Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines

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Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
Detection of weak transitions
      in forests of lines

             Cécile Favre
           (IPAG, Grenoble)

      Atelier « Spectro Bordeaux » – June 23, 2015   1
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
Simple & Complex molecules
  in the interstellar and circumstellar media

                            More than 180 molecules detected,
                             including ~63 complex species

                    Complex molecule: 6 or more atoms

http://www.astro.uni-koeln.de/cdms/molecules                    2
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
But …

             Many relatively weak
                    lines!

                            Tercero et al. (2010)
                            2 mm molecular survey of Orion-KL
Weeds & confusion           (IRAM-30m)                     3
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
But …

                                     Tercero et al. (2010)
                                     2 mm molecular survey of Orion-KL
                                     (IRAM-30m)

 ²   Many lines (most peaks are real lines)

 ²   Many unidentified (here ~31%)

 ²   Many with a low intensity

       such molecules have relatively low abundance
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
Outline

v   Why looking for weak transitions/low abundance species?

v   Observations: single-dish & Interferometric
                                                   ALMA
       - High spectral resolution
       - High angular resolution
       - High sensitivity observations

v   Interpretation and analysis of the data
       - Spectroscopy (laboratory measurements)
       - Modeling
       - Survey (e.g. Herschel/HEXOS) along with modeling

                                                               5
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
Low abundance complex organic molecules

                               Whether, how, when and where
                               complex organic molecules are
                                         formed?

                                 Involved physico-chemical
                                         processes?
                     © NRAO

       Observations (single-dish & interferometry)
Ø Physical conditions (temperature, density & structure)
Ø Formation mechanisms of molecules: grain mantle versus gas
   phase controversy
Ø Prebiotic molecules

                                                                6
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
Outline

v   Why looking for weak transitions/low abundance species?

v   Observations: single-dish & Interferometric
                                                   ALMA
       - High spectral resolution
       - High angular resolution
       - High sensitivity observations

v   Interpretation and analysis of the data
       - Spectroscopy (laboratory measurements)
       - Modeling
       - Survey (e.g. Herschel/HEXOS) along with modeling

                                                               7
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
Spectral Resolution        Frequency    Beam       Spectral Resolution
                             (MHz)

      (’’X’’)

    (MHz)      (km.s-1)

                            101414

     3.8 X 2.0

    0.625         1.85

                            225855

     3.6 X 2.3

    0.313         0.42

                                                 Δv = 1.1 km/s
           Δv = 3.6 km/s

                                                                                  8
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
Angular Resolution                         T

                                                        Ethylene glycol

                                                                                                             SO2
                                                                          Formamide
                                            30m

                                                                                      IRAM-30m
                                                                                        (11’’)

       PdBI                30m beam

                                                                               Fréquence (MHz)
       beam

                                                  T                                                   PdBI

                                                      Ethylene glycol

                                                                            Formamide
                                                                                          (2.52’’ x 1.64’’)

                                                                                                             SO2
                 Ethylene glycol

                                                                                          U-line

             Brouillet et al. (2015)

PdBI                                                                           Fréquence (MHz)                     9
Cécile Favre (IPAG, Grenoble) - Detection of weak transitions in forests of lines
High Sensitivity for faint lines!
                                        Jørgensen, Favre et al. (2012)
     IRAS 16293-2422
Low-mass star forming-region
                                 ALMA observations (2.5’’ x 1.0’’)

       Rms (13 mJy/beam)
       Methyle formate HCOOCH3
                                         Glycolaldehyde CH2OHCHO
                                      First detection in a solar-type protostar! 10
High Sensitivity for faint lines!

     IRAS 16293-2422
                                     Cycle 2 data (Band 7)
Low-mass star forming-region
                               Portion of survey - ACA observations
                                       (PHILS collaborations)

                           RMS < 100 mJy
                                                                  11
Outline

v   Why looking for weak transitions/low abundance species?

v   Observations: single-dish & Interferometric
                                                   ALMA
       - High spectral resolution
       - High angular resolution
       - High sensitivity observations

v   Interpretation and analysis of the data
       - Spectroscopy (laboratory measurements)
       - Modeling
       - Survey (e.g. Herschel/HEXOS) along with modeling

                                                               12
Spectroscopic Characterization
                 Accurate abundance ratios / Line identification
Ø            Intensity calculation at different temperature
Ø            Spectroscopic determination of transition frequencies,
              assignments & line strengths
Ø            Complete partition function

                                                                 G29.96
                                                            Beuther et al. (2009)
     T (Jy)

                                 Rest Frequency [Mhz]                          13
Spectroscopy & Modeling
        Accurate abundance ratios / Line identification
Ø   Intensity calculation at different temperature
Ø   Spectroscopic determination of transition frequencies,
     assignments & line strengths
Ø   Complete partition function

 Databases:   v   CDMS (Cologne Database for Molecular Spectroscopy)
              v   JPL (Jet Propulsion Laboratory)
              v   Splatalogue
     Spectroscopic journals & Collaboration with spectroscopists

        Goal: characterize the physical parameters for each
      species (Trot, Ncol, Δv, vLSR, θ) and spectral component

      Line Analysis software:       v   XCLASS (Schilke et al. 2001)
                                    v   CASSIS (Caux et al. 2011)
                                    v   WEEDS (Maret et al. 2011)
                                                                        14
XCLASS Modeling of 12C- and 13C-HCOOCH3
                                ALMA-SV observations of Orion-KL
                                         (1.7” x 1.1”)
           HC                                                                Favre et al. (2014a)
156 transitions        CR
                      167 transitions

          HCOOCH3

           HC
73 transitions         CR
                      135 transitions
          H13COOCH3

            HC

67 transitions         CR
                      122 transitions   In collaboration with Isabelle Kleiner and Miguel Carvajal
         HCOO13CH3

                                                                                                 15
XCLASS Modeling of 12C- and 13C-HCOOCH3
HCOOCH3                       Favre et al. (2014a)

                                               16
XCLASS Modeling of 12C- and 13C-HCOOCH3
H13COOCH3                     Favre et al. (2014a)

                                               17
XCLASS Modeling of 12C- and 13C-HCOOCH3
HCOO13CH3                     Favre et al. (2014a)

                                               18
Tmb (K)     Herschel/HEXOS survey of Orion-KL

                     Frequency (GHz)

T. Bergin
Survey(s)

Herschel            Herschel/HIFI/HEXOS fit template model spectra
                      for each emissive molecule in Orion-KL scan
                                                     Crockett et al. (2014)

           ©: ESA

                                v ~13,000 features have been identified
                                     - 79 molecules (including isotopologues)
                                     - 12% of U-line

                                Ø   Line identifications
                                Ø   Where the potential blend may exist
                                                                                20
Summary
        Weak transitions/low abundance (complex) molecules,
       including those of prebiotic interest, are detected toward
            low-mass and high-mass star-forming regions

But ...
- Forests of lines
- still U-lines

  ²   Need homogeneous datasets (large bandwidth, same resolution)
  ²   High angular and spectral resolution
  ²   Accurate laboratory spectroscopic measurements
  ²   Merge the legacy of Herschel with future observations
  ²   High sensitivity: Detection / Search for new molecules / Physical and
       Chemical processes
  ²   ALMA/NOEMA/IRAM-30m …
           More complex spectra!
   So much line signal that it is challenging
      to define where the continuum is.
                                                                          21
Thank you
for your attention

                     22
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