dual II Magnum (S-metolachlor)
  Spirit (prosulfuron + primisulfuron)         Carotenoid Biosynthesis                    Medal II (S-metolachlor)
  Steadfast Q (rimsulfuron + nicosulfuron)     (Pigment Inhibiitor) [Group 13]            Outlook, Establish (dimethenamid-P)
  Synchrony (chlorimuron+ thifensulfuron)        Command (clomazone)                      Define (flufenacet)
                                                                                          Zidua (pyroxasulfone)
                                               4-HPPDs
                                               (Pigment Inhibiitor) [Group 27 (28)]
                                                 Armezon (topramezone)
                                                 Balance (isoxaflutole)
                                                 Bellum (mesotrione)
                                                 Callisto (meostrione)
                                                 Impact (topramezone)
                                                 Laudis (tembotrione)
9

           Adjuvants and Additives                                               Sprayer Calibration
                                                                            To be sure of applying the right amount of material
         An adjuvant is any substance included in the
                                                                  per acre, it is necessary to know how much liquid the
herbicide formulation which enhances the effectiveness of
                                                                  sprayer is delivering per acre at a given speed and
the herbicide.       Additives include adjuvants or other
                                                                  pressure. The following is a fast, simple method of
substances added to the spray mixture which may result in
                                                                  calibrating a sprayer for broadcast application.
increased or decreased effectiveness of the spray mixture
or for improving application. Products typically
                                                                  Ounce Calibration Method:
recommended for use with herbicides contain 80 to 90% of
                                                                     1) Measure the correct distance in the field shown in
the active agent. Additives include such substances as:
                                                                         the following table. Select the appropriate distance
     1) Emulsifier—a substance which promotes the
                                                                         for your nozzle or row spacing.
         suspension of one liquid or another
                                                                     2) In the field to be sprayed, note the time in seconds
     2) Surfactant—a material which favors or improves
                                                                         spent to drive the measured distance at the desired
         the emulsifying, dispersing, spreading, wetting or
                                                                         throttle setting (speed).
         other surface modifying properties of liquids
                                                                     3) Catch the nozzle discharge for the noted time
     3) Oil Concentrate—a blend of non-phytotoxic crop
                                                                         (#2 above) in a measuring cup or other container
         oils, surfactants and emulsifiers
                                                                         graduated in ounces.
     4) Wetting Agent—a substance that reduces
                                                                     4) The total discharge per row or nozzle spacing in
         interfacial tensions and causes spray solutions or
                                                                         ounces is equal to the gallons per acre applied.
         suspensions to make better contact with treated
                                                                     5) Repeat for each nozzle or nozzle group to ensure
         surfaces.
                                                                         equal distribution.
     5) Nitrogen Fertilizers—an ammonium containing
         fertilizer that enhances the uptake of certain post-
                                                                            SPRAYER CALIBRATION (Distance)
         emergence herbicides inside the cell wall (eg. 28%
         or 32% Urea Ammonium Nitrate or Ammonium
                                                                         Nozzle Spacing               Distance to Catch
         Sulfate)
                                                                            (inches)                   Discharge (feet)
     6) Drift Control Agent—a substance added to the
                                                                               40                            102
         spray solution to reduce the potential for off-site
                                                                               38                            107
         movement of spray particles.
                                                                               36                            113
                   Weed Sprayers                                               34
                                                                               32
                                                                                                             120
                                                                                                             127
         Even distribution of herbicides at the proper rate is                 30                            136
essential for good weed control. A small variation in the rate                 28                            146
of application of some herbicides may result in failure to kill                26                            157
weeds or may cause injury to the crop. For spray                               24                            170
applications of herbicides in farm crops, the low pressure                     22                            185
sprayer (15 to 50 pounds per square inch pressure) is most                     20                            204
suitable either for broadcast or band spraying. Hand                           18                            227
sprayers of 3 or 4-gallon capacity are suitable for small                      16                            255
areas and for spot spraying.                                                   14                            291

A good field sprayer should have:                                 Sprayer Cleanup
   1) a pump that is easily replaced, resistant to wear and                 Ideally spray equipment should be cleaned in the
      chemicals, and that has a capacity of 8 to 15 gallons       field after the spray job has been completed. Do not clean
      per minute;                                                 spray equipment in areas where rinse water will
   2) a boom equipped with nozzles with replaceable tips,         contaminate water supplies, streams, or injure susceptible
      the nozzles being evenly spaced on the bottom for           crops.
      broadcast spraying;                                                   Flushing of spray equipment with water will be
   3) 50-mesh screens for suction line and nozzles, and a         sufficient for removing potentially harmful amounts of many
      gauge that measures pressure accurately from 10 to          pesticides. However, there are certain groups of pesticides
      100 pounds per square inch; and                             such as a plant growth-regulator, sulfonylurea herbicides
   4) a mechanical or jet agitator to keep the spray well         and organophosphate insecticides that may require special
      mixed and prevent the herbicide from settling to the        attention in cleaning equipment. Special attention to clean
      bottom of the tank.                                         out procedures can be critically important when switching
                                                                  applications between crops to help avoid significant crop
       For row-band spraying, use an even, flat fan nozzle        injury. As a rule, a sprayer that has been used to apply 2,4-
such as a Tee Jet® 8003-E or similar nozzle type for              D, dicamba, or other growth regulator type herbicides
mounting back of each planter press-wheel.                        should not be used in treating tobacco or other susceptible
                                                                  crops.
10
          Some pesticide labels provide specific information                                   To make a cleaning solution add one of following to
on cleaning spray equipment; therefore, consult the label for                                  each 50 gallons of water:
guidelines. If specific guidelines are not indicated on the                                     a) 2 quarts of household ammonia, or
label the following procedure is generally recommended:                                         b) 4 pounds of trisodium phosphate cleaner.
  1. Fill the tank at least one-half full with fresh water.                                    3. Add more water and rinse the system again by using
      Flush tanks, lines, booms, and nozzles for at least 5                                       a combination of agitation and spraying. Remove and
      minutes using a combination of agitation and spraying.                                      clean nozzles, screens, and strainers in a bucket of
      Rinsate from this procedure is best sprayed onto                                            cleaning agent and water. Use safety precautions for
      cropland to avoid accumulation of pesticide-                                                the agrichemicals and cleaning products used.
      contaminated rinsate at one site. Thoroughly rinse the                                   4. Make a final rinse and flush the system again with
      inside surfaces of the tank. Pay particular attention to                                    clean water.
      the surfaces around the tank fill access and tank
      plumbing fixtures. The use of a 360-degree nozzle or                                                                      Nozzles
      other special rinsing nozzles installed permanently to
      the spray system can help automate this procedure.                                     Many types of nozzles are available for use. Each type
  2. Fill the tank again with fresh water and add one of the                                 provides different patterns, flow rates, spray angles, and
      following cleaning solutions or a commercially                                         droplet sizes. The following chart is meant as an aid in
      available tank cleaner. Agitate the solution for 15                                    sprayer calibration and are presented courtesy of Spraying
      minutes and operate the spray booms long enough to                                     Systems Co. of Wheaton, Illinois. Though the TeeJet®
      ensure that all nozzles and boom lines are filled with                                 brand is popular in Kentucky, similar nozzles from other
      the cleaning solution. Let the solution stay in the                                    manufacturers are perfectly acceptable.
      system for several hours, preferably overnight. When
      emptying the tank, spray the cleaning solution onto an
      area suitable for the rinsate solution.

            TIP NO.                                               GALLONS PER ACRE    GALLONS PER ACRE
     (Strainer Screen Size)    Liquid    Capacity    Capacity       20" SPACING         30" SPACING
                                                                                                                                     SPACING
       80º         110º       Pressure   1 Nozzle    1 Nozzle    5    6     7      8 5    6     7      8
      SERIES      SERIES       in PSI     in GPM    in oz./min. MPH MPH MPH MPH MPH MPH MPH MPH
                                30         .09          11        5.1    4.3    3.7    3.2    3.4    2.9    2.5    2.1
                                35         .09          12        5.6    4.6    4.0    3.5    3.7    3.1    2.6    2.3
     8001VS    11001VS
                                40         .10          13        5.9    5.0    4.2    3.7    4.0    3.3    2.8    2.5
   (100 Mesh) (100 Mesh)                                                                                                                                                   SPRAY
                                45         .11          14        6.3    5.3    4.5    3.9    4.2    3.5    3.0    2.6
                                60         .12          15        7.3    6.1    5.2    4.6    4.9    4.0    3.5    3.0                                                    HEIGHT*
                                30         .13          17        7.7    6.4    5.5    4.8    5.1    4.3    3.7    3.2
                                35         .14          18        8.3    6.9    6.0    5.2    5.6    4.6    4.0    3.5
    80015VS    110015VS
                                40         .15          19        8.9    7.4    6.4    5.6    5.9    5.0    4.2    3.7
   (100 Mesh) (100 Mesh)                                                                                                   *Adjust spray height in the field to overlap
                                45         .16          20        9.5    7.9    6.8    5.9    6.3    5.3    4.5    3.9
                                60         .18          23       10.9    9.1    7.8    6.8    7.3    6.1    5.2    4.6     approximately 30% of each edge of pattern.
                                30         .17          22       10.3    8.6    7.4    6.4    6.9    5.7    4.9    4.3
                                35         .19          24       11.1    9.3    7.9    6.9    7.4    6.2    5.3    4.6
    8002VS        11002VS
                                40         .20          26       11.9    9.9    8.5    7.4    7.9    6.6    5.7    5.0
   (50 Mesh)     (50 Mesh)
                                45         .21          27       12.6   10.5    9.0    7.9    8.4    7.0    6.0    5.3
                                                                                                                              SUGGESTED MINIMUM
                                60         .25          32       14.6   12.1   10.4    9.1    9.7    8.1    6.9    6.1
                                                                                                                                 SPRAY HEIGHT
                                30         .26          33       15.4   12.9   11.0    9.7   10.3    8.6    7.4    6.4
                                                                                                                            SPRAY     SPRAY HEIGHT
                                35         .28          36       16.7   13.9   11.9   10.4   11.1    9.3    7.9    6.9
    8003VS        11003VS                                                                                                   ANGLE      20" SPACING
                                40         .30          38       17.8   14.9   12.7   11.1   11.9    9.9    8.5    7.4
   (50 Mesh)     (50 Mesh)
                                45         .32          41       18.9   15.8   13.5   11.8   12.6   10.5    9.0    7.9         80º             17-19"
                                60         .37          47       22     18.2   15.6   13.6   14.6   12.1   10.4    9.1        110º             10-12"
                                30         .35          45       21     17.2   14.7   12.9   13.7   11.4    9.8    8.6
                                35         .37          47       22     18.5   15.9   13.9   14.8   12.3   10.6    9.3
    8004VS        11004VS
                                40         .40          51       24     19.8   17.0   14.9   15.8   13.2   11.3    9.9
   (50 Mesh)     (50 Mesh)
                                45         .42          54       25     21     18.0   15.8   16.8   14.0   12.0   10.5     Flat Fan Spray Tips
                                60         .49          63       29     24     21     18.2   19.4   16.2   13.9   12.1
                                30         .43          55       26     21     18.4   16.1   17.2   14.3   12.3   10.7     8002VS      Stainless Steel with VisiFlo
    8005VS        11005VS
                                35         .47          60       28     23     19.8   17.4   18.5   15.4   13.2   11.6                 color coding
                                40         .50          64       30     25     21     18.6   19.8   16.5   14.1   12.4
   (50 Mesh)     (50 Mesh)
                                45         .53          68       32     26     23     19.7   21     17.5   15.0   13.1     8002-HSS Hardened Stainless Steel
                                60         .61          78       36     30     26     23     24     20     17.3   15.2
                                30         .52          67       31     26     22     19.3   21     17.2   14.7   12.9     8002-SS     Stainless Steel
                                35         .56          72       33     28     24     21     22     18.5   15.9   13.9
    8006VS        11006VS
                                40         .60          77       36     30     25     22     24     19.8   17.0   14.9     8002        Brass
   (50 Mesh)     (50 Mesh)
                                45         .64          82       38     32     27     24     25     21     18.0   15.8
                                60         .74          95       44     36     31     27     29     24     21     18.2
                                30         .69         88        41     34     29     26     27     23     19.6   17.2
                                35         .75         96        44     37     32     28     30     25     21     18.5
    8008VS        11008VS
                                40         .80        102        48     40     34     30     32     26     23     19.8
   (50 Mesh)     (50 Mesh)
                                45         .85        109        50     42     36     32     34     28     24     21
                                60         .98        125        58     49     42     36     39     32     28     24
                                                 Tee JetTM is a registered trademark of Spraying Systems Co. of Wheaton, Illinois.
11

                 Herbicides, Formulations, Manufacturers, and Crops
Trade Name*           MOA Group Active Ingredient                   Manufacturer                  Crops**
AAtrex 4WDL                                                                          corn (field, popcorn),
                        Group 5    atrazine                            Syngenta
        90 WDG                                                                       grain sorghum
Abundit Edge                       glyphosate                                        corn (field, popcorn, sweet),
                        Group 9                                         Corteva
 [4.5 lb ae/gal]                    (isopropylamine salt)                            soybean
                                   nicosulfuron (54.5%)+
Accent Q                Group 2                                         Corteva      corn (field, popcorn, sweet)
                                   isoxadifen (safener)
                                                                                     corn (field, popcorn), soybean,
Acumen 3.3EC            Group 3    pendimethalin                        Tenkoz
                                                                                     tobacco
                                   S-metolachlor (2.14 lb) +
                        Group 15
                                   atrazine (1.0 lb) +
                        Group 5
Acuron                             mesotrione (0.24 lb) +              Syngenta      corn (field, popcorn, sweet)
                        Group 27
                                   bicyclopyrone (0.06 lb) +
                        Group 27
                                   benoxacor (safener)
                                   S-metolachlor (2.86 lb) +
                        Group 15
                                   mesotrione (0.32 lb) +
Acuron Flexi            Group 27                                       Syngenta      corn (field, popcorn, sweet)
                                   bicyclopyrone (0.08 lb) +
                        Group 27
                                   benoxacor (safener)
                        Group 2    thifensulfuron (5%) +
Afforia 50.8 WDG        Group 2    tribenuron (5%) +                    Corteva      soybean
                        Group 14   flumioxazin (40.8%)
                                                                                    corn (field, popcorn), grain
Aim 2EC                 Group 14   carfentrazone                         FMC
                                                                                    sorghum, soybean, wheat, barley
                                                                                    GT27 soybean (isoxaflutole-
Alite 27 (4SC)          Group 27   isoxaflutole (4 lb)                   BASF
                                                                                    resistant)
Andros                  Group 14   fomesafen (1.88 lb)              Rotam N America soybean
                        Group 14   fluthiacet-methyl (0.063 lb) +                    corn (field, popcorn, sweet),
Anthem (2.15L)                                                           FMC
                        Group 15   pyroxasulfone (2.087 lb)                          soybean
                        Group 5    atrazine (4.006 lb) +
Anthem ATZ (4.5S)       Group 14   fluthiacet-methyl (0.014 lb) +        FMC         corn (field, popcorn, sweet)
                        Group 15   pyroxasulfone (0.485 lb)
Anthem Flex (4SE)       Group 14   carfentrazone (0.267 lb) +
                                                                         FMC         wheat
                        Group 15   pyroxasulfone (3.733 lb)
Anthem MAXX             Group 14   fluthiacet-methyl (0.126 lb) +                    corn (field, popcorn, sweet),
                                                                         FMC
(4.3SC)                 Group 15   pyroxasulfone (4.174 lb)                          soybean
Armezon 2.8SC           Group 27   topramezone                           BASF        corn (field, popcorn, sweet)
Armezon PRO             Group 15   dimethenamid-P (5.25 lb) +
(6.25L)                                                                  BASF        corn (field, popcorn, sweet)
                        Group 27   topramezone (0.1 lb)
Arrow 2EC               Group 1    clethodim                            ADAMA        soybean
Assure II 0.88E         Group 1    quizalofop P-ethyl                   AMVAC        soybean
Atrazine 4 WDL                                                                       corn (field, popcorn),
                        Group 5    atrazine                             (various)
          90 WDG                                                                     grain sorghum
Authority Assist 4L     Group 14   sulfentrazone (3.33 lb) +
                                                                         FMC         soybean
                        Group 2    imazethapyr (0.67 lb)
Authority Edge          Group 14   sulfentrazone (2.73 lb) +
                                                                         FMC         soybean
4.25 SC                 Group 15   pyroxasulfone (1.52 lb)
Authority Elite 7L      Group 14   sulfentrazone (0.7 lb) +
                                                                         FMC         soybean
                        Group 15   S-metolachlor (6.3 lb)
Authority First         Group 14   sulfentrazone (62.1%) +
         (70DF)                                                          FMC         soybean
                        Group 2    cloransulam (7.9%)
Authority Maxx          Group 14   sulfentrazone (62.12%) +
                                                                         FMC         soybean
          (60DF)        Group 2    chlorimuron (3.88%)
Authority MTZ           Group 14   sulfentrazone (18%) +
                                                                         FMC         soybean
     45DF               Group 5    metribuzin (27%)
12

                 Herbicides, Formulations, Manufacturers, and Crops
Trade Name*           MOA Group Active Ingredient                    Manufacturer                  Crops**
Authority Supreme       Group 14     sulfentrazone (2.08 lb) +
                                                                         FMC        soybean
                        Group 15     pyroxysulfone (2.08 lb)
Authority XL 70DF       Group 14     sulfentrazone (62.22%) +
                                                                         FMC        soybean
                        Group 2      chlorimuron (7.78%)
Axial Bold              Group 1      pinoxaden (0.457 lb) +
                                                                       Syngenta     wheat, barley
                        Group 1      fenoxaprop-p-ethyl (0.228 lb)
Axiom 68DF              Group 15     flufenacet (54.4%) +                Bayer
                                                                                    corn (field), soybean, wheat
                        Group 5      metribuzin (13.6%)               CropScience
Balance Flexx                        isoxaflutole (2 lb) +               Bayer
                      Group 27(28)                                                  corn (field)
                                     cyprosulfamide (safener)         CropScience
Basis 75 WDG            Group 2      rimsulfuron (50%) +
                                                                        Corteva     corn (field)
                        Group 2      thifensulfuron (25%)
Basis Blend             Group 2      rimsulfuron (20%) +
                                                                        Corteva     corn (field)
                        Group 2      thifensulfuron (10%)
Battle Star             Group 14     fomesafen (1.88 lb)                Albaugh     soybean
Battle Star GT          Group 14     fomesafen (0.54 lb) +
                                                                        Albaugh     soybean [glyphosate-tolerant]
                        Group 9      glyphosate (2.26 lb)
Beacon 75DF             Group 2      primisulfuron                     Syngenta     corn (field, popcorn)
                                                                                    corn (field, popcorn, sweet corn),
Bellum 4SC              Group 27     mesotrione (4 lb)                  Rotam
                                                                                    sorghum (grain, sweet)
Bicep II Magnum         Group 15     S-metolachlor (2.4 lb) +
           5.5L         Group 5      atrazine (3.1 lb) +               Syngenta     corn (all types), grain sorghum
                                     benoxacor (safener)
Boundary 6.5EC          Group 15     S-metolachlor (5.25 lb) +
                                     metribuzin (1.25 lb)              Syngenta     soybean
                        Group 5
Brawl II 7.64EC                      S-metolachlor (2.4 lb) +                       corn (all types), soybean,
                        Group 15                                        Tenkoz
                                     benoxacor (safener)                            grain & forage sorghum
Brawl II ATZ 5.5L                    S-metolachlor (2.4 lb) +
                        Group 15
                                     atrazine (3.1 lb) +                Tenkoz      corn (all types), grain sorghum
                        Group 5
                                     benoxacor (safener)
Breakfree NXT 7E                     acetochlor (7 lb)+
                        Group 15                                        Corteva     corn (field, popcorn)
                                     dichlormid (safener)
Breakfree NXT ATZ                    acetochlor (3.1 lb) +
           5.6L         Group 15
                                     atrazine (2.5 lb) +                Corteva     corn (field, popcorn)
                        Group 5
                                     dichlormid (safener)
                                                                                    corn (field, popcorn), grain
Broclean                Group 6      bromoxynil (2lb)                  Loveland
                                                                                    sorghum, wheat, barley, oats
BroadAxe XC             Group 14     sulfentrazone (0.7 lb) +
                                                                       Syngenta     soybean
                        Group 15     S-metolachlor (6.3 lb)
Buccaneer 4S or
                                     glyphosate                                     corn (field, popcorn), grain
Buccaneer Plus          Group 9                                         Tenkoz
                                     (isopropylamine salt)                          sorghum, soybean, wheat, barley
 [3 lb ae/gal]
Buccaneer 5                          glyphosate                                     corn (field, popcorn), grain
                        Group 9                                         Tenkoz
 [3.75 lb ae/gal]                    (isopropylamine salt)                          sorghum, soybean, wheat, barley
Cadet 0.91EC            Group 14     fluthiacet-methyl (0.91 lb)         FMC        corn (field, popcorn), soybean
Callisto 4SC                         mesotrione (4 lb)                              corn (field, popcorn, sweet corn),
                        Group 27                                       Syngenta
                                                                                    sorghum (grain, sweet)
Callisto GT (4.18L)     Group 9      glyphosate (3.8 lb) +
                                                                       Syngenta     corn (field) [glyphosate-tolerant]
                      Group 27(28)   mesotrione (0.38 lb)
Callisto Xtra 3.7L      Group 5      atrazine (3.2 lb) +                            corn (field, yellow popcorn, silage,
                                                                       Syngenta
                      Group 27(28)   mesotrione (0.5 lb)                            sweet corn)
Canopy 75WDG            Group 2      chlorimuron (10.7 %) +
                                                                        Corteva     Soybean
                        Group 5      metriburin (64.3%)
13

                  Herbicides, Formulations, Manufacturers, and Crops
Trade Name*          MOA Group Active Ingredient                      Manufacturer                       Crops**
Canopy Blend            Group 2      chlorimuron (8.3 %) +
                                                                           Corteva        soybean
                        Group 5      metribuzin (50%)
Canopy EX               Group 2      chlorimuron (22.7 %) +
                                                                           Corteva        Soybean
     29.5 WDG           Group 2      tribenuron (6.8%)
                                     thiencarbozone (0.57 lb) +
                        Group 2
Capreno 3.45SC                       tembotrione (2.88 lb) +          Bayer CropScience corn (field, popcorn, sweet corn)
                      Group 27(28)
                                     isoxadifen (safener)
Charger Max                          S-metolachlor +                                      corn (all types), grain sorghum,
                       Group 15                                         Winfield United
        7.64EC                       (seed safener)                                       soybean
Charger Max ATZ                      S-metolachlor (2.4 lb) +
                       Group 15
         5.5 L                       atrazine (3.1 lb) +               Winfield United    corn (all types), grain sorghum
                       Group 5
                                     (seed safener)
Cheetah                              glufosinate-ammon. (2.34 lb)                         corn (field), soybean [glufosinate-
                       Group 10                                            Nufarm
                                                                                          tolerant]
Cheetah Max            Group 10      glufosinate-ammonium (2 lb)+
                                                                           Nufarm         soybean [glufosinate-tolerant]
                       Group 14      fomesafen (1 lb)
Cinch 7.64EC                         S-metolachlor +                                      corn (all types), grain sorghum,
                       Group 15                                            Corteva
                                     benoxacor (safener)                                  soybean
Cinch ATZ 5.5L                       S-metolachlor (2.4 lb) +
                       Group 15
                                     atrazine (3.1 lb) +                   Corteva        corn (all types), grain sorghum
                       Group 5
                                     benoxacor (safener)
Cinco                                glyphosate                                           corn (field, popcorn), grain
                        Group 9                                       Loveland Products
  [4 lb ae/gal]                      (isopropylamine salt)                                sorghum, soybean, wheat, barley
                                     dicamba                                              corn (field, popcorn), grain
Clarity 4S              Group 4                                             BASF
                                     (diglycolamine salt)                                 sorghum, wheat, barley
                                     dicamba                                              corn, grain sorghum, wheat, barley,
Clash                   Group 4                                            Nufarm
                                     (diglycolamine salt)                                 oats
Classic 25DF           Group 2       chlorimuron                           AMVAC          soybean
Cloak 75WDG            Group 2       chlorimuron (10.7%0 +
                                                                           Nufarm         soybean
                       Group 5       metribuzin (64.3%)
Cloak EX               Group 2       chlorimuron (22.7% +
                                                                           Nufarm         soybean
    29.5WDG            Group 2       tribenuron (6.8%)
Cobra 2EC              Group 14      lactofen                               Valent        soybean
Command 3ME            Group 13      clomazone                               FMC          soybean, tobacco
Confidence 7E          Group 15      acetochlor + (safener)             Winfield United   corn (field, popcorn)
Confidence Xtra        Group 15      acetochlor (3.1 lb) +
                                                                        Winfield United   corn (field, popcorn)
           5.6L        Group 5       atrazine (2.5 lb) + (safener)
Cornerstone Plus                     glyphosate                                           corn (field, popcorn), grain
                        Group 9                                         Winfield United
  [3 lb ae/gal]                      (isopropylamine salt)                                sorghum, soybean, wheat, barley
Cornerstone 5 Plus                   glyphosate                                           corn (field, popcorn), grain
                        Group 9                                         Winfield United
  [4 lb ae/gal]                      (isopropylamine salt)                                sorghum, soybean, wheat, barley
                                     thiencarbozone (0.75 lb) +
                        Group 2                                             Bayer
Corvus 2.63L                         isoxaflutole (1.88 lb) +                             corn (field)
                      Group 27(28)                                       CropScience
                                     safener
Coyote                               S-metolachlor (3.34 lb) +
                       Group 15                                                           corn (field, sweet, yellow popcorn),
                                     mesotrione (0.33 lb) +                  UPL
                       Group 27                                                           grain sorghum
                                     benoxacor (safener)
                                                                                          corn (field, popcorn), grain
Credit 5.4 Extra        Group 9      glyphosate [IPA salt] (4.0 lb)        Nufarm
                                                                                          sorghum, soybean, wheat, barley
Credit Xtreme                        glyphosate
                                                                                          corn (field, popcorn), grain
 [4.5 lb ae/gal]        Group 9      [isopropylamine salt (2.5 lb)+        Nufarm
                                                                                          sorghum, soybean, wheat, barley
                                     potassium salt (2.0 lb)]
14

               Herbicides, Formulations, Manufacturers, and Crops
Trade Name*          MOA Group Active Ingredient                    Manufacturer                   Crops**
Crusher 50WDG          Group 2    rimsulfuron (25%) +
                                                                         FMC          corn (field), soybean
                       Group 2    thifensulfuron-methyl (25%)
2,4-D                                                                                 corn, grain sorghum, soybean,
                       Group 4    2,4-D                                (various)
 [several forms]                                                                      wheat, barley
Degree Xtra                       acetochlor (2.7 lb) +
                       Group 15                                         Bayer         corn (field, popcorn), grain
          4.04CS                  atrazine (1.34 lb) +
                       Group 5                                       CropScience      sorghum
                                  MON13900 (safener)
                                                                                      corn, grain sorghum, wheat, barley,
Diablo 4S              Group 4    dicamba (dimethylamine salt)         Nufarm
                                                                                      oats
                       Group 4    dicamba (diglycolamine salt)+         Bayer
DiFlexx 4SC                                                                           corn (field, silage, popcorn)
                                  cyprosulfamide (safener)           CropScience
                                  dicamba (1.26 lb ae) +
                       Group 4                                          Bayer
DiFlexx Duo 2.13SC                tembotrione (0.27 lb)                               corn (field, silage, popcorn)
                       Group 27                                      CropScience
                                  cyprosulfamide (safener)
Dimetric Charge        Group 5    metribuzin (3 lb)
                                                                    Winfield United   soybean
3.67 L                 Group 14   flumioxazin (0.67)
Dual II Magnum                    S-metolachlor +                                     corn (all types), grain sorghum,
                       Group 15                                       Syngenta
         7.64EC                   benoxacor (safener)                                 soybean
Duramax                           glyphosate                                          corn (field, popcorn), grain
                       Group 9                                         Corteva
 [4 lb ae/gal]                    (dimethylamine salt)                                sorghum, soybean, wheat, barley
Durango DMA                       glyphosate                                          corn (field, popcorn), grain
                       Group 9                                         Corteva
 [4 lb ae/gal]                    (dimethylamine salt)                                sorghum, soybean, wheat, barley
                                                                                      corn, sorghum, soybean, wheat,
Elevore                Group 4    halauxifen-methyl (0.572 lb)         Corteva
                                                                                      barley
Encompass 51DG         Group 14   flumioxazin                          Tenkoz         soybean
Engenia                Group 4    Dicamba (BAPMA) (5 lb ae)             BASF          corn, soybean [dicamba-tolerant]
                       Group 4    2,4-D [choline salt] (1.6 lb) +
Enlist Duo                                                             Corteva        corn, soybean [Enlist]
                       Group 9    glyphosate [DMA salt] (1.7 lb)
Enlist One             Group 4    2,4-D [choline salt] (3.8 lb)        Corteva        corn, soybean [Enlist]
                       Group 2    chlorimuron (9.2%) +
Envive 41.3DG          Group 2    thifensulfuron (2.9%) +              Corteva        soybean
                       Group 14   flumioxazin (29.2%)
                                                                                      corn (field, popcorn),
Establish 6E           Group 15   dimethenamid-P                       Tenkoz
                                                                                      grain sorghum, soybean
Expert 4.88L           Group 15   S-metolachlor (1.74 lb) +                           corn (field corn, Roundup Ready
                       Group 5    atrazine (2.14 lb) +                Syngenta        hybrids, popcorn, sweet corn),
                       Group 9    glyphosate [IPA salt] (1.0 lb)                      grain sorghum, forage sorghum
                                                                                      corn (field, popcorn, sweet corn),
Explorer 4SC           Group 27   mesotrione (4 lb)                   Syngenta
                                                                                      sorghum (grain, sweet)
Express (TotalSol)                                                                    corn (field), grain sorghum,
                       Group 2    tribenuron-methyl                      FMC
      50 DF                                                                           soybean, wheat, barley, fall fallow
Extreme 2.17L          Group 2    imazethapyr (0.17 lb) +               BASF
                                                                                      soybean
                       Group 9    glyphosate [IPA salt] (2 lb)
FeXapan
                       Group 4    dicamba [DGA salt] (2.9 lb ae)       Corteva        corn, soybean [dicamba-tolerant]
 Plus VaporGrip
                       Group 14   flumioxazin (33.5%) +
Fierce 76WDG                                                            Valent        corn (field), soybean, wheat
                       Group 15   pyroxasulfone (42.5%)
                       Group 14   flumioxazin (0.5 lb) +
Fierce MTZ             Group 15   pyroxasulfone (0.64) +                Valent        soybean
                       Group 5    metribuzin (1.5 lb)
                       Group 14   flumioxazin (1.34 lb) +
Fierce EZ                                                               Valent        corn (field), soybean
                       Group 15   pyroxasulfone (1.7 lb)
15

                 Herbicides, Formulations, Manufacturers, and Crops
Trade Name*         MOA Group Active Ingredient                    Manufacturer                      Crops**
                      Group 2       chlorimuron (6.67%)
Fierce XLT            Group 14      flumioxazin (24.57 %)                Valent       soybean
                      Group 15      pyroxasulfone (31.7%)
Finesse Cereal        Group 2       chlorsulfuron (62.5%) +
                                                                         FMC          wheat, barley, triticale
  and Fallow          Group 2       metsulfuron-methyl (12.5%)
FirstRate 84WDG       Group 2       cloransulam                         AMVAC         soybean
FirstShot SG          Group 2       thifensulfuron (25%) +                            corn (field), grain sorghum,
                                                                         FMC
   (TotalSol)         Group 2       tribenuron (25%)                                  soybean, wheat, barley, fallow
Flexstar 1.88L        Group 14      fomesafen                          Syngenta       soybean
Flexstar GT 3.5       Group 14      fomesafen (0.56 lb) +
                                                                       Syngenta       soybean [glyphosate-tolerant]
       [2.82S]        Group 9       glyphosate (2.26 lb)
                                    glufosinate-ammonium                              corn (field), soybean
Forfeit 280SL         Group 10      (2.34 lb)                          Loveland
                                                                                        [glufosinate-tolerant]
FulTime NXT [4SE]     Group 15      acetochlor (2.7 lb) +
                                                                        Corteva       corn (field, popcorn, sweet)
                      Group 5       atrazine (1.34 lb)
Fusilade DX 2E        Group 1       fluazifop-P-butyl (2 lb)           Syngenta       soybean
Fusion 2.56EC         Group 1       fluazifop-P-butyl (2 lb) +
                                                                       Syngenta       soybean
                      Group 1       fenoxaprop-P-ethyl (0.56 lb)
Glory 75DF                                                                            Corn (field), soybean,
                       Group 5      metribuzin (75%)                    ADAMA
Glory 4L                                                                              wheat (tolerant varieties)
Glyphogan                           glyphosate                                        corn (field, popcorn), grain
                       Group 9                                          ADAMA
 [3 lb ae/gal]                      (isopropylamine salt)                             sorghum, soybean, wheat, barley
Gly Star Plus                       glyphosate                                        corn (field, popcorn),grain
                       Group 9                                          Albaugh
 [3 lb ae/gal]                      (isopropylamine salt)                             sorghum, soybean, wheat, barley
Gramoxone SL 2.0                    paraquat (2 lb) or                                corn (field, popcorn), grain
                      Group 22                                         Syngenta
Gramoxone SL 3.0                    paraquat (3 lb)                                   sorghum, soybean, wheat, barley
Grapple                Group 2      rimsulfuron (25%)                   NuFarm        corn (field)
GuardsmanMax 5E       Group 15      dimethenamid-P (1.7 lb) +                         corn (field, popcorn),
                                                                         BASF
                       Group 5      atrazine (3.3 lb)                                 grain sorghum
                      Group 15      S-metholachlor (2.09) +
Halex GT [4.39EC]      Group 9      glyphosate (2.09) +                Syngenta       corn (Glyphosate-Tolerant hybrids)
                     Group 27(28)   mesotrione (0.209)
Harmony Extra SG       Group 2      thifensulfuron (33.33%) +                         wheat, barley, oats, corn(field),
                                                                         FMC
  (TotalSol) 50SG      Group 2      tribenuron (16.67%)                               grain sorghum, soybean, fallow
Harmony SG                                                                            wheat, barley, oats, corn (field),
                       Group 2      thifensulfuron (50%)                 FMC
  (TotalSol) 50SG                                                                     grain sorghum, soybean, fallow
Harness 7E                          acetochlor +                         Bayer
                      Group 15                                                        corn (field, popcorn)
                                    furilazole (safener)              CropScience
Harness Xtra 5.6L                   acetochlor (3.1 lb) +
                      Group 15                                           Bayer
                                    atrazine (2.5 lb) +                               corn (field, popcorn)
                      Group 5                                         CropScience
                                    furilazole (safener)
                                                                                      corn (field, popcorn), grain
Helmquat 3SL          Group 22      paraquat                         HELM AGRO
                                                                                      sorghum, soybean, wheat, barley
Honcho K6                           glyphosate                           Bayer        corn (field, popcorn), grain
                       Group 9
 [4.5 lb ae/gal]                    (isopropylamine salt)             CropScience     sorghum, soybean, wheat, barley
Hornet 68.5WDG         Group 2      flumetsulam (18.5%) +
                                                                        AMVAC         corn (field)
                       Group 4      clopyralid (50%)
Hoss Ultra                          glyphosate                                        corn (field, popcorn), grain
                       Group 9                                          Helena
 [3 lb ae/gal]                      (isopropylamine salt)                             sorghum, soybean, wheat, barley
                      Group 27      pyrasulfotole (0.31 lb) +
Huskie                                                             Bayer CropScience wheat, barley, grain sorghum
                      Group 6       bromoxynil (1.75 lb)
Impact 2.8SC          Group 27      topramezone                         AMVAC         corn (field, popcorn, sweet)
16

                 Herbicides, Formulations, Manufacturers, and Crops
Trade Name*          MOA Group Active Ingredient                    Manufacturer                       Crops**
Impact Core 7.15EC     Group 27     topramezone (0.071 lb) +
                                                                         AMVAC          corn (field, popcorn)
                       Group 15     acetochlor (7.08 lb)
Impact Z 4.26S         Group 27     topramezone (0.26 lb) +
                                                                         AMVAC          corn (field, popcorn, sweet)
                       Group 5      atrazine (4 lb)
Incinerate 4SC                      mesotrione (4 lb)                                   corn (field, popcorn, sweet corn),
                       Group 27                                      WinField United
                                                                                        sorghum (grain, sweet)
                       Group 2      rimsulfuron (4.17%) +
Instigate 45.8WDG                                                        Corteva        corn (field)
                       Group 27     mesotrione (41.67%)
Intensity 2EC          Group 1      clethodim                            Loveland       soybean
IntensityOne                        clethodim
                       Group 1                                           Loveland       soybean, corn (field)
        0.97EC
                                    glufosinate (2.34 lb)                               corn (field), soybean [glufosinate-
Interline (SL)         Group 10                                            UPL
                                                                                        tolerant]
                                    glufosinate (1.07 lb) +
Intermoc               Group 10                                            UPL          soybean [glufosinate-tolerant]
                                    S-metolachlor (2.5 lb)
Intimidator           Group 15      S-metolachlor (3.39 lb) +
                       Group 5      metribuzin (0.75 lb) +               Loveland       soybean
                      Group 14      fomesafen (0.67 lb)
Keystone NXT          Group 15      acetochlor (3.1 lb) +
5.6SE                                                                    Corteva        corn (field, popcorn, sweet)
                       Group 5      atrazine (2.5 lb)
Kyber                 Group 14      flumioxazin (0.5 lb) +
                       Group 5      metribuzin (1.5 lb) +                Corteva        corn (field), soybean
                      Group 15      pyroxasulfone (0.64 lb)
Laudis               Group 27(28)   tembotrione (3.5 lb)            Bayer CropScience corn (field, popcorn, sweet)
LeadOff 33.4WDG        Group 2      rimsulfuron (16.7%) +
                                                                         Corteva        corn (field), soybean
                       Group 2      thifensulfuron-methyl (16.7%)
                      Group 15      S-metolachlor (5.25 lb) +
Ledger 6.5EC                        metribuzin (1.25 lb)                  Tenkoz        soybean
                       Group 5
                                    S-metolachlor (1.74 lb) +
                      Group 15
Lexar EZ                            mesotrione (0.224 lb) +                             corn (field, popcorn, sweet),    grain
                     Group 27(28)                                       Syngenta
                                    atrazine (1.74 lb) +                                sorghum
                       Group 5
                                    benoxacor (safener)
                                    glufosinate-ammonium                               corn (field), soybean [glufosinate-
Liberty 280SL          Group 10                                           BASF
                                    (2.34 lb)                                          tolerant]
Linex 4L               Group 7      linuron (4 lb)                  Tessenderlo Kerley soybean
                                    S-metolachlor (2.49 lb) +
                      Group 15
Lumax EZ                            mesotrione (0.249 lb) +                             corn (field, popcorn, sweet),
                     Group 27(28)                                       Syngenta
                                    atrazine (0.935 lb) +                               grain sorghum
                       Group 5
                                    benoxacor (safener)
Mad Dog or
                                    glyphosate                                          corn (field, popcorn), grain
Mad Dog Plus           Group 9                                           Loveland
                                    (isopropylamine salt)                               sorghum, soybean, wheat, barley
 [3 lb ae/gal]
Maestro 2EC                                                                             corn (field, popcorn), sorghum,
                       Group 6      bromoxynil                            Nufarm
Maestro 4EC                                                                             wheat, barley, oats, rye, triticale
                       Group 4      dicamba (1.1 lb) +
Marksman 3.2S                                                             BASF          corn (field, popcorn)
                       Group 5      atrazine (2.1 lb)
Marvel 3L              Group 14     fluthiacet (0.117 lb) +
                                                                           FMC          soybean
                       Group 14     fomesafen (2.883 lb)
                       Group 15     S-metolachlor (3.38 lb) +
Matador-S              Group 5      metribuzin (0.75 lb) +               Loveland       soybean
                        Group2      imazethapyr (0.17)
Mauler                 Group 5      metribuzin (4 lb)                     Valent        soybean
MCPA                   Group 4      MCPA                                 (various)      small grains
You can also read