PROFICIENCY TESTING SCHEME - Annual Programme 2021 - Vienna, November 25th, 2020 - Umweltbundesamt

 
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PROFICIENCY TESTING SCHEME - Annual Programme 2021 - Vienna, November 25th, 2020 - Umweltbundesamt
PROFICIENCY TESTING SCHEME
         Annual Programme 2021

                            © Olivier – Fotolia.com

               Vienna, November 25th, 2020
Proficiency Testing Scheme – Annual Programme 2021

PROFICIENCY TESTING PROGRAMME 2021

Interlaboratory comparison plays an important part in the adaptation, standardisation and
validation of measurement techniques, as well as in the assessment of laboratories and the
production of reference materials. Accredited laboratories also need it as proof of their technical
competence.

The Environment Agency Austria (Umweltbundesamt) offers different interlaboratory
comparisons which will take place during 2021. This allows the verification of the validity of your
test results by an external quality control programme.

The main facts of the process are:

 All interlaboratory comparisons are performed according to the requirements
  of EN ISO/IEC 17043.
 You will receive samples from us. These samples will be analysed in your laboratory.
 Your results will be submitted electronically by entering the test data online.
 ISO 5725-2 and ISO 13528 will be used as the basis for the statistical analysis.
 The so-called ‘z score’ will be used as assessment criterion for participant performance.
 The additional informative assessment for the participants using ‘En-Scores’ for proficiency
  testing of real water samples takes into account the expanded measurement uncertainties
  of the participants results and the expanded uncertainty of the assigned value.
 In case of proficiency testing of real water samples control testing can from time to time be
  subcontracted. This is also clearly stated in the report. When subcontracting occurs, it is
  placed with a competent subcontractor and the proficiency testing provider is responsible for
  this work.
 You will receive a final report with the results of all participating laboratories in aggregated
  and anonymised form and a certificate of participation.

Accredited Proficiency Testing Provider according to EN ISO /IEC 17043:2010

Within the cooperation between IFA-Tulln and the Umweltbundesamt in 2021 all described
proficiency tests for synthetic water samples (IFA-Tulln: initial accreditation date May 2020)
and for real water samples (Umweltbundesamt audit in June 2020 for expansion of the
accreditation scope for chemical analysis, hearing in November 2020) will be offered within the
scope of accreditation.

For any further questions please do not hesitate to contact us:

ringversuche@umweltbundesamt.at

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                     3/31
Proficiency Testing Scheme – Annual Programme 2021

HOW TO PARTICIPATE?

Proficiency Testing Scheme for Water Analysis

Since 2013 within the cooperation between IFA-Tulln and the Umweltbundesamt we offer
interlaboratory comparisons for real water samples (ground water, surface water, urban waste
water and drinking water, partly spiked).
https://www.umweltbundesamt.at/en/ic-wateranalysis
Interlaboratory comparisons for synthetic water samples are provided by IFA-Tulln,
a department of the University of Natural Resources and Life Sciences, Vienna.
The Umweltbundesamt organizes all real water sample proficiency tests.
Registration for the Proficiency Testing Scheme for Water Analysis is handled
by our partner IFA-Tulln: https://www.ifatest.eu/.

Proficiency Testing Scheme for Environmental Analysis

The Umweltbundesamt carries out Proficiency Testing Schemes yearly in a series of
Substances for instance waste as well as air samples.
Registration for the Proficiency Testing Scheme for Enviromental Analysis by:
https://www.umweltbundesamt.at/en/en-prof-tests-matrices

Shortly after transmitting the completed registration form, you will receive a confirmation
of order by e-mail, containing all the relevant information (date of dispatch, approximate
date of arrival of the samples).
Once you have paid the participation fee, your registration will be completed and you will
receive the samples as specified in our catalogue.

We are obliged to charge VAT and reverse charge is applicable.

The prices stated are exclusive of 20 % VAT and shipment costs.

In this catalogue you can find all details and information for proficiency tests which are
offered.

4/31                           Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

Here is a list of all proficiency tests, which will be offered:

 Programme                                                                         Matrices            Page

 Proficiency Testing Scheme for Water Analysis

 Metals and Trace elements                                                           Water                6

 Nutrients/Major ions                                                                Water                7

 Herbicides/Pesticides                                                               Water                8

 Herbicides/Pesticides                                                               Water                9

 Herbicides/Pesticides                                                               Water               10

 Advance notice of Pesticides in accordance with the Drinking Water                  Water               11
 Ordinance – 2022
 Polycyclic aromatic hydrocarbons (PAH)                                              Water               13

 Pharmaceuticals, Industrial Chemicals and Artificial Sweeteners                     Water               14

 Sum parameters: Hydrocarbon oil index and Phenol index                              Water               15

 BTEX and MTBE and Volatile Halogenated Hydrocarbons (VHH)                           Water               17

 Minimum concentrations and performance criterion                                    Water               19

 Proficiency Testing Scheme for Environmental Analysis

 Waste acc to landfill directive (Austria) (total contents)                          Waste               27

 Advance notice of Waste acc to landfill directive (Austria) (eluate                 Waste               27
 metals) – 2022
 Advance notice of Waste acc to landfill directive (Austria) (eluate                 Waste               27
 ions) - 2022
 Chlorinated hydrocarbons (CHC)                                                   Ambient Air            29

 BTEX & C5-C10                                                                    Ambient Air            30

 Chlorinated hydrocarbons (CHC) and BTEX & C5-C10                                 Ambient Air            31

For further information please have a look at our website

https://www.umweltbundesamt.at/en/proficiency-testing

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                             5/31
Proficiency Testing Scheme – Annual Programme 2021

PROFICIENCY TESTING SCHEME
FOR WATER ANALYSIS

 Description of Programme
 No M155                           Metals and trace elements
 List of substances:               Al, As, Pb, Cd, Cr, Fe, Cu, Mn, Ni, Hg, Se, U, Zn
 Matrix:                           Natural water
 Samples:                          2; 1 ground water sample, 1 surface water sample (partly fortified)
 Sample dispatch:                  09 February 2021
 Closing date:                     09 March 2021
 Cost:                             EUR 395,–

 Technical Information

 Parameter                                         Bottle/sample
                                                                                  Stabilisation       Refrigeration
 to analyse                             Volume         Number        Type
                                         250 ml          1
                                                                                yes, with HNO3
 Al, As, Pb, Cd, Cr, Fe, Cu,              and           and         plastic
                                                                                                           yes
 Mn, Ni, Hg, Se, U, Zn                                             container     yes, with HCl
                                      100 ml (Hg)        1
                                                                                     (Hg)

 Recommended period to start the sample treatment:                                           D0 + 8

D0 ... Day the samples are sent to all participants.

Additional proficiency tests (synthetic samples) performed by our partner IFA-Tulln
(registration www.ifatest.eu) Cost: EUR 395,–; M157 with additional substances EUR 435,–.

                                                                     Sample dispatch              Closing date
 No M156       Metals and trace elements                              08 March 2021               09 April 2021*
 No M157       Metals and trace elements (additionally                 17 May 2021                11 June 2021
               Ag, Ba, Ce, Co, Li, Mo, Sb, Sn, V)
 No M158       Metals and trace elements                            06 September 2021         01 October 2021
 No M159       Metals and trace elements                            08 November 2021        03 December 2021
* Note: 5 weeks between sample dispatch and closing date (due to holiday).

6/31                                 Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No N155                           Nutrients/Major ions
 List of substances:               Total hardness, alkalinity KS 4,3, electrical conductivity (25°C), HCO3-, Ca2+,
                                   Mg2+, Na+, K+, NO3-, NO2-, NH4+, Cl-, SO42-, o-PO43-, B, DOC,
                                   total-P (dissolved, as PO43-); pH, total-N (N155 only)
 Matrix:                           Natural water
 Samples:                          2; 1 ground water sample, 1 surface water sample (partly fortified)
 Sample dispatch:                  09 February 2021
 Closing date:                     09 March 2021
 Cost:                             EUR 395,–

 Technical Information

 Parameter                                               Bottle/sample
                                                                                    Stabilisation      Refrigeration
 to analyse                                     Volume    Number         Type
 hardness, alkalinity KS 4,3, electrical        500 ml        2
 conductivity (25°C), HCO3-, Ca2+,                                                        no
                                                  and       and
 Mg2+, Na+, K+, NO3-, NO2-, NH4+,                                      Plastic
                                                                                                             yes
 Cl-, SO42-, o-PO43-, B, DOC, total-P                                 container
 (dissolved, as PO43-)                          250 ml                                   yes,
                                                              1
 and pH, total-N (N155 only)                    (DOC)                              with HCl (DOC)

 Recommended period to start the sample treatment:                                                  D0 + 8
                   -,    +,        3-
 For DOC, NO2 NH4 o-PO4 and pH we recommend analysis
 as soon as possible after receipt of the samples.

D0 ... Day the samples are sent to all participants.

Additional proficiency tests (synthetic samples) performed by our partner IFA-Tulln
(registration www.ifatest.eu) Cost: EUR 395,–.

                                                                         Sample dispatch            Closing date
 No N156        Nutrients/major ions                                      08 March 2021          09 April 2021*
                (additionally total-Si (dissolved) and fluoride)
 No N157        Nutrients/major ions (additionally KMnO4-                  17 May 2021              11 June 2021
                index (as O2) acc. to EN ISO 8467 (H5))
 No N158        Nutrients/major ions                                   06 September 2021        01 October 2021
                (additionally easily liberatable cyanide
                acc. to DIN 38405-D13 (ISO 14403-2:2012;
                ISO 6703-2:1984))
 No N159        Nutrients/major ions                                   08 November 2021        03 December 2021
                (additionally KMnO4-index (as O2) acc. to
                EN ISO 8467 (H5))
* Note: 5 weeks between sample dispatch and closing date (due to holiday).

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                                     7/31
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No H109                           Herbicides/Pesticides
 List of substances:               2,6-Dichlorobenzamide, Alachlor, Atrazine, Atrazine-desethyl, Atrazine-
                                   desethyl-desisopropyl, Atrazine-desisopropyl, Bromacil, Chloridazon,
                                   Chloridazon-desphenyl, Chloridazon-methyl-desphenyl, Clopyralid,
                                   Cyanazine, Dimethenamide, Diuron, Metolachlor, N,N-Dimethylsulfamide
                                   (DMS), Nicosulfurone, Prometryn, Propazine, Sebuthylazine, Simazine,
                                   Terbuthylazine, Terbuthylazine-desethyl, Terbutryn
 Matrix:                           Natural water
 Samples:                          2; 1 ground water, 1 surface water
 Sample dispatch:                  23 February 2021
 Closing date:                     30 March 2021
 Cost:                             EUR 470,–

 Technical Information

 Parameter                                                      Bottle/sample
                                                                                       Stabilisation   Refrigeration
 to analyse                                        Volume        Number         Type
 2,6-Dichlorobenzamide, Alachlor,
 Atrazine, Atrazine-desethyl, Atrazine-                300 ml       2
 desethyl-desisopropyl, Atrazine-                        or         or
 desisopropyl, Bromacil, Chloridazon,
 Chloridazon-desphenyl, Chloridazon-
 methyl-desphenyl, Clopyralid,                     1000 ml          2      Aluminium
                                                                                            no             yes
 Cyanazine, Dimethenamide, Diuron,                       or         or     container
 Metolachlor, N,N-Dimethylsulfamide
 (DMS), Nicosulfurone, Prometryn,
 Propazine, Sebuthylazine, Simazine,
 Terbuthylazine, Terbuthylazine-                   1000 ml          4
 desethyl, Terbutryn

 Recommended period to start the sample treatment:                                                      D0 + 8

D0 ... Day the samples are sent to all participants.

8/31                                 Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No H110                           Herbicides/Pesticides
 List of substances:               2,4,5-Trichlorophenoxyacetic acid, 2,4-D (2,4-Dichlorophenoxyaceticacid),
                                   Alachlor, Alachlor-t-acid (Alachlor-OA), Alachlor-t-sulfonic acid (Alachlor-
                                   ESA), Aminomethylphosphonic acid (AMPA), Bentazone, Dicamba,
                                   Dichlorprop, Glufosinate, Glyphosate, Mecoprop, Metazachlor,
                                   Metazachlor oxanilic acid (Metazachlor-OA), Metazachlor ethane sulfonic
                                   acid (Metazachlor-ESA), Metolachlor, s-Metolachlor oxanilic acid
                                   (Metolachlor-OA), s-Metolachlor ethanesulfonic acid (Metolachlor-ESA)
 Matrix:                           Natural water
 Samples:                          2; 1 ground water, 1 surface water
 Sample dispatch:                  22 June 2021
 Closing date:                     27 July 2021
 Cost:                             EUR 470,–

 Technical Information

 Parameter                                                      Bottle/sample
                                                                                         Stabilisation Refrigeration
 to analyse                                        Volume       Number          Type
 2,4,5-Trichlorophenoxy-acetic acid,                   300 ml      2
 2,4-D (2,4-Dichlorophenoxyaceticacid),                  or        or      Aluminium
 Alachlor, Alachlor-t-acid (Alachlor-OA),                                  container
                                                   1000 ml         2
 Alachlor-t-sulfonic acid (Alachlor-ESA),
                                                     or            or
 Aminomethylphosphonic acid (AMPA),
 Bentazone, Dicamba, Dichlorprop,                  1000 ml         4            and
 Glufosinate, Glyphosate, Mecoprop,                  and          and                        no            yes
 Metazachlor, Metazachlor oxanilic acid
 (Metazachlor-OA), Metazachlor ethane                                        plastic
 sulfonic acid (Metazachlor-ESA),                                          container
 Metolachlor, s-Metolachlor oxanilic               1000 ml         1        (AMPA,
 acid (Metolachlor-OA), s-Metolachlor                                     Glufosinate,
 ethanesulfonic acid (Metolachlor-ESA)                                    Glyphosate)

 Recommended period to start the sample treatment:                                                      D0 + 8

D0 ... Day the samples are sent to all participants.

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                                   9/31
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No H111                           Herbicides/Pesticides
 List of substances:               Acetamiprid, Aldrin, Atrazine, Atrazine-desethyl, Atrazine-desisopropyl,
                                   Bromacil, Chlordane, Clothianidin, Cyanazine, DDD, DDE, DDT, Dieldrin,
                                   Dinotefurane, Endosulfan, Endrin, Heptachlor, Imidacloprid, Lindane,
                                   Nitenpyram, Prometryn, Propazine, Thiacloprid, Thiamethoxam
 Matrix:                           Natural water
 Samples:                          2; 1 ground water, 1 surface water
 Sample dispatch:                  12 October 2021
 Closing date:                     16 November 2021
 Cost:                             EUR 470,–

 Technical Information

 Parameter                                                      Bottle/sample
                                                                                       Stabilisation Refrigeration
 to analyse                                            Volume    Number         Type
 Acetamiprid, Aldrin, Atrazine, Atrazine-              300 ml       2
 desethyl, Atrazine-desisopropyl,
                                                         or        or
 Bromacil, Chlordane, Clothianidin,
 Cyanazine, DDD, DDE, DDT, Dieldrin,               1000 ml          2      Aluminium
                                                                                           no            yes
 Dinotefurane, Endosulfan, Endrin,                       or        or      container
 Heptachlor, Imidacloprid, Lindane,
 Nitenpyram, Prometryn, Propazine,
                                                   1000 ml          4
 Thiacloprid, Thiamethoxam

 Recommended period to start the sample treatment:                                                    D0 + 8

D0 ... Day the samples are sent to all participants.

10/31                                Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 Advance notice             Pesticides in accordance with the Drinking Water Ordinance
 No PM04 (2022)
 List of substances:        Pesticides: 2,4-D (2,4-Dichlorophenoxyaceticacid), 2,4-DP (Dichlorprop),
                            Alachlor, Aldrin, Atrazine, Azoxystrobin, Bentazone, Bromacil, Chloridazon,
                            Clopyralid, Clothianidin, Dicamba, Dieldrin, Dimethachlor, Dimethenamid-
                            P, Diuron, Ethofumesate, Flufenacet, Glufosinate, Glyphosate, Heptachlor,
                            Heptachlorepoxide, Hexazinone, Imidacloprid, Iodosulfuron-methyl,
                            Isoproturon, MCPA, MCPB, MCPP (Mecoprop), Mesosulfuron-methyl,
                            Metalaxyl-M, Metamitron, Metazachlor, Metolachlor, Metribuzin,
                            Metsulfuron-methyl, Nicosulfuron, Pethoxamid, Propazine, Propiconazole,
                            Simazine, Terbuthylazine, Thiacloprid, Thiamethoxam, Thifensulfuron-
                            methyl, Tolylfluanid, Tribenuron-methyl, Triclopyr, Triflusulfuronmethyl,
                            Tritosulfuron
                            Relevant metabolites: 2-Amino-4-methoxy-6-methyl-1,3,5-triazine, 3,5,6-
                            Trichloro-2-pyridinol, 6-Chloro-1,3,5-Triazine-2,4-Diamine (Atrazine-
                            desethyl-desisopropyl), Atrazine-desethyl, Atrazine-desisopropyl,
                            Dimethachlor Metabolite CGA 369873, Dimethachlor Metabolite CGA
                            373464 (acetic acid methyl ester) - IUPAC: [(2,6-dimethyl-phenyl)-
                            methoxycarbonylmethyl-carbamoyl]-methanesulfonic acid sodium salt;
                            Dimethachlor Metabolite CGA 373464 (free acid) - CAS-No. 1196157-87-5
                            Synonym: [(2,6-Dimethylphenyl)(2-sulfoacetyl)amino]acetic acid sodium
                            salt; Dimethachlor oxalamic acid (CGA 50266, Dimethachlor-OA),
                            Dimethachlor ethane sulfonic acid (CGA 354742, Dimethachlor-ESA),
                            Isoproturon-desmethyl, Propazine-2-hydroxy, Terbuthylazine-2-hydroxy,
                            Terbuthylazine-2-hydroxy-desethyl, Terbuthylazine-desethyl
                            Non-relevant metabolites: 2,6-Dichlorobenzamide, Alachlor-t-acid
                            (Alachlor-OA), Alachlor-t-sulfonic acid (Alachlor-ESA), Aminomethyl-
                            phosphonic acid (AMPA), Atrazine-2-hydroxy, Azoxystrobin-O-demethyl
                            (CyPM), Chloridazon-desphenyl, Chloridazon-methyl-desphenyl,
                            Chlorothalonil-sulphonic acid (R417888), 3-carbamyl-2,4,5-trichlorobenzoic
                            acid (R611965), Dimethenamid-P-acid (Dimethenamid-OA),
                            Dimethenamid-P-sulfonic acid (Dimethenamid-ESA), Flufenacet oxanilic
                            acid (Flufenacet-OA), Flufenacet sulfonic acid (Flufenacet-ESA),
                            Metazachlor oxanilic acid (Metazachlor-OA), Metazachlor ethane sulfonic
                            acid (Metazachlor-ESA), Metribuzin-Desamino, N,N-Dimethylsulfamide
                            (DMS), s-Metolachlor Metabolite CGA 368208, s-Metolachlor Metabolite
                            NOA 413173, s-Metolachlor oxanilic acid (Metolachlor-OA), s-Metolachlor
                            ethanesulfonic acid (Metolachlor-ESA)
 Matrix:                    Water
 Samples:                   2; drinking water (spiked)
 Sample dispatch:           Note: The next round will be in 2022.
 Closing date:              5 Weeks after Sample dispatch
 Cost:                      EUR 790,–

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                       11/31
Proficiency Testing Scheme – Annual Programme 2021

 Technical Information

 Parameter                                                  Bottle/sample
                                                                                      Stabilisation Refrigeration
 to analyse                                       Volume    Number          Type
                                                               2
                                                                        Aluminium
                                                               or
 All mentioned groups of substances                                     container
 at page 11:                                                   4
                                                                            and
                                                              and
 Pesticides                                       1000 ml                                  no            yes
                                                                1         plastic
 Relevant metabolites                                                    container
                                                               or
 Non-relevant metabolites                                               for AMPA,
                                                                       Glyphosate,
                                                                2
                                                                       Glufosinate

The proficiency test covered pesticides, relevant and non-relevant metabolites of the drinking
water ordinance taking into account Codex chapter B1/drinking water. Supplements to codex B1
are published by the Federal Ministry of Health based on the resolution of the commission to
issue the Austrian Food Code (see BMASGK-75210/0004-IX/B/13/2019 from 05.07.2019).
Pesticides and metabolites as stipulated in the drinking water ordinance are listed in tabular
form in Codex Chapter B1/drinking water, Annex 9 of the Austrian Food Code.
(https://www.lebensmittelbuch.at/b-1-trinkwasser/anhang-9-ueberwachung-von-pestiziden-
gemaess-twv-und-nicht-relevanter-metaboliten-in-trinkwasser.html).

Note: Each pesticide/metabolite is present in at least one sample (concentration: range 1/4 up
to 10-fold of parameter value/ action value for metabolites acc. to codex chapter B1/drinking
water, Annex 9 of the Austrian Food Code).

 Recommended period to start the sample treatment:                                                   D0 + 8

D0 ... Day the samples are sent to all participants.

This proficiency test is offered every two years and the next round will take place in 2022.

12/31                                Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No P22                            Polycyclic aromatic hydrocarbons (PAH)
 List of substances:               Naphthalene, Acenaphthene, Acenaphthylene, Fluorene, Anthracene,
                                   Phenanthrene, Fluoranthene, Pyrene, Benzo(a)anthracene, Chrysene,
                                   Benzo(b)fluoranthene, Benzo(k)fluoranthene, Benzo(a)pyrene,
                                   Dibenzo(ah)anthracene, Benzo(ghi)perylene, Indeno(1,2,3-cd)pyrene
 Matrix:                           Natural water
 Samples:                          2; 1 drinking water (spiked), 1 ground water
 Sample dispatch:                  04 May 2021
 Closing date:                     01 June 2021
 Cost:                             EUR 470,–

 Technical Information

 Parameter                                                   Bottle/sample
                                                                                       Stabilisation Refrigeration
 to analyse                                            Volume      Number      Type
 Naphthalene, Acenaphthene,
 Acenaphthylene, Fluorene, Anthracene,
 Phenanthrene, Fluoranthene, Pyrene,
                                                                              brown
 Benzo(a)anthracene, Chrysene,                         1000 ml         2                   no            yes
                                                                              glass
 Benzo(b)fluoranthene, Benzo(k)fluoranthene,
 Benzo(a)pyrene, Dibenzo(ah)anthracene,
 Benzo(ghi)perylene, Indeno(1,2,3-cd)pyrene

 Recommended period to start the sample treatment:                                                    D0 + 2

D0 ... Day the samples are sent to all participants.

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                                 13/31
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No AZ8                            Pharmaceuticals, industrial chemicals and artificial sweeteners
 List of substances:               4-Acetylaminoantipyrine, Amidotrizoic acid, Atenolol, Bisoprolol,
                                   Carbamazepine, Diazepam, Diclofenac, 10,11-Dihydro-10,11-
                                   Dihydroxycarbamazepine, 4-Formylaminoantipyrine, Ibuprofen, Iopamidol,
                                   Metoprolol, Sotalol, Sulfamethoxazole, Benzotriazole, Acesulfame,
                                   Cyclamate, Saccharin, Sucralose
 Matrix:                           Natural water
 Samples:                          2; 1 municipal waste water, 1 surface water
 Sample dispatch:                  16 March 2021
 Closing date:                     20 April 2021*
 Cost:                             EUR 470,–
* Note: 5 weeks between sample dispatch and closing date (due to holiday).

 Technical Information

 Parameter                                                      Bottle/sample
                                                                                       Stabilisation Refrigeration
 to analyse                                            Volume    Number         Type
 4-Acetylaminoantipyrine, Amidotrizoic
 acid, Atenolol, Bisoprolol,
 Carbamazepine, Diazepam,
                                                                                          yes
 Diclofenac, 10,11-Dihydro-10,11-Di-
                                                                                        (approx.
 hydroxycarbamazepine,                                                     Aluminium
                                                   1000 ml          2                    10 mg           yes
 4-Formylaminoantipyrine, Ibuprofen,                                       container
                                                                                        Sodium
 Iopamidol, Metoprolol, Sotalol,
                                                                                         azide)
 Sulfamethoxazole, Benzotriazole,
 Acesulfame, Cyclamate, Saccharin,
 Sucralose

 Recommended period to start the sample treatment:                                                   D0 + 8

D0 ... Day the samples are sent to all participants.

14/31                                Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No SP06                           Sum parameters
 List of sum parameters:           Hydrocarbon oil index and phenol index
                                   Optional: only hydrocarbon oil index possible
 Matrix:                           Natural water
 Samples:                          2; 1 drinking water (spiked), 1 ground water
 Sample dispatch:                  18 May 2021
 Closing date:                     15 June 2021
 Cost:                             EUR 415,– (for hydrocarbon oil index and phenol index)
                                   EUR 250,– (for hydrocarbon oil index only)

 Technical Information

 Parameter                                        Bottle/sample
                                                                                 Stabilisation        Refrigeration
 to analyse                               Volume       Number      Type
 Hydrocarbon oil index                    1000 ml        2        Glass               no                  yes
                                                                            yes, pH < 4 with H3PO4
 Phenol index                             1000 ml        2        Glass              and                  yes
                                                                              CuSO4 x 5H2O 1g/l

 Recommended period to start the sample treatment:                                                     D0 + 2

D0 ... Day the samples are sent to all participants.

For SP06, you can choose proficiency test for hydrocarbon oil index and phenol index or
hydrocarbon oil index only. The selection of phenol index only is not possible. The evaluation
data of both sum parameters are presented in a joint report.

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                                  15/31
Proficiency Testing Scheme – Annual Programme 2021

 Programmbeschreibung
 No B12                            BTEX/MTBE
 List of substances:               BTEX: Benzene, Toluene, Ethylbenzene, o-Xylene, sum of m-Xylene and
                                   p-Xylene; Methyl-tertiary-butylether (MTBE)
 Matrix:                           Natural water
 Samples:                          2; 1 surface water, 1 ground water (partly fortified)
 Sample dispatch:                  1 June 2021
 Closing date:                     29 June 2021
 Cost:                             EUR 435,–

 Technical Information

 Parameter                                                      Bottle/sample
                                                                                       Stabilisation Refrigeration
 to analyse                                            Volume Number            Type
 BTEX: Benzene, Toluene,
 Ethylbenzene, o-Xylene, sum of                                            Aluminium
                                                       600 ml      1                       no            yes
 m-Xylene and p-Xylene;                                                    container
 Methyl-tertiary-butylether (MTBE)

 Recommended period to start the sample treatment:                                                    D0 + 8

D0 ... Day the samples are sent to all participants.

Additional proficiency tests (synthetic samples) performed by our partner IFA-Tulln
(registration www.ifatest.eu). The single price for BTEX/MTBE or VHH is EUR 435,–.
The price for VHH and BTEX/MTBE is EUR 790,–.

                                                                        Sample dispatch         Closing date
 No             BTEX/MTBE                                               11 October 2021      12 November 2021*
 B-CB08         BTEX: Benzene, Toluene, Ethylbenzene,
                o-Xylene, sum of m-Xylene and p-Xylene;
                Methyl tertiary-butyl ether (MTBE)
* Note: 5 weeks between sample dispatch and closing date (due to holiday).

In round CB08 the extent of participation is selectable (BTEX/MTBE, VHH or both).
Evaluation of the round will be carried out in a joint report.

16/31                                Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Programmbeschreibung
 Advance notice                    Volatile Halogenated Hydrocarbons (VHH)
 No C66 (2022)
 List of substances:               VHH: Bromodichloromethane, Dibromochloromethane, 1,2-Dichloroethane,
                                   1,1-Dichloroethene, cis-1,2-Dichloroethene, trans-1,2-Dichloroethene,
                                   Dichloromethane, Tetrachloroethene, Tetrachloromethane, Tribromomethane,
                                   1,1,1-Trichloroethane, Trichloroethene, Trichloromethane
 Matrix:                           Natural water
 Samples:                          2; 1 surface water, 1 ground water (partly fortified)
 Sample dispatch:                  Note: The next proficiency test VHH in real water samples will take place in
                                   2022.
 Closing date:                     4 weeks after sample delivery
 Cost:                             EUR 435,–

 Technical Information

 Parameter                                                      Bottle/sample
                                                                                        Stabilisation Refrigeration
 to analyse                                            Volume Number            Type
 VHH: Bromodichloromethane,
 Dibromochloromethane,
 1,2-Dichloroethane, 1,1-Dichloroethene,
 cis-1,2-Dichloroethene, trans-1,2-                                        Aluminium
                                                       600 ml      1                        no            yes
 Dichloroethene, Dichloromethane,                                          container
 Tetrachloroethene, Tetrachloromethane,
 Tribromomethane, 1,1,1-Trichloroethane,
 Trichloroethene, Trichloromethane

 Recommended period to start the sample treatment:                                                     D0 + 8

D0 ... Day the samples are sent to all participants.

The proficiency tests VHH and BTEX&MTBE in real water samples will be offered in an
alternating mode. In 2021 BTEX&MTBE are offered and a proficiency test for VHH for real
water samples will take place in 2022.

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                                  17/31
Proficiency Testing Scheme – Annual Programme 2021

Additional proficiency tests (synthetic samples) will be performed by our partner IFA-Tulln
(registration www.ifatest.eu). The single price for VHH or BTEX/MTBE is EUR 435,–.
The price for VHH and BTEX/MTBE is EUR 790,–.

                                                                    Sample dispatch         Closing date
 No C64        Volatile halogenated hydrocarbons (VHH)              22 February 2021        19 March 2021
               VHH: Bromodichloromethane,
               Dibromochloromethane, 1,2-Dichloroethane,
               1,1-Dichloroethene, cis-1,2-Dichloroethene,
               trans-1,2-Dichloroethene, Dichloromethane,
               Tetrachloroethene, Tetrachloromethane,
               Tribromomethane, 1,1,1-Trichloroethane,
               Trichloroethene, Trichloromethane
 No C65        Volatile halogenated hydrocarbons (VHH)                 07 June 2021          02 July 2021
               VHH: Bromodichloromethane,
               Dibromochloromethane, 1,2-Dichloroethane,
               1,1-Dichloroethene, cis-1,2-Dichloroethene,
               trans-1,2-Dichloroethene, Dichloromethane,
               Tetrachloroethene, Tetrachloromethane,
               Tribromomethane, 1,1,1-Trichloroethane,
               Trichloroethene, Trichloromethane
 No CB08       Volatile halogenated hydrocarbons (VHH)               11 October 2021     12 November 2021*
               VHH: Bromodichloromethane,
               Dibromochloromethane, 1,2-Dichloroethane,
               1,1-Dichloroethene, cis-1,2-Dichloroethene,
               trans-1,2-Dichloroethene, Dichloromethane,
               Tetrachloroethene, Tetrachloromethane,
               Tribromomethane, 1,1,1-Trichloroethane,
               Trichloroethene, Trichloromethane
 No CB08       BTEX/MTBE                                             11 October 2021     12 November 2021*
               BTEX: Benzene, Toluene, Ethylbenzene,
               o-Xylene, sum of m-Xylene and p-Xylene;
               Methyl tertiary-butyl ether (MTBE)
* Note: 5 weeks between sample dispatch and closing date (due to holiday).

In round CB08 the extent of participation is selectable (VHH, BTEX/MTBE or both).
Evaluation of the round will be carried out in a joint report.

18/31                             Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

Minimum concentrations and performance criterion

The concentrations are at levels typical for natural water samples (ground water, surface water).
The pesticides, relevant and non-relevant metabolites of the drinking water ordinance are in a
concentration range from 1/4 up to 10-fold of the parameter or action value according to Codex
chapter B1/drinking water (www.lebensmittelbuch.at/trinkwasser/). The lower concentration
limits are given in the tables below.

The criterion used to evaluate the participants’ performance is the reproducibility standard
deviation calculated from previous rounds of proficiency testing with real water samples (more
than 6 rounds, since 2013, see tables below). As an alternative criterion, the reproducibility
standard deviation vR is calculated from the participants’ results after removal of outliers in the
current round.
Please find additional information on synthetic water samples at our partner IFA-Tulln website
(www.ifatest.eu).

 Metals and Trace elements
 Parameter                                                      Unit      Lower limit       Criterion
 Aluminium                                                      µg/l               10            15 %
 Arsenic                                                        µg/l               0.5           13 %
 Cadmium                                                        µg/l              0.01           10 %
 Chromium                                                       µg/l              0.15          8.5 %
 Copper                                                         µg/l                 1            9%
 Iron                                                           µg/l               10            18 %
 Lead                                                           µg/l               0.1           15 %
 Manganese                                                      µg/l                 1          7.2 %
 Mercury                                                        µg/l               0.1           14 %
 Nickel                                                         µg/l               0.5           12 %
 Selenium                                                       µg/l               0.3           12 %
 Uranium                                                        µg/l               0.5          6.6 %
 Zinc                                                           µg/l                 5            9%

 Nutrients and Major ions
 Parameter                                                      Unit      Lower limit       Criterion
 Alkalinity KS 4,3                                           mmol/l                0.4          2.0 %
 Ammonium (as NH4+)                                             mg/l              0.01           12 %
 Boron                                                          mg/l             0.015           11 %
 Calcium                                                        mg/l               10           3.1 %
 Chloride                                                       mg/l                 1          4.0 %
 DOC dissolved organic carbon (as C)                            mg/l               0.5           10 %
 Electrical conductivity (25 °C)                              µS/cm               100           1.3 %
 Hydrogen carbonate                                             mg/l               20           2.0 %
 K (Potassium)                                                  mg/l                 1          5.2 %
 Mg (Magnesium)                                                 mg/l                 1          4.0 %
 Na (Sodium)                                                    mg/l                 1          3.4 %

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                    19/31
Proficiency Testing Scheme – Annual Programme 2021

 Nutrients and Major ions
 Parameter                                                             Unit       Lower limit        Criterion
 Nitrate (as NO3    -)                                                  mg/l                 1           5.0 %
 Nitrite (as NO2-)                                                      mg/l              0.01           5.3 %
 Ortho-Phosphate (as PO43-)                                             mg/l              0.02           9.0 %
 pH                                                                        -                 5           2.0 %
 Sulfate SO4   2-                                                       mg/l                 1           3.3 %
 Total hardness                                                      mmol/l               0.02           3.0 %
 Total N (total Nitrogen)                                               mg/l               0.5           8.3 %
 Total P (dissolved as PO4   3-)                                        mg/l              0.02           7.5 %

 Herbicides/Pesticides - H109
 Parameter                                                              Unit      Lower limit        Criterion
 2,6-Dichlorbenzamide                                                    µg/l             0.03            15 %
 Alachlor                                                                µg/l             0.03            12 %
 Atrazine                                                                µg/l             0.03            11 %
 Atrazine-Desethyl                                                       µg/l             0.05            12 %
 Atrazine-Desethyl-Desisopropyl                                          µg/l             0.05              vR
 Atrazine-Desisopropyl                                                   µg/l             0.05            14 %
 Bromacil                                                                µg/l             0.03            14 %
 Chloridazon                                                             µg/l             0.03            13 %
 Chloridazon-Desphenyl                                                   µg/l             0.05            11 %
 Chloridazon-Methyl-Desphenyl                                            µg/l             0.03            13 %
 Clopyralid                                                              µg/l             0.05            34 %
 Cyanazine                                                               µg/l             0.03            14 %
 Dimethenamide                                                           µg/l             0.03           9.9 %
 Diuron                                                                  µg/l             0.03            13 %
 Metolachlor                                                             µg/l             0.03            15 %
 N,N-Dimethylsulfamide (DMS)                                             µg/l             0.05            15 %
 Nicosulfurone                                                           µg/l             0.05            37 %
 Prometryn                                                               µg/l             0.03            13 %
 Propazine                                                               µg/l             0.03            13 %
 Sebuthylazine                                                           µg/l             0.03           9.3 %
 Simazine                                                                µg/l             0.03            11 %
 Terbuthylazine                                                          µg/l             0.03            11 %
 Terbuthylazine-Desethyl                                                 µg/l             0.05            11 %
 Terbutryn                                                               µg/l             0.03            10 %

20/31                              Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Herbicides/Pesticides - H110
 Parameter                                                       Unit      Lower limit       Criterion
 2,4,5- Trichlorophenoxy-acetic acid                              µg/l             0.05           18 %
 2,4-D (2,4-Dichlorophenoxyaceticacid)                            µg/l             0.05           14 %
 Alachlor                                                         µg/l             0.05           12 %
 Alachlor-t-acid (Alachlor-OA)                                    µg/l             0.05           15 %
 Alachlor-t-sulfonic acid (Alachlor-ESA)                          µg/l             0.05             vR
 Aminomethylphosphonic acid (AMPA)                                µg/l             0.06           13 %
 Bentazone                                                        µg/l             0.03           15 %
 Dicamba                                                          µg/l             0.05           20 %
 Dichlorprop                                                      µg/l             0.05           12 %
 Glufosinate                                                      µg/l             0.06           34 %
 Glyphosate                                                       µg/l             0.06           20 %
 Mecoprop                                                         µg/l             0.05           13 %
 Metazachlor                                                      µg/l             0.03           12 %
 Metazachlor oxanilic acid (Metazachlor-OA)                       µg/l             0.05           21 %
 Metazachlor ethane sulfonic acid (Metazachlor-ESA)               µg/l             0.05           19 %
 Metolachlor                                                      µg/l             0.03           15 %
 s-Metolachlor oxanilic acid (Metolachlor-OA)                     µg/l             0.05           14 %
 s-Metolachlor ethanesulfonic acid (Metolachlor-ESA)              µg/l             0.05           20 %
 Herbicides/Pesticides - H111
 Acetamiprid                                                      µg/l             0.03             vR
 Aldrin                                                           µg/l             0.02           44 %
 Atrazine                                                         µg/l             0.03           11 %
 Atrazine-Desethyl                                                µg/l             0.05           12 %
 Atrazine-Desisopropyl                                            µg/l             0.05           14 %
 Bromacil                                                         µg/l             0.03           14 %
 Chlordane                                                        µg/l             0.02           30 %
 Clothianidin                                                     µg/l             0.03           11 %
 Cyanazine                                                        µg/l             0.03           14 %
 DDD                                                              µg/l             0.02           37 %
 DDE                                                              µg/l             0.02           37 %
 DDT                                                              µg/l             0.02           39 %
 Dieldrin                                                         µg/l             0.02           23 %
 Dinotefurane                                                     µg/l             0.05             vR
 Endosulfan                                                       µg/l             0.02           41 %
 Endrin                                                           µg/l             0.02           18 %
 Heptachlor                                                       µg/l             0.02           46 %
 Imidacloprid                                                     µg/l             0.03           15 %
 Lindane                                                          µg/l             0.01           20 %
 Nitenpyram                                                       µg/l             0.05             vR
 Prometryn                                                        µg/l             0.03           13 %
 Propazine                                                        µg/l             0.03           13 %
 Thiacloprid                                                      µg/l             0.05           14 %
 Thiamethoxam                                                     µg/l             0.05           17 %

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                     21/31
Proficiency Testing Scheme – Annual Programme 2021

 Pesticides in accordance with the Drinking Water Ordinance
 Parameter                                                          Unit      Lower limit        Criterion
 2,4-D (2,4-Dichlorophenoxyaceticacid)                               µg/l            0.025            14 %
 2,4-DP (Dichlorprop)                                                µg/l            0.025            12 %
 Alachlor                                                            µg/l            0.025            12 %
 Aldrin                                                              µg/l          0.0075             44 %
 Atrazine                                                            µg/l            0.025            11 %
 Azoxystrobin                                                        µg/l            0.025              vR
 Bentazone                                                           µg/l            0.025            15 %
 Bromacil                                                            µg/l            0.025            14 %
 Chloridazon                                                         µg/l            0.025            13 %
 Clopyralid                                                          µg/l            0.025            34 %
 Clothianidin                                                        µg/l            0.025            11 %
 Dicamba                                                             µg/l            0.025            20 %
 Dieldrin                                                            µg/l          0.0075             23 %
 Dimethachlor                                                        µg/l            0.025              vR
 Dimethenamid-P                                                      µg/l            0.025            10 %
 Diuron                                                              µg/l            0.025            13 %
 Ethofumesate                                                        µg/l            0.025              vR
 Flufenacet                                                          µg/l            0.025              vR
 Glufosinate                                                         µg/l            0.025            34 %
 Glyphosate                                                          µg/l            0.025            20 %
 Heptachlor                                                          µg/l          0.0075             46 %
 Heptachlorepoxide                                                   µg/l          0.0075               vR
 Hexazinone                                                          µg/l            0.025              vR
 Imidacloprid                                                        µg/l            0.025            15 %
 Iodosulfuron-methyl                                                 µg/l            0.025              vR
 Isoproturon                                                         µg/l            0.025              vR
 MCPA                                                                µg/l            0.025              vR
 MCPB                                                                µg/l            0.025              vR
 MCPP (Mecoprop)                                                     µg/l            0.025            13 %
 Mesosulfuron-methyl                                                 µg/l            0.025              vR
 Metalaxyl-M                                                         µg/l            0.025              vR
 Metamitron                                                          µg/l            0.025              vR
 Metazachlor                                                         µg/l            0.025            12 %
 Metolachlor                                                         µg/l            0.025            15 %
 Metribuzin                                                          µg/l            0.025              vR
 Metsulfuron-methyl                                                  µg/l            0.025              vR
 Nicosulfuron                                                        µg/l            0.025            37 %
 Pethoxamid                                                          µg/l            0.025              vR
 Propazine                                                           µg/l            0.025            13 %
 Propiconazole                                                       µg/l            0.025              vR
 Simazine                                                            µg/l            0.025            11 %
 Terbuthylazine                                                      µg/l            0.025            11 %

22/31                          Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Pesticides in accordance with the Drinking Water Ordinance
 Parameter                                                       Unit      Lower limit       Criterion
 Thiacloprid                                                      µg/l           0.025            14 %
 Thiamethoxam                                                     µg/l           0.025            17 %
 Thifensulfuron-methyl                                            µg/l           0.025              vR
 Tolylfluanid                                                     µg/l           0.025              vR
 Tribenuron-methyl                                                µg/l           0.025              vR
 Triclopyr                                                        µg/l           0.025              vR
 Triflusulfuron-methyl                                            µg/l           0.025              vR
 Tritosulfuron                                                    µg/l           0.025              vR
 Relevant metabolites
 2-Amino-4-Methoxy-6-Methyl-1,3,5-Triazine                        µg/l           0.025              vR
 3,5,6-Trichloro-2-Pyridinol                                      µg/l           0.025              vR
 6-Chloro-1,3,5-Triazine-2,4-Diamine (Atrazine-Desethyl-          µg/l           0.025              vR
 Desisopropyl)
 Atrazine-Desethyl                                                µg/l           0.025            12 %
 Atrazine-Desisopropyl                                            µg/l           0.025            14 %
 Dimethachlor ethane sulfonic acid (CGA 354742,                   µg/l           0.025              vR
 Dimethachlor-ESA)
 Dimethachlor oxalamic acid (CGA 50266, Dimethachlor-             µg/l           0.025              vR
 OA)
 Dimethachlor Metabolite - CGA 373464                             µg/l           0.025              vR
 Dimethachlor Metabolite - CGA 369873                             µg/l           0.025              vR
 Isoproturon-Desmethyl                                            µg/l           0.025              vR
 Propazine-2-Hydroxy                                              µg/l           0.025              vR
 Terbuthylazine-Desethyl                                          µg/l           0.025            11 %
 Terbuthylazine-2-Hydroxy                                         µg/l           0.025              vR
 Terbuthylazine-2-Hydroxy-Desethyl                                µg/l           0.025              vR
 Non-relevant metabolites
 2,6-Dichlorobenzamide                                            µg/l             0.75           15 %
 Alachlor-t-acid (Alachlor-OA)                                    µg/l             0.75           15 %
 Alachlor-t-sulfonic acid (Alachlor-ESA)                          µg/l             0.75             vR
 Aminomethyl-phosphonic acid (AMPA)                               µg/l             0.75           13 %
 Atrazine-2-Hydroxy                                               µg/l             0.75             vR
 Azoxystrobin-O-Demethyl (CyPM)                                   µg/l             0.25             vR
 Chloridazon-Desphenyl                                            µg/l             0.75           11 %
 Chloridazon-Methyl-Desphenyl                                     µg/l             0.75           13 %
 Chlorothalonil-sulphonic acid (R417888)                          µg/l             0.75             vR
 3-carbamyl-2,4,5-trichlorobenzoic acid (R611965)                 µg/l             0.75             vR
 Dimethenamid-P-sulfonic acid (Dimethenamid-ESA)                  µg/l           0.125              vR
 Dimethenamid-P-acid (Dimethenamid-OA)                            µg/l           0.125              vR
 Flufenacet sulfonic acid (Flufenacet-ESA)                        µg/l             0.25             vR
 Flufenacet oxanilic acid (Flufenacet-OA)                         µg/l           0.075              vR
 Metazachlor ethane sulfonic acid (Metazachlor-ESA)               µg/l             0.75           19 %
 Metazachlor oxanilic acid (Metazachlor-OA)                       µg/l             0.75           21 %

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                     23/31
Proficiency Testing Scheme – Annual Programme 2021

 Pesticides in accordance with the Drinking Water Ordinance
 Parameter                                                          Unit      Lower limit        Criterion
 Metribuzin-Desamino                                                 µg/l            0.075              vR
 N,N-Dimethylsulfamide (DMS)                                         µg/l             0.25            15 %
 s-Metolachlor ethanesulfonic acid (Metolachlor-ESA)                 µg/l             0.75            20 %
 s-Metolachlor oxanilic acid (Metolachlor-OA)                        µg/l             0.75            14 %
 s-Metolachlor Metabolite NOA 413173                                 µg/l            0.075              vR
 s-Metolachlor Metabolite CGA 368208                                 µg/l            0.075              vR

 Polycyclic aromatic hydrocarbons (PAH)
 Parameter                                                           Unit     Lower limit        Criterion
 Acenaphthene                                                         ng/l               5            19 %
 Acenaphthylene                                                       ng/l               5              vR
 Anthracene                                                           ng/l               5              vR
 Benzo(a)anthracene                                                   ng/l               5            21 %

 Benzo(a)pyrene                                                       ng/l               5            24 %
 Benzo(b)fluoranthene                                                 ng/l               5            17 %
 Benzo(g,h,i)perylene                                                 ng/l               5            32 %
 Benzo(k)fluoranthene                                                 ng/l               5            26 %
 Chrysene                                                             ng/l               5              vR
 Dibenzo(a,h)anthracene                                               ng/l               5            30 %
 Fluoranthene                                                         ng/l               5            18 %
 Fluorene                                                             ng/l               5            14 %
 Indeno(1,2,3-cd)pyrene                                               ng/l               5              vR
 Naphthalene                                                          ng/l               5            21 %
 Phenanthrene                                                         ng/l               5            15 %
 Pyrene                                                               ng/l               5            16 %

 Pharmaceuticals, Industrial Chemicals and Artificial Sweeteners
 Parameter                                                           Unit     Lower limit        Criterion
 10,11-Dihydro-10,11-Dihydroxycarbamazepine                           µg/l            0.05              vR
 4-Acetylaminoantipyrine                                              µg/l            0.05              vR
 4-Formylaminoantipyrine                                              µg/l            0.05              vR
 Acesulfame                                                           µg/l            0.05            17 %
 Amidotrizoic acid                                                    µg/l            0.05              vR
 Atenolol                                                             µg/l            0.05              vR
 Benzotriazole                                                        µg/l            0.05            12 %
 Bisoprolol                                                           µg/l            0.05              vR
 Carbamazepine                                                        µg/l            0.03            13 %
 Cyclamate                                                            µg/l            0.03              vR
 Diazepam                                                             µg/l            0.05              vR

24/31                          Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Pharmaceuticals, Industrial Chemicals and Artificial Sweeteners
 Parameter                                                        Unit    Lower limit       Criterion
 Diclofenac                                                       µg/l           0.05            14 %
 Ibuprofen                                                        µg/l           0.05                vR
 Iopamidol                                                        µg/l           0.05                vR
 Metoprolol                                                       µg/l           0.05            25 %
 Saccharin                                                        µg/l           0.05            22 %
 Sotalol                                                          µg/l           0.05            22 %
 Sucralose                                                        µg/l           0.05            30 %
 Sulfamethoxazole                                                 µg/l           0.05            12 %

 Sum parameters: Hydrocarbon oil index and Phenol index
 Parameter                                                 Unit          Lower limit     Criterion
 Hydrocarbon oil index                                            mg/l            0.1            42 %
 Phenol Index                                                     mg/l           0.01            11 %

 Volatile Halogenated Hydrocarbons (VHH), BTEX and MTBE
 Parameter                                                        Unit    Lower limit       Criterion
 VHH
 1,1,1-Trichloroethane                                            µg/l           0.15            15 %
 1,1-Dichloroethene                                               µg/l             0.5           17 %
 1,2-Dichloroethane                                               µg/l             0.5           13 %
 Bromodichlormethane                                              µg/l           0.15           8.4 %
 cis-1,2-Dichloroethene                                           µg/l           0.15            10 %
 Dibromochloromethane                                             µg/l           0.15            12 %
 Dichloromethane                                                  µg/l               1           13 %
 Tetrachloroethene                                                µg/l           0.15            17 %
 Tetrachloromethane                                               µg/l           0.15            16 %
 trans-1,2-Dichloroethene                                         µg/l           0.15            20 %
 Tribromomethane                                                  µg/l           0.15            12 %
 Trichloroethene                                                  µg/l           0.15            15 %
 Trichloromethane                                                 µg/l           0.25            13 %
 BTEX and MTBE
 Benzene                                                          µg/l             0.5           16 %
 Ethylbenzene                                                     µg/l             0.5               vR
 o-Xylene                                                         µg/l             0.5               vR
 Sum of m-Xylene and p-Xylene                                     µg/l               1           20 %
 Toluene                                                          µg/l             0.5           28 %
 Methyl-tert-butylether (MTBE)                                    µg/l             0.5           13 %

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                    25/31
Proficiency Testing Scheme – Annual Programme 2021

PROFICIENCY TESTING SCHEME
ENVIRONMENTAL ANALYSIS

 Description of Programme
 No AB10                           Waste acc. to landfill directive (Austria) (total contents)
 List of substances:               Solid samples:
                                   Sb, As, Ba, Pb, Cd, Cr, Co, Cu, Mo, Ni, Hg, Se, Ag, V, Zn, Sn, TOC,
                                   hydrocarbon oil index, PAH (sum of 16 polycyclic aromatic hydrocarbons
                                   acc. to EPA), Benzo(a)pyrene
 Matrix:                           Waste
 Samples:                          1 homogenized solid sample
 Sample dispatch:                  21 September 2021
 Closing date:                     19 October 2021
 Cost excl. VAT:                   EUR 470,–

 Technical Information

 Parameter                                                 Vessel/sample
                                                                                       Stabilisation Refrigeration
 to analyse                                      Volume        Number        Type
 Total content
 Sb, As, Ba, Pb, Cd, Cr, Co, Cu,
 Mo, Ni, Hg, Se, Ag, V, Zn, Sn,                  approx.          1         plastic
 TOC, hydrocarbon oil index, sum                                                           no             no
                                                  0.3 kg         each      container
 of PAHs (EPA), Benzo(a)pyrene

 Recommended period to start the sample treatment:                                                    D0 + 8

D0 ... Day the samples are sent to all participants.

26/31                                Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 Advance notice                    Waste acc to landfill directive (Austria) (eluate metals only)
 No AB11 2022
 List of substances:               eluate:
                                   Al, Sb, As, Ba, Pb, B, Cd, Cr, Co, Fe, Cu, Mo, Ni, Hg, Se, Ag, V, Zn, Sn
 Matrix:                           Waste
 Samples:                          1 eluate sample
 Sample dispatch:                  2022
 Closing date:                     4 weeks after sample dispatch
 Cost excl. VAT:                   EUR 470,–

 Technical Information

 Parameter                                              Bottle/sample
                                                                                   Stabilisation     Refrigeration
 to analyse                                    Volume Number            Type
                                               100 ml       1                    yes, with HNO3
Al, Sb, As, Ba, Pb, B, Cd, Cr, Co, Fe,          and        and      plastic            and                   yes
Cu, Mo, Ni, Hg, Se, Ag, V, Zn, Sn                                  container
                                               100 ml       1                   yes, with HCl (Hg)

 Recommended period to start the sample treatment:                                                    D0 + 8

D0 ... Day the samples are sent to all participants.

 Description of Programme
 Advance notice                    Waste acc to landfill directive (Austria) (eluate ions only)
 No AB12 2022
 List of substances:               eluate:
                                   pH, electrical conductivity, evaporation residue, NH4+ (as N), Cl-, F-,
                                   NO3- (as N), NO2- (as N), PO43- (as P), SO42-, TOC (as C)
 Matrix:                           Waste
 Samples:                          1 eluate sample
 Sample dispatch:                  2022
 Closing date:                     4 weeks after sample dispatch
 Cost excl. VAT:                   EUR 470,–

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                                 27/31
Proficiency Testing Scheme – Annual Programme 2021

 Technical Information

 Parameter                                               Bottle/sample
                                                                                     Stabilisation Refrigeration
 to analyse                                     Volume       Number        Type

 pH, electrical conductivity,                   500 ml          1                          no
 evaporation residue, NH4 (as N),                and           and        plastic         and
                                                                                                         yes
 Cl, F, NO3 (as N), NO2 (as N),                                          container     yes, with
 PO4 (as P), SO4, TOC (as C)                    100 ml           1
                                                                                      HCl (TOC)

 Recommended period to start the sample treatment:                                                   T0 + 8

D0 ... Day the samples are sent to all participants.

28/31                                Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No CL08                           Chlorinated hydrocarbons (CHC)
 List of substances:               Trichloromethane, 1,1,1-Trichloroethane, Trichloroethene, Tetrachloro-
                                   methane, Tetrachloroethene, cis-1,2-Dichloroethene, trans-1,2-
                                   Dichloroethene
 Matrix:                           Ambient air
 Samples:                          1 (+ 1 unloaded tube)
 Sample dispatch:                  05 October 2021
 Closing date:                     02 November 2021
 Cost excl. VAT:                   EUR 470,–

 Technical Information

 Parameter                                             Tube/sample
                                                                                    Stabilisation Refrigeration
 to analyse                                 Volume      Number          Type
 Trichloromethane,
 1,1,1-Trichloroethane,
                                                            1         activated
 Trichloroethene,
                                                          (and      charcoal tube
 Tetrachloromethane,                            –                                       no             no
                                                       1 unloaded    (Orbo 32 S,
 Tetrachloroethene,
                                                          tube)       Supelco)
 cis-1,2-Dichloroethene,
 trans-1,2-Dichloroethene

 Recommended period to start the sample treatment:                                                 D0 + 8

D0 ... Day the samples are sent to all participants.

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                              29/31
Proficiency Testing Scheme – Annual Programme 2021

 Description of Program
 No BL09                           BTEX & C5-C10
 List of substances:               BTEX: Benzene, Toluene, Ethylbenzene, sum of m-Xylene and p-Xylene,
                                   o-Xylene; C5-C10: n-Pentane, n-Hexane, n-Heptane, n-Octane, n-Nonane,
                                   n-Decane
 Matrix:                           Ambient air
 Samples:                          1 (+ 1 unloaded tube)
 Sample dispatch:                  05 October 2021
 Closing date:                     02 November 2021
 Cost excl. VAT:                   EUR 470,–

 Technical Information

 Parameter                                               Tube/sample
                                                                                      Stabilisation Refrigeration
 to analyse                                   Volume     Number           Type
 BTEX: Benzene, Toluene,
                                                            1          activated
 Ethylbenzene, sum of m-Xylene
                                                          (and       charcoal tube
 and p-Xylene, o-Xylene; C5-C10:                 –                                         no            no
                                                       1 unloaded     (Orbo 32 S,
 n-Pentane, n-Hexane, n-Heptane,
                                                          tube)        Supelco)
 n-Octane, n-Nonane, n-Decane

 Recommended period to start the sample treatment:                                                   D0 + 8

D0 ... Day the samples are sent to all participants.

30/31                                Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021
Proficiency Testing Scheme – Annual Programme 2021

 Description of Programme
 No CBL07                          Chlorinated hydrocarbons (CHC) and BTEX & C5-C10
 List of substances:               CHC: Trichloromethane, 1,1,1-Trichloroethane, Trichloroethene,
                                   Tetrachloromethane, Tetrachloroethene, cis-1,2-Dichloroethene, trans-1,2-
                                   Dichloroethene;
                                   BTEX: Benzene, Toluene, Ethylbenzene, sum of m-Xylene and p-Xylene,
                                   o-Xylene; C5-C10: n-Pentane, n-Hexane, n-Heptane, n-Octane, n-Nonane,
                                   n-Decane
 Matrix:                           Ambient air
 Samples:                          2 (+ 1 unloaded tube each)
 Sample dispatch:                  05 October 2021
 Closing date:                     02 November 2021
 Cost excl. VAT:                   EUR 820,–

 Technical Information

 Parameter                                              Tube/sample
                                                                                     Stabilisation Refrigeration
 to analyse                                   Volume    Number            Type
 CHC: Trichloromethane,
 1,1,1-Trichloroethane,
 Trichloroethene,
 Tetrachloromethane,
 Tetrachloroethene,
                                                                       activated
 cis-1,2-Dichloroethene,                                  1+1
                                                                       charcoal
 trans-1,2-Dichloroethene;                                (and
                                                 –                       tube             no             no
                                                       1 unloaded
 BTEX: Benzene, Toluene,                                              (Orbo 32 S,
                                                       tube each)
 Ethylbenzene, sum of m-xylene                                         Supelco)
 and p-xylene, o-xylene;
 C5-C10: n-Pentane, n-Hexane,
 n-Heptane, n-Octane, n-Nonane,
 n-Decane

 Recommended period to start the sample treatment:                                                   D0 + 8

D0 ... Day the samples are sent to all participants.

Electronic registration:

https://www.ifatest.eu/ or
https://www.umweltbundesamt.at/en/proficiency-testing

Umweltbundesamt  https://www.umweltbundesamt.at/en/proficiency-testing  2021                                31/31
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