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Article
Repair of a Cracked Historic Maryan Bell by Gas Welding
Dariusz Bartocha              and Czesław Baron *

                                          Department of Foundry, Silesian University of Technology, 7 Towarowa St., 44-100 Gliwice, Poland;
                                          dariusz.bartocha@polsl.pl
                                          * Correspondence: czeslaw.baron@polsl.pl

                                          Abstract: In this article, the range of works connected with the repair of a historical Maryan bell from
                                          1639 are presented. The first attempts to repair damaged bells occurred in the 1930s in Poland. How-
                                          ever, this process was stopped because of extensive technological difficulties. Welding and soldering-
                                          welding were the basic methods. There is one difference between these two methods—connecting
                                          surfaces are melted during the welding process but only heated until the melting temperature of the
                                          material added to the connection (that is the solder) during the soldering-welding process. It was
                                          important to heat the bell to the proper temperature during welding. Uneven heating causes the
                                          enlargement of existing cracks or the appearance of new ones, or even the complete destruction of the
                                          bell. Nowadays, a method of even heating using a special heating mat has been devised. Thanks to
                                          this method it is possible to control the heating and cooling process. The most important task during
                                          the whole operation of bell welding was obtaining the original sound. During this research, the
                                          chemical composition was examined to prepare a welding rod with a suitable chemical composition.
                                          After the repair process, an analysis of the sound of the bell was conducted. It was shown that the
                                          repair of bells is possible when correct thermal parameters are used. The most highly recommended
                                          technique for repairing bells is gas welding.
         
                                   Keywords: high-tin bronzes; microstructure; welding of bell; bell’s sound
Citation: Bartocha, D.; Baron, C.
Repair of a Cracked Historic Maryan
Bell by Gas Welding. Materials 2021,
14, 2504. https://doi.org/10.3390/        1. Introduction
ma14102504
                                                There are a lot of churches with very old, historical bells in Poland, as it has historically
                                          been a Catholic country. Unfortunately, their strength is decreasing and cracks and scratches
Academic Editor: Sergei Yu Tarasov
                                          are have appeared. These defects make them useless, because not only does the sound
                                          become worse, but reacting to the damage too late can cause the complete destruction of
Received: 2 April 2021
                                          the bell as well.
Accepted: 9 May 2021
Published: 12 May 2021
                                                The lifetime of the bell was determined to be 200–300 years [1] on the basis of data in
                                          the literature. After that time the probability of the bell cracking is increased. Of course,
Publisher’s Note: MDPI stays neutral
                                          it depends on many factors, such as the frequency of bell work and the bell’s rotation on
with regard to jurisdictional claims in
                                          its suspension. Unless the bell is rotated, the clapper hits the same place and it may cause
published maps and institutional affil-
                                          cracks. It is important to control the thickness of that place. If the thickness falls more than
iations.                                  10%, it is necessary to rotate the bell to allow it to hit another place. Constant hits on the
                                          same place also causes changes to the inner structure of the material. It becomes harder
                                          and loses strength properties. Concurrently, inner stresses increase. When stresses exceed
                                          the material strength limit, the bell will be damaged, and cracks and scratches will appear.
                                          It is hard to notice such a crack on a bell placed high in a tower, but it is possible to hear
Copyright: © 2021 by the authors.
Licensee MDPI, Basel, Switzerland.
                                          the change in the sound, which is usually much worse than the original sound.
This article is an open access article
                                                The repair of the bell is possible up to its complete destruction. Repairing the bell is
distributed under the terms and
                                          an expensive and time-consuming process. However, attempts to repair these bells are not
conditions of the Creative Commons        rare, because the bell is a precious item not only thanks to its material value but also its
Attribution (CC BY) license (https://     historical and artistic value as well. Despite the avoidance of the repair of cracked bells in
creativecommons.org/licenses/by/          Poland for a long time, this problem has been considered in many other countries [2,3].
4.0/).

Materials 2021, 14, 2504. https://doi.org/10.3390/ma14102504                                               https://www.mdpi.com/journal/materials
Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
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                                          It is necessary to examine the chemical composition of the alloy used to produce the
                                         It is
                                   bell to      necessary
                                            repair    the crack. to examine    thebells
                                                                      The oldest     chemical
                                                                                           are madecomposition
                                                                                                         of gunmetal,of the  alloy
                                                                                                                         while   theused    to produce
                                                                                                                                      younger    are made  the
                                  bell  to repair
                                   of bronze.        the crack.
                                                   Copper       at a The   oldest bellsofare
                                                                       concentration             made
                                                                                             about    80%of and
                                                                                                             gunmetal,
                                                                                                                  tin with while  the younger between
                                                                                                                              a concentration      are made
                                  of  bronze.     Copper        at  a concentration       of about    80%    and
                                   19% and 21% are the main components in both alloys. Gunmetal also contains zinc,tin with   a concentration      between
                                                                                                                                                       lead,
                                  19%    and    21%    are   the    main  components         in  both   alloys.   Gunmetal
                                   carbon, and iron. Trace amounts of silver and gold are also possible to observe in both      also  contains    zinc,  lead,
                                  carbon,     and    iron.     Trace    amounts      of  silver  and    gold   are  also  possible
                                   alloys because of the tradition to add these elements into the liquid metal to ennoble the         to  observe    in  both
                                  alloys
                                   material because
                                                [4–6]. of the tradition to add these elements into the liquid metal to ennoble the
                                  material     [4–6].
                                          The melting temperature of bronze is about 850–950 °C. The alloys with high tin con-
                                                                                                                        ◦ C. The alloys with high tin
                                   tent The      melting temperature
                                         are characterized            by great of    bronzebut
                                                                                 strength,      is about     850–950low
                                                                                                    concurrently            toughness—they are very
                                  content     are characterized
                                   brittle (Figure      1). This, in by     great strength,
                                                                         combination       withbuthigh concurrently     low toughness—they
                                                                                                         thermal expansion        and high diversityare very
                                                                                                                                                           of
                                  brittle   (Figure     1).   This,    in combination        with    high   thermal    expansion
                                   the microstructure component properties, has a negative influence on weldability. It is            and   high   diversity
                                  of  the microstructure
                                   proper     to heat the whole      component
                                                                          bell at theproperties,
                                                                                         adequatehas       a negative
                                                                                                       speed              influence
                                                                                                                until it reaches     theontemperature
                                                                                                                                            weldability.ofIt
                                  is350–450
                                     proper°C,   to heat
                                                     before welding. This allows differences in temperature between the weldedof
                                                            the    whole    bell  at the   adequate      speed   until  it reaches    the  temperature
                                  350–450      ◦ C, before welding. This allows differences in temperature between the welded
                                   place and the rest of the bell which are too large to be avoided. What’s more, it is also
                                  place    and the
                                   important            restitofslowly
                                                  to cool           the bell
                                                                           andwhich
                                                                                 evenly  are  toospeed
                                                                                           (the     largeoftothe
                                                                                                               becooling
                                                                                                                   avoided.     What’s
                                                                                                                             process       more,
                                                                                                                                       should    beitslower
                                                                                                                                                      is also
                                  important       to  cool    it  slowly   and   evenly    (the   speed    of the  cooling    process
                                   than heating). This is connected with the risk of inducing residual heat as a result of dif-         should    be  slower
                                  than    heating).
                                   ferences              This is rates
                                                in the cooling         connected     with parts
                                                                            of different     the risk     of structure
                                                                                                     of the  inducing(Figure
                                                                                                                          residual    heat
                                                                                                                                   2a,b      as adifferent
                                                                                                                                         shows     result of
                                  differences
                                   phases accordingin the cooling       rates ofcooling
                                                               to different       different    partsIfofthe
                                                                                            rates).       the bell
                                                                                                               structure   (Figure
                                                                                                                     had not    been2a,b   showsonly
                                                                                                                                        heated,     different
                                                                                                                                                          the
                                  phases
                                   welded part would have shrunk and new cracks would have appeared. On thewelded
                                             according      to   different   cooling    rates).  If the  bell  had  not  been   heated,   only  the    other
                                  part
                                   hand,would      have process
                                            a cooling      shrunk and       new
                                                                        which  iscracks
                                                                                   too fast would     have appeared.
                                                                                               may cause      new stresses,On the
                                                                                                                                withother
                                                                                                                                       newhand,
                                                                                                                                             cracksa cooling
                                                                                                                                                      as the
                                  process
                                   result.    which     is  too    fast may   cause    new    stresses,    with  new   cracks    as the  result.

                                  Figure
                                  Figure 1. Theinfluence
                                         1. The influenceofoftin
                                                               tinonon chosen
                                                                     chosen    mechanical
                                                                            mechanical     properties,
                                                                                       properties, the the   tin bronze
                                                                                                        tin bronze       hardness
                                                                                                                     hardness     change
                                                                                                                              change
                                  dependent on tin
                                  dependent     tin concentration.
                                                     concentration.(E—elongation,   UTS—ultimate
                                                                       (E—elongation,  UTS—ultimate  tensile strength,
                                                                                                         tensile        BHN—Brinell
                                                                                                                  strength, BHN—Brinell
                                  hardness number,
                                  hardness  number,KV—impact
                                                     KV—impact strength,
                                                                    strength, YS—yield
                                                                              YS—yield strength) [7].
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            2. (a) Phase
     Figure 2.     Phase diagram
                           diagram Cu-Sn,
                                      Cu-Sn, (b)
                                             (b) Metastable
                                                 Metastable phases
                                                            phases Cu-Sn;
                                                                   Cu-Sn; dashed
                                                                          dashed line—casting
                                                                                 line—casting solidified in sandy mold, dotted
     line—casting solidified
                    solidified in
                               in aa metal
                                     metal mold
                                           mold [8,9].
                                                 [8,9].

                                 2. Historical
                                    Historical Background
                                        In Poland,
                                        In  Poland,the    the  first
                                                            first     attempts
                                                                  attempts        to repair
                                                                             to repair  damaged damaged      bells
                                                                                                    bells were      were observed
                                                                                                                  observed    in the 1930s.in the  1930s.
                                                                                                                                                Welding
                                 Welding      and    soldering-welding          were  the   base  methods.     There
                                 and soldering-welding were the base methods. There is one difference between these two  is one   difference    between
                                 these two methods:
                                 methods:      connecting     connecting
                                                                 surfaces aresurfaces
                                                                                 melted areduring
                                                                                             melted welding
                                                                                                      during welding
                                                                                                                   processprocess
                                                                                                                             and only  andheated
                                                                                                                                            only heated
                                                                                                                                                     until
                                 untilmelting
                                 the     the melting      temperature
                                                    temperature            of the
                                                                      of the      material
                                                                               material        added
                                                                                           added    to to the
                                                                                                        the    connection(that
                                                                                                             connection        (thatisissolder)
                                                                                                                                         solder) during
                                 the soldering-welding process. Additionally, a welding rod with a chemical composition
                                 similar to
                                 similar    to indigenous
                                                indigenous metal metal was
                                                                         was used
                                                                               used during
                                                                                     during welding
                                                                                                welding process,
                                                                                                           process, whilst
                                                                                                                        whilst sticks
                                                                                                                                 sticks made
                                                                                                                                         made of of brass
                                                                                                                                                    brass
                                 alloy    (known      as  bronzite)    were   used  for   soldering-welding.
                                 alloy (known as bronzite) were used for soldering-welding.
                                        First, it
                                        First,   it was
                                                     wasdesirable
                                                           desirabletotoestimate
                                                                            estimate thethesize of the
                                                                                              size      crack.
                                                                                                   of the        A simple
                                                                                                            crack.   A simplepenetration
                                                                                                                                   penetrationstudy   was
                                                                                                                                                   study
                                 conducted        with   the  use   of chalk   and  kerosene.    Chalk    was   rubbed
                                 was conducted with the use of chalk and kerosene. Chalk was rubbed into the inner side    into  the  inner   side of  the
                                 bellthe
                                 of    and   theand
                                           bell     external   side was
                                                       the external        lubricated
                                                                         side             with kerosene.
                                                                               was lubricated                The greasy
                                                                                                   with kerosene.        Thespot
                                                                                                                              greasywasspotusedwas
                                                                                                                                                 to show
                                                                                                                                                     used
                                 the  range     of  the  crack.   After   estimating     the  size of  the  damage,      the
                                 to show the range of the crack. After estimating the size of the damage, the place of repairplace    of  repair  should
                                 be properly
                                 should             prepared.
                                            be properly            In bothIn
                                                               prepared.      cases,
                                                                                boththe     method
                                                                                       cases,         of action
                                                                                                the method      of was
                                                                                                                    actionsimilar.   A groove
                                                                                                                             was similar.          with a
                                                                                                                                               A groove
                                 v–shape     was     cut  along   the  crack   and  metal    was  poured    in.  In
                                 with a v–shape was cut along the crack and metal was poured in. In this procedure  this   procedure     the  hole  at the
                                                                                                                                                       the
                                 end   of  the   crack   must    be  remembered.      Its  task  was  to  limit  the   increase
                                 hole at the end of the crack must be remembered. Its task was to limit the increase of the       of the   crack  during
                                 bell heating.
                                 crack    duringAn   bellacetylene
                                                           heating. torch      was usedtorch
                                                                       An acetylene         as the welding
                                                                                                 was  used as tooltheinwelding
                                                                                                                         both methods.
                                                                                                                                   tool in Uniformity
                                                                                                                                             both meth-
                                 of the    weld    obtained     was   the  main   difference    between     welding
                                 ods. Uniformity of the weld obtained was the main difference between welding and the   and  the   soldering-welding
                                 process. The weld had nearly the same chemical composition as welded material during
                                 soldering-welding process. The weld had nearly the same chemical composition as
                                 the welding process. The weld had different chemical composition to the repaired bell
                                 welded material during the welding process. The weld had different chemical composi-
                                 during the soldering-welding process, which caused worse sound.
                                 tion to the repaired bell during the soldering-welding process, which caused worse sound.
                                        The position heated by charcoal (in the past it was often used as a fuel) was used
                                        The position heated by charcoal (in the past it was often used as a fuel) was used to
                                 to heat the bell before repair. This solution was connected with uneven bell heating and
                                 heat the bell before repair. This solution was connected with uneven bell heating and cool-
                                 cooling. It may have caused new cracks or increased the old ones as a result.
                                 ing. It may have caused new cracks or increased the old ones as a result.
Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
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                           3. Maryan Bell Crack Repairing
                                The company Rduch Bells & Clocks and Foundry Department collectively made a
                           decision to repair a cracked Maryan bell from the 17th century at the request of urban
                           restorer in Krosno–Marta Rymar. The bell hangs in a church tower. It is the smallest bell of
                           three cast in 1639, weighing 580 kg. It is characterized by producing a “G#” sound. The bell
                           was cast by two bell founders, Szepan Meutel and Jerzy Olivier, for a special order from
                           the great philanthropist Robert Wojciech Portius. The Maryan bell is one of three treated
                           bells. On the tower there are also the Urban bell and the Jan bell. The bells are tuned to a
                           major scale. This means that they sound happy, merry, and concurrently noble. The lack of
                           one bell or unclear sound will cause the whole set to lose its musical value. This is why it
                           was so important not only to repair the crack but to do it in such a way as to avoid changes
                           to the sound.
                                The most important task during welding process was to obtain the original sound.
                           Fortunately, in 2013, during the change of the clapper, acoustic measurements were con-
                           ducted. Thanks to this it was possible to obtain the sound before and after the damage
                           to the bell (the damage occurred in 2017—exact date is unknown). This was the base for
                           further activities. The work was divided into a few steps:
                           1.    The first step was to take a material sample to determine the averaged chemical
                                 composition of the alloy, which was analyzed with a glow–discharge spectrometer
                                 LECO GDS500A (LECO Corporation, St. Joseph, MI, USA, 2011) (Table 1);
                           2.    In the next step a series of welding rods with the same chemical composition were
                                 prepared on the basis of these results, which were used during bell welding process;
                           3.    The next step was to determine the size and range of the crack, and penetration
                                 research was conducted;
                           4.    The next step was preparing the bell for the welding process by properly bevelling
                                 the sides of the bell;
                           5.    The next step was heating and keeping the bell at the proper temperature;
                           6.    The next step was obtaining the required temperature to conduct welding process;
                           7.    After welding slow cooling was conducted to avoid stresses;
                           8.    The last step was analysis of the sound of the repaired bell.

                           Table 1. Chemical composition of the Maryan bell (wt. %).

                                Sn         Pb          Sb          Zn           Fe         Ni          Ag          Cu
                                15.2       2.84        2.69        0.35        0.03       0.41        0.15        bal.

                                 Accuracy in all of these activities allowed us to obtain the ideal sound from the repaired
                           bell. The samples of material obtained were examined with the use of a spectrometer to
                           determine averaged chemical composition (presented in Table 1). The analysis of structure
                           was also conducted with the use of a scanning microscope to determine the distribution and
                           size of solid and gaseous inclusions. (Figure 3a,b). The chemical composition in particular
                           places (with visible solid and gaseous inclusions) was presented in Table 2.
                                 Metallographic microsections showed the original structure of the bell. Unfortunately,
                           many gaseous (Figure 3a, 6) and non–metallic inclusions were observed. A large amount
                           of carbon (Figure 3b, 1) can indicate residue of charcoal, which was used as fuel during
                           the melting process. Zinc inclusions were also observed (Figure 3a, 5).This negatively
                           influenced the welding process.
                                 A series of welding rods were made after chemical composition determination and
                           consultations with the company conducting the welding process. Their composition was
                           selected to be as compatible as possible with the examined material of the bell. A set of
                           molds was worked out and prepared in the Foundry Department, and thanks to them
                           welding rods of different lengths and diameters were produced (Figure 4).
Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
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                             (a) 100 μm                                                           (b) 20 μm

         Figure
     Figure      3. Location
             3. Location      of the
                          of the     measurement
                                  measurement      points
                                                points for for scanning
                                                           scanning       microscope
                                                                       microscope    examination
                                                                                  examination  withwith  visible
                                                                                                     visible     impurities
                                                                                                             impurities andand inclusions.
                                                                                                                            inclusions.
         (a) 1–6
     (a) 1–6     measurement
             measurement          points
                             points      for magnification
                                     for magnification 530× 530×,
                                                             , (b) (b)
                                                                   1–31–3  measurement
                                                                       measurement      points
                                                                                     points for for magnification
                                                                                                magnification       800×.
                                                                                                                 800× .

                                     Table
                                  Table     2. Chemical
                                        2. Chemical     composition
                                                    composition     in particular
                                                                in particular     examined
                                                                              examined     places
                                                                                       places     presented
                                                                                              presented     in Figure
                                                                                                        in Figure 3. 3.

                                                          Figure
                                                       Figure 3a 3a                                              Figure
                                                                                                              Figure 3b 3b
                                                        Element
                                                      Element             Atomic
                                                                       Atomic                                Element
                                                                                                           Element             Atomic
                                                                                                                            Atomic
                                       Number
                                     Number                                           Number
                                                        Symbol        Concentration Number                      Symbol     Concentration
                                                      Symbol         Concentration                            Symbol      Concentration
                                                           Cu               21.43                                  C             75.57
                                                        Cu               21.43                                   C            75.57
                                                         C
                                                           C                70.37
                                                                         70.37                                  Zn
                                                                                                                   Zn            12.53
                                                                                                                              12.53
                                           1   1        SnSn                 1.77
                                                                          1.77        1 1                       CuCu              3.56
                                                                                                                               3.56
                                                         OO              6.446.44                                S S              5.12
                                                                                                                               5.12
                                                                                                                 OO            3.22
                                                                                                                                  3.22
                                                         CuCu                28.54
                                                                          28.54                                 CuCu             17.76
                                                                                                                              17.76
                                                         SnSn              6.34
                                                                              6.34                               C C          75.99
                                                                                                                                 75.99
                                           2   2                                              2    2
                                                         C                57.87                                  S             3.79
                                                           C                 57.87                                  S             3.79
                                                         O                7.25                                   O             2.47
                                                            O                7.25                                  O              2.47
                                                         Cu               24.57                                 Pb             9.95
                                                         C Cu                24.57
                                                                          64.84                                  C Pb             9.95
                                                                                                                              64.53
                                           3              S C                64.84
                                                                           6.57               3                 Cu C             64.53
                                                                                                                               7.85
                                               3         O S              3.846.57                 3             O Cu           177.85
                                                         Sb               0.19                                  Sn             0.68
                                                            O                 3.84                                 O               17
                                                         Cu               25.7
                                                            Sb                0.19                                 Sn             0.68
                                           4             C                63.68
                                                          S Cu                25.7
                                                                           7.44
                                               4         Zn C                63.68
                                                                          24.46
                                                         C S                  7.44
                                                                          57.29
                                           5              S Zn            13.12
                                                                             24.46
                                                         Cu               2.88
                                                            C                57.29
                                                         O                2.25
                                               5             S               13.12
                                                            Cu                2.88
                                                            O                 2.25
Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
during the melting process. Zinc inclusions were also observed (Figure 3a, 5).This nega-
                           during the melting process. Zinc inclusions were also observed (Figure 3a, 5).This nega-
                            tively influenced the welding process.
                           tively influenced the welding process.
                                 A series of welding rods were made after chemical composition determination and
                                A series of welding rods were made after chemical composition determination and
                            consultations with the company conducting the welding process. Their composition was
                           consultations with the company conducting the welding process. Their composition was
Materials 2021, 14, 2504    selected to be as compatible as possible with the examined material of the bell. A6set  of
                                                                                                                of 10
                           selected to be as compatible as possible with the examined material of the bell. A set  of
                            molds was worked out and prepared in the Foundry Department, and thanks to them
                           molds was worked out and prepared in the Foundry Department, and thanks to them
                            welding rods of different lengths and diameters were produced (Figure 4).
                           welding rods of different lengths and diameters were produced (Figure 4).

                            Figure4.4.Welding
                                      Welding rodsofof different lengths and diameters  (the length  of rods was 40 the
                                                                                                                    cm;diameters
                                                                                                                         the diam-
                           Figure
                           Figure  4. Welding rods
                                              rods ofdifferent
                                                      differentlengths
                                                                lengthsand
                                                                        anddiameters
                                                                            diameters(the length
                                                                                       (the      of of
                                                                                            length  rods was
                                                                                                       rods  40 cm;
                                                                                                            was 40 cm;  the diam-
                            eters were 8 mm and 6 mm).
                           were were
                           eters 8 mm8and
                                        mm6and
                                             mm).6 mm).
                                 Thesize
                                The    sizeand
                                            andrange
                                                rangeofofthe
                                                          thecrack
                                                              crackwere
                                                                      were examinedwith
                                                                                      with theuse
                                                                                               use ofpenetration
                                                                                                       penetration testing
                                The  size and  range of  the crack   were examined
                                                                            examined with the
                                                                                          the use of
                                                                                                   of penetration testing
                                                                                                                   testing
                            (Figure 5).
                           (Figure 5).   Penetrator
                                   5). Penetrator   was
                                        Penetrator was   used
                                                   was used   for
                                                        used for   this
                                                             for this   examination
                                                                  this examination  by
                                                                       examination by  covering
                                                                                   by covering  the
                                                                                      covering the  crack
                                                                                               the crack  andfilm,
                                                                                                   crack and
                                                                                                         and   film,which
                                                                                                                     which
                           (Figure                                                                           film, which
                            helped
                           helped toto  determine
                                   to determine
                                      determine thethe range
                                                  the range  of
                                                      range of   the
                                                            of the    crack.
                                                               the crack.
                                                                     crack.
                           helped

                                               Figure 5. Penetration testing.
                                              Figure 5. Penetration
                                              Figure 5. Penetration testing.
                                                                    testing.

                                After crack range determination, mechanical treatment of the damaged place was
                           conducted to remove the external oxidized surface (Figure 5). This phase was performed
                           in such way to obtain the best access to whole crack by the welder during the welding
                           process (Figure 6). It was found during mechanical treatment that the bell’s structure is
                           very porous, especially the external surface. This worsened the welding process. The
                           welding process was conducted with the use of an oxyacetylene torch. During this process
                           the bell edges were melted with the welding rods made earlier. Welding was conducted
                           with the use of the “up method”. Better efficiency of welding and very good penetration of
                           the whole thickness of the connected parts were obtained thanks to this method. It was
                           possible to perform the weld with a single torch cut due to this method.
Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
in such way to obtain   the best
                                                      conducted         access to
                                                                    to remove     whole
                                                                                the        crack
                                                                                     external     by the surface
                                                                                               oxidized   welder (Figure
                                                                                                                   during 5).
                                                                                                                            theThis
                                                                                                                                welding
                                                                                                                                     phase was performed
                                    process (Figure 6). It was    found  during   mechanical    treatment   that the  bell’s structure
                                                      in such way to obtain the best access to whole crack by the welder during        is    the welding
                                    very porous, especially     the  external  surface.  This   worsened    the welding    process.  The
                                                      process (Figure 6). It was found during mechanical treatment that the bell’s structure is
                                    welding process was
                                                      veryconducted     with the use
                                                            porous, especially      theofexternal
                                                                                          an oxyacetylene
                                                                                                   surface. torch.  During thisthe
                                                                                                              This worsened       process
                                                                                                                                     welding process. The
                                    the bell edges were  melted    with  the welding    rods  made   earlier. Welding    was  conducted
                                                      welding process was conducted with the use of an oxyacetylene torch. During this process
Materials 2021, 14, 2504            with the use of the “up                                                                                  7 of 10
                                                      the  bellmethod”.   Better
                                                                 edges were      efficiency
                                                                              melted          of welding
                                                                                       with the   weldingandrodsvery
                                                                                                                  madegood   penetration
                                                                                                                         earlier. Welding was conducted
                                    of the whole thickness  of the
                                                      with the    useconnected
                                                                      of the “upparts   were obtained
                                                                                  method”.               thanks to
                                                                                               Better efficiency  ofthis method.
                                                                                                                     welding   andItvery
                                                                                                                                     was good penetration
                                    possible to perform  the weld    with  a single  torch cut  due to this  method.
                                                      of the whole thickness of the connected parts were obtained thanks to this method. It was
                                                         possible to perform the weld with a single torch cut due to this method.

                                    Figure 6. Mechanical treatment of the damaged place.
                                      Figure 6. Mechanical treatment of the damaged place.
                                                         Figure 6. Mechanical treatment of the damaged place.
                                         It It
                                            was   important
                                                was          to heat
                                                     important      toand
                                                                        heatkeep
                                                                               andthekeep
                                                                                      bell atthe
                                                                                              the bell
                                                                                                  properat temperature
                                                                                                            the proper during       the weld-
                                                                                                                            temperature         during the
                                    ing process. This temperature
                                                              It was      was  obtained
                                                                      important to   heat by  using
                                                                                           and keep   heating   mats    and  aluminosilicate
                                      welding process. This       temperature      was  obtained     bythe bell at
                                                                                                         using      the proper
                                                                                                                 heating    matstemperature      during the weld-
                                                                                                                                   and aluminosilicate
                                    fiber isolation. The   whole   process oftemperature
                                                                                heating waswas under    the control    of and recorded      byand
                                                                                                                                                a aluminosilicate
                                      fiber isolation.ing Theprocess.
                                                                wholeThis process of heating       obtained
                                                                                                   was   under bytheusing   heating
                                                                                                                         control   of mats
                                                                                                                                      and recorded       by
                                    computer program       (Figure
                                                        fiber        7);theThe
                                                               isolation.   heating
                                                                                wholerate was ~10
                                                                                       process    of °C/h.
                                                                                                     heatingThe
                                                                                                              wastime   of cooling
                                                                                                                     under   the    after per-
                                                                                                                                  control    of
                                      a computer
                                    forming          program
                                               the weld was longer(Figure
                                                                       than 7);the   heating
                                                                             the(Figure
                                                                                 heating  time,rate
                                                                                                 and was
                                                                                                                  ◦
                                                                                                            ~10 C/h.
                                                                                                      the rate
                                                                                                          cooling           The~7time        cooling after by a
                                                                                                                                         ofThus and recorded
                                                        computer     program             7);the  heating       wasrate~10was
                                                                                                                           °C/h.   °C/h.
                                                                                                                                 The   time   of cooling after per-
                                      performing
                                    slow            theconducted
                                          cooling was     weld was longer        than the which
                                                                                             heating time,    and     the cooling
                                                                                                                                bellrate     was  ~7 ◦ C/h.
                                                        forming theto     avoid
                                                                        weld  wasstresses,
                                                                                   longer than thecould     have
                                                                                                      heating      caused
                                                                                                               time,        the cooling
                                                                                                                       and the        to crack
                                                                                                                                           rate was ~7 °C/h. Thus
                                      Thus slow cooling was conducted to avoid stresses, which could have caused the bell to
                                    again.              slow cooling was conducted to avoid stresses, which could have caused the bell to crack
                                      crack again.       again.

                                                                        A
                                                                                            A

                                                                                              B
                                                                                                                   B

                                       (a)                                                   (b)
                                                          (a)fibro isolation; red circle–the place of welding (b) (b)
        Figure 7. Welding process (a) the bell protected by                                                        close–up of the place
        of welding. A—acetylene torch, B—bronze rod.
                           Figure 7. Welding
                                     Figure 7.process  (a) the
                                                 Welding        bell protected
                                                            process            by fibro
                                                                       (a) the bell     isolation;
                                                                                    protected   byred  circle–the
                                                                                                    fibro         placered
                                                                                                           isolation;   of welding (b) close–up
                                                                                                                           circle–the  place of of the place
                                                                                                                                                welding
                           of welding. A—acetylene torch, B—bronze rod.
                                     (b) close–up
                                         After the of the place
                                                   cooling      of welding.
                                                            process,        A—acetylene
                                                                     the place            torch,
                                                                               of welding was    B—bronze
                                                                                              ground      rod.8) and the sound
                                                                                                     (Figure
                                    of bell was examined. After the cooling process, the place of welding was ground (Figure 8) and the sound
     Materials 2021, 14, x FOR PEER REVIEW After the cooling process, the place of welding was ground (Figure 8) and
                                                                                                                  8 of the
                                                                                                                       10 sound
                                                     of bell was examined.
                                      of bell was examined.

                                       Figure 8.
                                      Figure  8. Welded
                                                 Weldedbell
                                                        bellattached
                                                             attachedto to
                                                                        thethe
                                                                            tower.
                                                                               tower.

                                       4. Sound Analysis of the Bell
                                            In 2013, before the crack, the bell’s sound was analyzed. After welding and the ther-
                                       mal stabilization process, this analysis was repeated. The sound of the bell, a G#4 note,
                                       did not worsen or even improve as a result of the negligible reduction of the main aliquots
Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
Materials 2021, 14, 2504                                                                                                     8 of 10

                                     4. Sound Analysis of the Bell
                                        In 2013, before the crack, the bell’s sound was analyzed. After welding and the
                                   thermal stabilization process, this analysis was repeated. The sound of the bell, a G#4
                                   note, did not worsen or even improve as a result of the negligible reduction of the main
                                   aliquots frequency.
                                        The target frequencies for the first partials are in the ratios 0.5:1.0:1.2:1.5:2.0 and these
                                   needed to be quite closely matched. The first aliquot, called the hum, is not prominent,
                                   and the perceived pitch is usually that of the second aliquot, called the prime, perhaps
                                   because it is reinforced by the harmonically-related aliquots with relative frequencies 2, 3,
                                   and 4. The tone of the bell is complex, however, particularly because of the presence of the
                                   minor-third (From Old French tierce, from Latin tertia) interval of 1.2 [10].
                                        The lower (tone lower than the prime about the octave) and upper (tone higher
                                   than the prime about the octave) octaves with prime, tierce and quint were found to be
                                   beautifully harmonious after the repair. There was no distortionary vibration and the bell
                                   sustained its note for a long time.
                                        The frequency spectrums of the Maryan bell before and after the crack are presented
                                   in Figure 9. The units of the amplitude in the figure are arbitrary; they are measured as
                                   voltages from a microphone, i.e., sound pressure levels on a linear scale. The amplitude
                                   of the spectrum is described in decibel scale. The program Wavanal [11] was used to
                                   analyze the sound of bell examined to determine the spectrum of emitted sound waves.
                                   This program was developed by W. A. Hibbert [12] for the sound analysis of bells to
                                   determine the influence of side tones on the height of the perceived strike tone (pitch tone).
                                   The possibility of fast and precise determination of their frequency was crucial, and the
                                   Wavanal program enabled it. This program allows a Fourier transform of sound waves
                                   directly recorded by a microphone joined to a computer or saved in a sound file recorded
                                   with other devices to be performed (Figure 10a,b). This program has received recognition
                                   among many bell makers as a great device for the evaluation of a bell’s sound and the
                                   process of tuning it up.
Materials 2021, 14, x FOR PEER REVIEW Determined by the Wavanal program, values of frequency of basic side tones (aliquots):                9
                                   the lower octave (hum), prime (fundamental), minor tierce, quint, and upper octave
                                   (nominal) of the bells examined are presented in Table 3 and as a diagram in Figure 11.

                                     Figure 9. The spectrum of the St. Maryan bell’s sound, before (BW) and after (AW) welding.
                                    Figure 9. The spectrum of the St. Maryan bell’s sound, before (BW) and after (AW) welding.
Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
Materials 2021, 14, 2504                                                                                                          9 of 10

                                  Figure 9. The spectrum of the St. Maryan bell’s sound, before (BW) and after (AW) welding.

                                (a)                                                           (b)
             10. The
      Figure 10. Theanalysis
                     analysisofof sound
                                sound   wave
                                      wave   emitted
                                           emitted     by C3
                                                   by bell bellinC3 in program
                                                                  program       Wavanal;
                                                                           Wavanal;         (a) theofshape
                                                                                    (a) the shape           of recorded
                                                                                                      recorded  wave, (b) wave,  (b) its
                                                                                                                          its spectrum.
      spectrum.
                                  Table 3. Main partials of the St. Maryan bell’s sound frequencies before and after welding in
                                       Determined
                                  comparison         by the
                                             to harmonic       Wavanal
                                                           tones           program,
                                                                   for the musical notevalues
                                                                                        G#4. of frequency of basic side tones (ali-
                                  quots): the lower octave (hum), prime (fundamental), minor tierce, quint, and upper oc-
                                        Partials Tone
                                  tave (nominal)                   BW (Hz)
                                                   of the bells examined                  AW (Hz)
                                                                         are presented in Table                G#4 (Hz)
                                                                                                3 and as a diagram      (ET) 11.
                                                                                                                   in Figure
                                            Hum                      212.5                    208.5                   207.6
                                  Table 3. Main
                                           Primepartials of the St. Maryan
                                                                      422  bell’s sound frequencies
                                                                                               413  before and after welding
                                                                                                                      415.3 in com-
                                  parison to harmonic tones for the musical note G#4.
                                           Tierce                     512                     502.5                   493.8
                                        Partials
                                            QuintTone              BW635
                                                                      (Hz)                   AW619
                                                                                                 (Hz)              G#4 622.3
                                                                                                                       (Hz) (ET)
Materials 2021, 14, x FOR PEER REVIEW
                                            Hum                     212.5                     208.5                    207.6 10 of 10
                                          Nominal                   853.5                      836                     830.6
                                            Prime                    422                       413                     415.3
                                           Tierce                    512                      502.5                    493.8
                                            Quint                    635                       619                     622.3
                                          Nominal                   853.5                      836                     830.6

                                  Figure11.
                                 Figure      Themain
                                         11.The   main partials
                                                     partials of of
                                                                 thethe
                                                                      St.St. Maryan
                                                                          Maryan     bell’s
                                                                                 bell’s     sound
                                                                                        sound      frequencies,
                                                                                               frequencies,     before
                                                                                                            before (BW),(BW),
                                                                                                                          afterafter
                                                                                                                                (AW) (AW)
                                  welding and  for musical note G#4   according to the  equal temperament   scale
                                 welding and for musical note G#4 according to the equal temperament scale (ET).  (ET).

                                 5.5.Conclusions
                                      Conclusions
                                        Basedon
                                       Based   onthe
                                                   the experience
                                                     experience   gained
                                                                gained    during
                                                                       during the the
                                                                                  workwork
                                                                                       and and  research
                                                                                           research      carried
                                                                                                    carried out onout
                                                                                                                   theon the
                                                                                                                       Mar-
                                  Maryan   bell, the following conclusions can be
                                 yan bell, the following conclusions can be drawn:drawn:
                                  1.  If the welding process is carried out with the correct parameters, especially with
                                 1. If the welding process is carried out with the correct parameters, especially with ther-
                                      thermal ones, and with monitoring and control of the heating and cooling rates, the
                                     mal ones, and with monitoring and control of the heating and cooling rates, the repair
                                      repair even of contaminated high tin bronze bells is possible;
                                     even of contaminated high tin bronze bells is possible;
                                  2.  After repair by welding, the bell has a “better” sound, and this is probably due to
                                 2. After repair by welding, the bell has a “better” sound, and this is probably due to a
                                      a kind of heat treatment performed, including a cycle of slow heating and cooling
                                     kind of heat treatment performed, including a cycle of slow heating and cooling
                                      which improves the properties of the material; and
                                     which improves the properties of the material; and
                                  3.  The most highly recommended technique for repairing bells is gas welding, due to
                                 3. The most highly recommended technique for repairing bells is gas welding, due to
                                      the relatively low temperature in the bonding area and the efficiency of the process.
                                     the relatively low temperature in the bonding area and the efficiency of the process.

                                 Author Contributions: Conceptualization, methodology, software, formal analysis, writing—re-
                                 view and editing, D.B.; conceptualization, methodology, investigation, writing—original draft prep-
                                 aration, C.B. Both authors have read and agreed to the published version of the manuscript.

                                 Funding: This research received no external funding
Repair of a Cracked Historic Maryan Bell by Gas Welding - MDPI
Materials 2021, 14, 2504                                                                                                        10 of 10

                                  Author Contributions: Conceptualization, methodology, software, formal analysis, writing—review
                                  and editing, D.B.; conceptualization, methodology, investigation, writing—original draft preparation,
                                  C.B. Both authors have read and agreed to the published version of the manuscript.
                                  Funding: This research received no external funding.
                                  Institutional Review Board Statement: Not applicable.
                                  Informed Consent Statement: Not applicable.
                                  Data Availability Statement: The data presented in this study are available in article.
                                  Acknowledgments: The authors would like to acknowledge to Rduch Bells and Clocks and Jan
                                  Felczynski’s Bell Foundry for materials and technical support.
                                  Conflicts of Interest: The authors declare no conflict of interest.

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      20, 22–27. [CrossRef]
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                                                                   ˛ Katowice, Poland, 1967.
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11.   Available online: http://www.hibberts.co.uk (accessed on 5 October 2020).
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      Keynes, Milton Keynes, UK, 2008, in press.
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