NICKELM Critical nickel: providing sustainable solutions - Nickel Institute

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NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
NICKEL

                                                                           MAGAZINE
                 T HE M AG A ZINE DE VOT ED TO NICK EL A ND I T S A PPLIC ATIONS

                                    NICKEL, VOL. 36, Nº 2, 2021

                  Critical nickel:
          providing sustainable solutions
Carbon capture                      Clean energy                                      Wind power in
 and storage                  What role does nickel play?                               the Arctic
NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
EDITORIAL:
                                                                                                                                                                                                                                                       SUSTAINABLE SOLUTIONS

                                                                                                                                                                                                                                                       “Secure global net-zero by mid-century and keep 1.5 degrees within reach”

                                                                                                                                                    SOURCE: IEA(2021)THE ROLE OF CRITICAL MINERALS IN CLEAN ENERGY TRANSITIONS. ALL RIGHTS RESERVED.
                                                                                                                                                                                                                                                       is the call of the November 2021 COP26 climate change summit in Glasgow.
                                                                                                                                                                                                                                                       Government policy changes, investment dynamics and consumer choices are
                                                                                                                                                                                                                                                       increasingly driving a major overhaul in the energy systems and technologies
                                                                                                                                                                                                                                                       that power the world.
                                                                                                                                                                                                                                                                                                                While energy demand from oil, gas

                                                                  CASE STUDY 22                                                                                                                                                                                Change in energy demand by type
KWANSOO E&C CO. LTD

                                                                                                                                                                                                                                                                   in 2020 relative to 2019                     and coal fell by 5% during 2020
                                                                                                                                                                                                                                                                                                                compared with 2019, the energy

                                                                  TEMBURONG BRIDGE                                                                                                                                                                     5%
                                                                                                                                                                                                                                                                                                                demand from new energy systems,
                                                                                                                                                                                                                                                                                                                such as renewables remained
                                                                                                                                                                                                                                                                                                                                                     “Stronger actions are required to counter
                                                                                                                                                                                                                                                                                                                                                     the upward pressure on emissions from
                                                                                                                                                                                                                                                        0                                                                                            mineral production, but the climate
                                                                                                                                                                                                                                                                                                                resilient. Considering 2020 was a
                                                                                                                                                                                                                                                                                                                                                     advantages of clean energy technologies
                                                                  At 30 km (19 miles) in length, the Temburong Bridge is one of the longest                                                                                                                                                                     year when most economic sectors      remain clear.”
                                                                  over-sea bridges in south east Asia and is the largest infrastructure project                                                                                                        -5%                                                      showed no growth or contraction      — The Role of Critical Minerals in Clean
                                                                  ever undertaken by the Government of Brunei.The bridge spans a part of
                                                                                                                                                                                                                                                                                                                due to the Covid19 pandemic, a       Energy Transitions International Energy
                                                                  Brunei Bay and connects the Brunei-Muara District with the Labu Forest                                                                                                                                                                                                             Agency
                                                                                                                                                                                                                                                       -10%                                                     1% growth in the renewables sector
                                                                  Reserve on the eastern shore. Before the bridge was opened in March 2020,                                                                                                                   Total   Oil   Coal   Gas   Nuclear     Modern

                                                                  vehicles were forced to drive through a part of Sarawak, Malaysia when
                                                                                                                                                                                                                                                                                                   Renewables   paints a positive outlook.
                                                                  traveling between these two districts.The bridge has reduced travel time                                                                                                             Despite needing energy to produce, nickel is one of the minerals that plays a
                                                                  from two hours to about 40 minutes.The Sultanate of Brunei foresees that                                                                                                             critical enabling role in the energy transition required to reduce CO2 emissions.
                         Opened in March 2020, the                this massive US$1.6 billion project will lead to an increase in tourism to the                                                                                                       Its unique properties facilitate the successful deployment of the spectrum of
                         Temburong Bridge in Brunei               beautiful Labu Forest Reserve.
                                                                                                                                                                                                                                                       clean energy technologies such as geothermal, batteries for EVs and energy
                         Darussalam spans part of Brunei          Construction of the bridge, which        box-girder structures. In order to                                                                                                          storage, hydrogen, wind, concentrating solar power and nuclear. And as

                                                                                                                                                                                                                                                                                                                                                                                                      PHOTO BY JUSTIN BULOTA, © TUGLIK ENERGY
                         Bay. It consists of massive viaducts     started in 2014, was carried out by      greatly extend service life in this                                                                                                         nickel-enabled greener energy becomes more available, the carbon footprint
                         and two cable-stayed navigation          the Daelim-Swee Joint Venture of         tropical marine environment, the
                         bridges. Stainless steel rebar was                                                                                                                                                                                            of nickel production is also being reduced.
                                                                  South Korea and the China State          use of stainless steel reinforcing bar
                         selected for critical parts of the       Construction & Engineering Corp.         (rebar) was specified for critical                                                                                                          In this edition of Nickel we take a close look at exactly where nickel is and its
                         reinforced concrete structures.          Their formidable task involved the       parts of the reinforced concrete                                                                                                            critical role in four of the technologies which will be part of the mix of solu-
                         Strong and corrosion-resistant           construction of a 12 km (7.5 miles)      structures. This requirement led to                                                                                                         tions for decarbonisation.
                         stainless steel rebar is now in wide     land viaduct to traverse the man-        the selection of a reported total of
                         use to extend the service lifetimes of                                                                                                                                                                                        Often a little nickel goes a long way in emissions-reducing technologies,
                                                                  grove swamps of the Labu Forest          approximately 3,500 tons of stainless                                                                                                                                                                                                     Cover: One of two wind turbines at the
                         important concrete structures like                                                                                                                                                                                            helping provide sustainable solutions to help us get to net-zero.
                                                                  Reserve, a long marine viaduct           steel rebar, including rebar made                                                                                                                                                                                                         Glencore Raglan Mine with the Northern
                         bridges, which must endure harsh         and two navigation bridges. These        from Type 304 (UNS S30400) and                                                                                                              Clare Richardson                                                                              Lights (Aurora Borealis).
                         environments.                            spectacular bridges are cable-stayed,    Type 2304 (S32304).                                                                                                                         Editor, Nickel

                      22 || NICKEL,
                            NICKEL, VOL.
                                    VOL. 36,
                                         36, Nº
                                             Nº 2,
                                                2, 2021
                                                   2021                                                                                                                                                                                                                                                                                                             NICKEL, VOL. 36, Nº 2, 2021 | 3
NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
NICKEL
                                                                                                                                                                                                                               A surprising tail

                                                                                                                                             NOTABLES
  CONTENTS                                                                                                                                                                                                                     While it’s not unusual to find various metals in the dust tails of comets,
                                                                                                                                                                                                                               nickel and iron have now been found in cold comets far from the Sun.
   02     Case study no. 22                                                                                                                                                                                                    What’s unusual about this? Solid metals don’t normally ‘sublimate’
                                                                                                                                                                                                                               (become gaseous) in cold temperatures. Polish astronomers first identified
          Temburong Bridge
                                                                                                                                                                                                                               nickel vapour in the tail of the icy interstellar comet 2I/Borisov in 2019.
   03     Editorial                                                                                                                                                                                                            Now Belgian astronomers J. Manfroid, D. Hutsemékers and E. Jehin have
                                                                                                                                                                                                                               identified similar gaseous nickel in cold solar system comets, suggesting a
          Sustainable solutions
                                                                                                                                                                                                                               possible organometallic origin. These vapours have been detected in comets
  04      Nickel notables
                                                                                                                                                                                                                               more than 480 million kilometres from the Sun, triple the Earth-Sun distance.

   06     Wind and water

          Nickel in clean energy

                                                                                                                                                                                                                                                                                                                                                                BALLYMORE PROPERTIES LIMITED
   10     The Northern Lights project

                                                                                                                                                                                                        WIKIMEDIA COMMONS
          Carbon capture and storage

   13     Nickel alloys
                                                                    A clearer solution
          ‘C’ Family of alloys
                                                                                                                                                                                                                                                                                                               Dive in

                                                                                                                                                        JOONDONG KIM FROM INCHEON NATIONAL UNIVERSITY

                                                                                                                                                                                                        SMARTTIRECOMPANY.COM
   14     Technical Q&A
                                                                                                                                                                                                                                                                                                               Architecture studio HAL has
          Tea staining                                                                                                                                                                                                                                                                                         created a ten-storey (35 metre)
                                                                                                                                                                                                                                                                                                               high transparent swimming
   15     New publications
                                                                                                                                                                                                                                                                                                               pool that also acts as a bridge
                                                                                                                                                                                                                                                                                                               between two buildings at the
   15     UNS details
                                                                                                                                                                                                                                                                                                               Embassy Gardens development in
                                                                                                                                                                                                                                                                                                               Battersea, London. Named Sky
   16     King Abdulaziz Center
                                                                                                                                                                                                                                                                                                               Pool, the 25 metre-long swimming
          World culture                                                                                                                                                                                                                                                                                        pool is made from acrylic panels,
                                                                                                                                                                                                                                                                                                               allowing swimmers to enjoy sweeping
                                                                                                                                                                                                                                                                                                               views of the neighbourhood,
  Nickel magazine is published by Nickel Institute
                                                                                                                                                                                                                                                                                                               including the Thames.

                                                                                                                                                                                                                               Mars to Earth
  www.nickelinstitute.org

  Dr. Hudson Bates, President
                                                                                                                                                                                                                                                                                                               Type 316L (UNS S31603) stainless
  Clare Richardson, Editor                                          It’s a brilliant idea with a bright future. Glass with invisible solar panels                                                                                                                                                              steel tubs anchor the pool to
  communications@nickelinstitute.org                                that generate electricity. In a recent study published in the Journal of                                                                                   The Smart Tire Company, Los Angeles, California, is set to introduce Shape      each building. The tubs are
  Contributors: Parul Chhabra, Gary Coates, Richard Matheson,       Power Sources, Professor Joondong Kim and his colleagues at Incheon                                                                                                                                                                        supported on bridge bearings
  Geir Moe, Kim Oakes, Frank Smith, Benoît Van Hecke,
                                                                                                                                                                                                                               Memory Alloy Radial Technology (SMART) for bicycles. This revolutionary
                                                                    National University, Korea, detailed their latest invention: fully transpar-                                                                                                                                                               allowing the structure to respond
  Odette Ziezold                                                                                                                                                                                                               new technology has evolved from shape memory alloy tires developed for
                                                                    ent solar cells that can be integrated into windows, buildings, or even                                                                                                                                                                    to the buildings’ movement
  Design: Constructive Communications                                                                                                                                                                                          the next generation of Mars rovers and other Space Exploration Vehicles.
                                                                    mobile phone screens. Abundant and easily manufactured nickel oxide is                                                                                                                                                                     and support the weight of the
  Material has been prepared for the general information of                                                                                                                                                                    These tires incorporate the advanced material, advanced nickel-titanium
  the reader and should not be used or relied upon for specific     playing a pivotal role.                                                                                                                                                                                                                    water. Two 38 mm diameter
  applications without first securing competent advice. While                                                                                                                                                                  material, Nitinol (UNS N01555), a shape memory alloy (SMA) that’s elastic yet
  the material is believed to be technically correct, Nickel        Until now, solar cells tended to be opaque, limiting their use. Professor                                                                                                                                                                  high strength spring-tensioned
  Institute, its members, staff and consultants do not represent                                                                                                                                                                strong to handle the extreme challenges NASA faces on Mars, including no
  or warrant its suitability for any general or specific use and    Kim and his team developed an innovative technique, zeroing in on the                                                                                                                                                                      stainless steel rods run under
  assume no liability or responsibility of any kind in connection                                                                                                                                                              roads and extreme temperatures that can reach -100 °C.
  with the information herein.                                      heterojunction, which comprises thin films of materials responsible for                                                                                                                                                                    the pool to connect the two tubs
   ISSN 0829-8351                                                   absorbing light. To make the junction, the researchers chose nickel oxide,                                                                                 Back on Earth, the patented load-bearing design takes advantage of              to reduce loads on the acrylic
                                                                    a semiconductor known to have high optical transparency. By combining                                                                                      the unique properties of the SMAs, as these special metals can expand,          structure. The result is not only
  Printed in Canada on recycled paper by Hayes Print Group
                                                                    titanium dioxide and nickel oxide semiconductors, they generated an                                                                                        contract, bend or unbend at a very rapid rate. Expected to be on the            a marvel of architecture and
  Cover: Photo by Justin Bulota, © Tugliq Energy
  Stock image credits: pg. 3 iStock©Petmal,                         efficient, transparent solar cell. Says Prof. Kim, “These transparent                                                                                      market by 2022, the company claims they will be a life-of-the-bike tire that    engineering; it is an amazing
  pg.7 iStock©Burben_Images, pg. 8 Shutterstock
  ©encikmohdfirdaus , pg. 13 iStock©typo-graphics                   photovoltaic cells could have various applications in human technology.”                                                                                   shouldn’t ever need replacing, just occasional retreading.                      sight to look up and see.

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NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
alloys like C-22 (N06022), but most        a hundred tons of nickel in the alloys
                                                                                                                               others can use lower alloyed materials.    used. These materials, all in their
                                                                                                                               Take for example, the Hellisheiði          correct application, provide corrosion
                                                                                                                               Power Station in Iceland, near the         resistance, strength and clean surfaces
                                                                                                                               capital Reykjavik, ranked as the sixth     for excellent heat transfer, resulting in

  WIND AND WATER                                                                                                               largest geothermal power plant in the      cost-effective service.
                                                                                                                               world. It produces 303 MW of electric-     Hydro-electric power
                                                                                                                               ity and 400 MW of thermal energy used

  NICKEL IN CLEAN ENERGY
                                                                                                                                                                          Hydro-electric power is presently the
                                                                                                                               to heat homes and businesses, carried      largest source of renewable electricity.
                                                                                                                               by a 19.5 km long pipe to the city. The    Capacity is expected to grow 70 % by
                                                                                                                               wells bring up water at a temperature      2040, mostly in the Asia Pacific region,     Some of the geothermal waters
                                                                                                                               of around 200 °C with a low amount         according to the IEA. It will remain an      are very corrosive as they
                                                                                                                               of chloride and some hydrogen              important renewable energy source            contain high amounts of chlorides
                                                                                                                               sulphide. The materials used in the        for the future. There will be more plants    and hydrogen sulphide. This
                                                                                                                               system range from typical carbon steel     but in addition, older plants will require   is where the use of nickel-
                                                                                                                               casing alloys through various types of
                                                                                                                                                                          refurbishment and efficiency improve-        containing alloys is critical.
  Even small quantities of             In its recent flagship report, The Role of Critical Minerals in Clean Energy            stainless steels to high nickel alloys.
                                                                                                                                                                          ments offering the opportunity for
  nickel in an application can         Transitions, the International Energy Agency documents the expected needs of            Even titanium is needed for certain
                                                                                                                                                                          current technology to be incorporated
  make a big difference to             different metals and minerals to enable low carbon-emitting technologies to             critical components. Some of the key
                                                                                                                                                                          for longer life and greater energy
                                       replace existing non-sustainable electrical generation methods.The report shows         components where nickel is found
  successful deployment.                                                                                                                                                  production.
                                       the importance of nickel (high, medium, low) for some of the clean technologies.        are the turbines, condensers, heat
                                                                                                                               exchangers, pumps and piping systems       Most hydro-electric power systems
                                       Even a small amount of nickel can be        pressurised hot water over about 150 °C                                                have dams that feed turbines to
                                                                                                                               which use, for example, stainless steels
    Clean Energy          Importance   critical in delivering resilience and       is brought up in pipes to the surface       Types 630 (S17400), 316L (S31603),         generate the electricity. Nickel is
    Technology            of Nickel    enabling successful deployment of           where it drives turbines to generate        various duplex alloys, 6 %Mo (S31254)      used in these systems for some key
    Solar Photo-Voltaic   Low          clean technologies. Take hydro-elec-        electricity and then cools. The now         and nickel alloy 625 (N06625). In the      components and it looks like nickel
                                       tric for example. Even though nickel is     lower temperature water is sent through     power plant there may be as much as
    Concentrating Solar   Moderate                                                                                                                                        will play an even greater role in the
    Power (CSP)                        indicated to be of low importance           pipes for district heating systems and
                                       (low quantity) in hydro-electric, its use   subsequently returned to the source
    Wind                  Moderate
                                       is critical in weldability of turbine       to be naturally reheated. One of the
    Hydro-electric        Low          blades and in the long life of other        main advantages of geothermal is that
    Bioenergy             Low          components used in dam gates. In            the energy obtained is reliable and
    Geothermal            High         some applications, we can even say          available all the time, unlike solar or
    Nuclear               Moderate     that nickel is essential for these          wind. Geothermal energy production
                                       technologies. While the IEA report          today is quite limited, perhaps only
    EVs and Battery       High
    Storage                            discusses only electrical power             16 GW capacity, limited to places
                                       generation, some other clean technol-       where the water sources are relatively
    Hydrogen              High
                                       ogies result in energy in the form of       close to the earth’s surface, typically
                                       heat. The production of biofuels is a       less than three kilometres deep. The
                                       case in point, relying heavily on the       capital cost of a geothermal power
                                       use of nickel in the form of stainless      plant tends to be higher than other
                                       steels. In fact, much of the energy mix     sustainable technologies, however the
                                       requires nickel in one form or another,     costs can be justified by the continuous
                                       and all the clean energy technologies       operation of the system.
                                       use nickel. Here we take a closer look      The quality of the water or steam varies
                                       at what nickel is doing in three of the     considerably depending on location.
                                       clean energy technologies: geother-         Some of the waters are very corrosive as
                                       mal, hydro-electric and wind power.         they contain high amounts of chlorides
                                       Geothermal                                  and hydrogen sulphide. This is where
                                       Heat from deep within the earth can be      the use of nickel-containing alloys is
                                       used to generate electricity as well as     critical. Some of the installations, such
                                       for heating homes and other buildings.      as the Salton Sea project in California,
                                       The concept is simple – steam or            make extensive use of nickel-base

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NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
future. At the heart of the power plant      to where 10 MW and larger turbines
                                      is the generator, which consists of a        are being offered today. Larger wind
                                      turbine (runner) driven by flowing           turbines result in lower intensity of
                                      water under pressure, with a moving          material use, meaning less material per
  Hydropower is the largest
                                      rotor containing magnets inside a            MW of energy is used, an important
  source of renewable electricity.
                                      fixed stator with copper wire windings       sustainability criterion. Here nickel is
  And the most durable turbines                                                    also playing a critical role.
                                      which then produces electricity.
  are made from nickel-
                                      Usually, the turbine is made from            Nickel use is most often associated
  containing stainless steel.         nickel-containing stainless steel. It        with stainless steels, and in wind
                                      needs both corrosion and cavitation          turbines, many safety-critical features
                                      resistance. Turbines vary in size but        such as ladders, control panels and
                                      are often very large, and their ability      fasteners will indeed use stainless steel
                                      to be welded and be weld-repaired is         alloys. But the main use of nickel in
                                      critical to material selection. For these    wind power will be small quantities
                                      reasons, the most durable turbines are       to increase the strength and improve
                                      made from nickel-containing martensi-        the toughness of low alloy steels.
                                      tic and austenitic stainless steels such     Many alloying elements will increase
                                      410NiMo (UNS S41500), EN 1.4488 (no          the strength and hardness of steel,
                                      UNS), Type 304 (S30400) and their            but nickel is one of the few that also
                                      cast equivalents.                            improves toughness – the ability to
                                      Stators are also large and here the non-     absorb mechanical energy without
                                      magnetic qualities of nickel-containing      fracturing – which is critical to wind
                                      austenitic stainless steel is key to their   turbine operation.

                                                                                                                                                                                                                                                                JUSTIN BULOTA
                                      performance, particularly alloys such        The gearbox of a turbine contains the
                                      as XM-19 (S20910).                           most critical moving parts. A gearbox
                                      With increasing water pressures and          for an 8 MW turbine can weigh 86 tons.

                                                                                                                                Wind power in the Arctic
                                      volumes, other system components can         If something major fails, replacing
                                      be lowered in weight and increased           parts or even the whole gearbox
                                      in durability with nickel. High strength     on a land-based wind turbine is a
                                      low alloy (HSLA) steels remain a great       very costly exercise, but for offshore       Providing electric power and heat       with a sophisticated energy storage
                                                                                   installations, the costs and downtime        to remote sites in northern Canada      system that includes lithium-ion bat-
                                      candidate for future development of
                                                                                   can be enormous. Thus, reliability
                                      penstocks (large diameter pipes that                                                      is always a challenge, especially if    teries. Integration of the wind turbine
                                                                                   and long life are essential factors in
                                      feed water to the turbine). Penstocks                                                     there are no roads to the site. Such    and diesel energy systems was also
                                                                                   making wind power economically
                                      can be up to 10 m in diameter. Higher
                                                                                   feasible. The weight of the gearbox is       is the case for the Raglan Mine, a      mandatory. These first steps were
                                      strength steel reduces weight and                                                                                                                                           Each turbine allows savings
                                                                                   also important, as the structure must        nickel mine owned by Glencore in        very successful, proving the concept,
                                      has the advantage of increasing the                                                                                                                                         of over 3,600 tons of CO2
                                                                                   support the weight of the nacelle,           Nunavik, which encompasses the          and now studies are underway to
                                      internal diameter. Nickel in these alloys                                                                                                                                   annually and requires
                                                                                   where the gearbox is located, in the         northern third of the province of
                                      promotes martensite formation needed                                                                                              potentially install two new 3 MW wind     about 2,000 kg of nickel
                                                                                   strongest of wind conditions. A one
                                      to obtain the high strength. Nickel has                                                   Quebec. A large supply of diesel fuel   turbines. Each turbine allows savings
                                                                                   kilogram weight reduction in the
                                      the added advantage of improving                                                          is brought in by sea during a short
                                                                                   nacelle can save as much as 10 kg                                                    of over two million litres of diesel
                                      weldability of the penstock materials.
                                                                                   of material in the support structure.        shipping season. The winters are dark   annually resulting in the reduction of
                                      These advantages, lower cost, lower
                                                                                   Design is critical, but so is alloy selec-   and bitterly cold, so having heat and   3,600 tons of carbon dioxide. Nickel
                                      steel usage and improved efficiency,
                                                                                   tion. Much of the steel in the gearbox       power is absolutely essential. Wind
                                      are key to the future of this important                                                                                           contributes to the success. In each
  We often refer to nickel as the                                                  today contains nickel, as much as 2 %
                                      renewable sector.                                                                         energy is one of the few potential      wind turbine, about 2,000 kgs of
  ‘hidden metal.’ In wind turbines,                                                for certain components. Even higher
                                      Wind Power                                   nickel alloy steels are being suggested      alternative sources of energy. But      nickel are used. Applications relying
  it is indeed hidden, but it is
                                      The use of wind to generate energy has       as turbine sizes as high as 20 MW are        can that technology work safely in      on nickel in the nacelle area include
  also an enabler of reliable and
                                      accelerated recently to where nearly         being considered. Components that            extreme Arctic conditions including
  cost-efficient energy generation.                                                                                                                                     bearings, shafts, gears and hydraulic
                                      750 GW of capacity exists worldwide.         today contain no nickel may in the           blizzards?                              components, and in other areas for
                                      The cost of energy from wind turbines        future contain about 0.5 %, in order
                                      has gone down while the size of              to decrease weight and increase              Two wind turbines were constructed      fasteners, control cabinet housings
                                      individual turbines has increased            reliability.                                 and installed in 2014 and 2018, along   and many other components.

8 | NICKEL, VOL. 36, Nº 2, 2021                                                                                                                                                                                               NICKEL, VOL. 36, Nº 2, 2021 | 9
NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
Permanently stored
                                                                                                                                                                                            CO2 received and temporarily stored
                                                                                                                                                                                            Exported via pipeline offshore
                                                                                                                                                                                            Permanently stored resevoir
                                                                                                                                                                                            (2,500-3000 metres

            THE NORTHERN LIGHTS PROJECT                                                                                                                           Transport                 below seabed)
                                                                                                                                                                  Compressed CO2
                                                                                                                                                                  transportd by ship

            CARBON CAPTURE AND STORAGE                                                                                               CO2 Capture
                                                                                                                                     Capture from
                                                                                                                                                                                                  Liquid CO2

            TO REDUCE GREENHOUSE GAS
                                                                                                                                     industrial plants
                                                                                                                                     Compressed and
                                                                                                                                     temporarily stored

                                             Carbon capture and storage (CCS) is a vital part of decarbonising society.
                                             One such process involves the capture of carbon dioxide (CO2) from large
                                             industrial plants, transported in pipelines or ships, and deposited, generally                               Liquid CO2

                                                                                                                                                                                                                                                                               NORTHERN LIGHTS
                                             underground, to prevent it from entering the atmosphere. It has a role to play
                                             in energy transition because renewable energy sources alone will not meet
                                             international 2050 energy and climate targets and completely stop greenhouse
                                             gas emissions. Firstly, there is the (slow) speed at which greening the energy         for food and beverage applications             liquid gas ensures a constant flow into        The proposed maritime CCS
                                             or fuel mix is taking place. Secondly, carbon dioxide can be emitted for               and pressurised products such as               the pipeline and the seabed and is             value chain from emission
                                             reasons unrelated to energy consumption, such as in the production of cement.          fire extinguishers. Nickel is essential        preferable to a start-stop feed which          to subsea storage.
                                             Places where carbon dioxide can be         (atmospheric) and semi-refrigerated         for strength and toughness in these            would occur without this onshore
EQUINOR

                                             safely stored are not generally in the     (semi-pressurised). Liquid CO2 can          thick-walled pressure vessels at below         terminal.
                                             areas where it is produced. Offshore       only exist at a combination of low          zero temperatures.                             As part of the first phase of opera-
                                             storage – despite its complexity –         temperature and pressures well above        About Northern Lights                          tions, Northern Lights is building
                                             seems to be gaining over onshore           atmospheric pressure. Hence, a CO2          Despite the challenges, CCS projects           two dedicated 130 m long, 7,500 m3
                                             storage, which is often resisted by        cargo tank should be of the pres-           are beginning to materialise. Northern         capacity CO2 carriers. These will take
                                             local residents. To bridge the distance    sure-type or semi-refrigerated.             Lights is the transport and storage            captured and liquefied CO2 from
                                             between the place of emission and          The semi-refrigerated type, including       component of the Longship project,             several emitters and transport it to the
                                             the place of storage, two options          the few existing CO2 carriers, is           promoted and supported by the                  onshore storage site before it is piped
                                             are available: shipping by vessel or       designed to take into consideration the     Norwegian government, which                    100 kilometres offshore and 2,600 m
            A fleet of dedicated CO2
                                             transportation by pipeline. Shipping is    combined conditions of temperature          includes capture of CO2 from indus-            beneath the seabed for permanent
            transport vessels will be
                                             more economical at low volume and          and pressure necessary for cargo gas        trial sources in the south-eastern part        storage. The first phase aims at
            required for maritime CCS
                                             long distance, while pipelines are the     to be kept as a liquid. Ship designers      of Norway (Brevik and Oslo). When              gradually storing up to one and a
            to reach its full potential.
                                             most viable option for large volumes       prefer this type as it enables larger and   it starts operations in 2024, Northern         half million tons per year under the
                                             at distances below 700 km. Also, in        less expensive ships to be built. The       Lights, owned by Equinor, Shell and            seabed, which is the amount the two
                                             an emerging activity, such as CCS,         cargo tank must operate at around           Total, will be the first-ever cross-           ships can transport annually.
                                             shipping requires less capital expendi-    -54 °C / 6 bar to -50 °C / 7 bar. This is   border, open-source CO2 transport              Essential nickel
                                             ture, making it the preferred option to    near the ‘triple point’ of CO2, where       and storage infrastructure network.            Because very few dedicated CO2
                                             ship the initially low volumes of CO2      gas, liquid and solids coexist, but the     It will ship captured CO2 to an                carriers exist, the design of the two
                                             to the few available storage facilities.   technology is not currently at the point    onshore terminal on the Norwegian              Northern Lights carriers required
                                             How to build a carbon dioxide ship?        where this design can be implemented        west coast and, from there, transport          engineers and the shipping classi-
                                             There are three types of tank struc-       efficiently and safely. Currently CO2       it by pipeline to an offshore subsur-          fication societies to agree on the
                                             tures for liquid gas transport ships:      carriers operate at higher pressure and     face storage location in the North Sea.        construction material for the onboard
                                             fully pressurised, low temperature         around -20 °C. They carry liquid CO2        This intermediate onshore storage of           pressure vessels. It had to be easy to

          10 | NICKEL, VOL. 36, Nº 2, 2021                                                                                                                                                                                                  NICKEL, VOL. 36, Nº 2, 2021 | 11
NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
fabricate and capable of accommo-           line pipe steel (similar to API 5L
                                                                dating high pressure and low temper-        X65) with 0.50 % nickel. With most
                                                                ature. The result was the selection         of the length having a thickness of
                                                                of a 50 mm thick, up to 2.50 % Ni           about 16 mm, this represents about
                                                                pressure vessel steel P690QL2 (EN
                                                                10028-6 type 1.8888). Two pressure
                                                                                                            13,000 tons of steel and 65 tons of
                                                                                                            nickel.                                                      NICKEL ALLOYS: WORKHORSE
                                                                                                                                                                         ‘C’ FAMILY NICKEL-BASE ALLOYS
                                                                vessels on each ship operate at 15 bar     •	Managing such a long pipeline in an
                                                                and -26 °C, safely away from the triple       offshore environment requires a set
                                                                point. This represents about 3,000 tons       of ancillary tubes that are bundled
                                                                of steel containing 75 tons of nickel.        into an ‘umbilical.’ The small tubes
                                                                The CCS value chain further                   inside the umbilical carry the
                                                                consists of:                                  hydraulics for remote operation of
                                                                •	Onshore storage: 12 pressure vessels       valves and other chemicals. These                          In the early 1930s, the first Ni-Cr-Mo alloy, known as alloy C (UNS N10002), was
                                                                                                                                                                         introduced. It was an optimisation of the Ni-Cr alloys which had good resistance
                                                                   with a total capacity of 8,250 m3.         tubes with a wall thickness of only
                                                                                                                                                                         to oxidising acids, such as nitric acid, and Ni-Mo alloys with superior resistance
                    CO2 emitted from sites in South                Nickel is again needed to cope             1.42 mm are hard to access once
                                                                                                                                                                         to reducing acids, such as hydrochloric acid. This combination resulted in an
                    East Norway will be shipped to                 with pressure and low temperature.         installed and must resist seawater.
                                                                                                                                                                         alloy family with exceptional corrosion resistance in a wide variety of severe
                    an onshore temporary storage                   The entire tank farm represents            For resilience they are fabricated
                                                                                                                                                                         corrosive environments typically encountered in chemical and petrochemical
                    facility before being transported              2,000 tons of pressure vessel steel        from Type 2507 (S32750) super
                                                                                                                                                                         processing, exceeding that of stainless steels which had been discovered in 1913.
                    by pipeline to offshore subsea                 P460ML1 (EN 10028-5) and P355NL1           duplex stainless steel. 35 km of
                                                                                                                                                                         In the mid-1960s, advances in both                  power plants. These units needed to

                                                                                                                                                     PENTICTON FOUNDRY
                    storage in the North Sea.                      (EN 10028-3) containing up to 0.50%        an umbilical with four 2507 tubes
                                                                   nickel.                                    represents about 10 tons of nickel.                        melting technology (namely the                      be resistant to the corrosive acids
                                                                                                                                                                         development of argon-oxygen                         formed by the flue gases. Alloy C-276
                                                                •	A 100 km 323.8 mm outside diameter      According to the Northern Lights                              decarburisation) and corrosion                      was used in many of these critical
                                                                   pipeline keeps the CO2 in the liquid    model, CCS will start to deliver                              science (knowledge of the influence                 applications. Also, at this time alloy
                                                                   phase. This again means pressure        its promise by 2024. About 150 to                             of minor element additions) led to                  C-4 (N06455) designed for the
                                                                   and low temperature. It runs on         200 tons of nickel are essential to                           the development of alloy C-276                      European chemical industry, was
                                                                   the seabed, to reach the offshore       capture and store 1.5 million tons                            (N10276), a low-carbon, low-silicon                 introduced.
                                                                   location from where the CO2 is          of CO2 per year this way. To achieve                          wrought version of alloy C. Alloy                   The early 1980s saw the introduction
                                                                   injected into a geological reservoir,   climate goals with CCS and other                              C-276 is now an industry standard for               of Alloy 22, with a higher chromium
                                                                   2.6 km under the seabed. The            technologies, nickel is clearly an                            use in chemical and petrochemical                   content increasing corrosion resist-
                                                                   pipeline is made of DNV 450 FPDS        essential component.                                          processing.                                         ance in oxidising media. In the 1990s
                                                                                                                                                                         The 1970 United States Clean Air Act                this was followed by Alloy 59
                                                                                                                                                                         led to the widespread adoption of                   (N06059), Alloy 686 (N06686) and
                                                                                 Onshore facility at
                          NORTHERN LIGHTS                                        Naturgassparken near                                                                    flue gas desulfurisation technology,                C-2000® (N06200), with additional        90 years after the introduction
                                                                                 Bergen                                                                                  mostly in the form of wet scrubbing                 improvements in corrosion resist-        of alloy C, the C family of nickel-
                          PROJECT MAP                                                                            Fortum Oslo Varme                                       units, to reduce sulfurous gas emis-                ance that expanded the range of          base alloys finds extensive use
                                                                                                                waste-to-energy plant                                    sions from the nation’s coal-fired                  more demanding applications.             in applications such as pollution
                                                                                            Norway                                                                                                                                                                    control, petrochemical/chemical,
                               Offshore subsea storage                                                                                                                     Typical composition of the C family alloys                                                 production of various acids, metal
                              location in the North Sea                                                                                                                                                                                                               processing, and pharmaceutical.
                                                                                                             Norcem
                                                                                                                                                                          Alloy     (UNS)           Decade              Ni       Cr     Mo      W      Cu     Fe
                                                                                                       cement factory                                                                             introduced
                                                                                                                                                                            C      (N10002)          1930s          Bal.         16     16      4       -      6
                                                                                                                                                                          C-276    (N10276)          1960s          Bal.         16     16      4       -      5
                                              Northern Lights consortium
                                   is handling transportation and storage                                                                                                  C-4     (N06455)          1970s          Bal.         16     16              -      2
                                                                                                                                                                           22      (N06022)         Mid 1980s       Bal.         21     13      3       -      3
                                                                                                                                                                           59      (N06059)        Early 1990s      Bal.         23     16      -       -
NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
ASK AN EXPERT FAQ FROM                                                                                   NEW PUBLICATIONS
                                                                 THE NICKEL INSTITUTE
                                                                                                                                                                          Stainless steel infrastructure:                       studies that the total cost of owner-
                                                                                                                                                                          a lifetime of savings explains how                    ship over the life of a stainless steel

                                                                 TECHNICAL ADVICE LINE
                                                                                                                                                                          the unique properties of nickel-con-                  asset can be highly competitive,
                                                                                                                                                                          taining stainless steel make it a                     despite its higher initial investment
                                                                                                                                                                          cost-effective choice of material for                 cost compared with less durable
                                                                                                                                                                          a wide range of structural appli-                     alternatives. Available for download
                                                                                                                                                                          cations. It demonstrates through                      from the Nickel Institute website.
                                                                                                                                                                          a selection of international case                     nickelinstitute.org

   Geir Moe P.Eng. is the Technical
   Inquiry Service Coordinator at
   the Nickel Institute. Along with
   other material specialists situated
   around the world, Geir helps
                                                                 Q
                                                                 Q: The stainless steel railing outside our building is showing
                                                                 rusty spots after a couple of years. Was the wrong grade of
                                                                 stainless steel installed?
                                                                 A: This is likely atmospheric corrosion related to the presence of salts
                                                                                                                                                                          Refreshed INCO publications
                                                                                                                                                                          Twenty-eight significant technical
                                                                                                                                                                          publications, originally produced by
                                                                                                                                                                          INCO, and maintained by the Nickel
                                                                                                                                                                                                                                relevant today. This high-quality
                                                                                                                                                                                                                                technical information will give
                                                                                                                                                                                                                                practitioners confidence in working
                                                                                                                                                                                                                                with nickel-containing materials
                                                                                                                                                                                                                                                                                                 SO
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                                                                                                                                                                                                                                                                                                                               LDU
                                                                                                                                                                                                                                                                                                 IN NG W    PRSOTEELSP       AND      DUCTILE
                                                                 and is commonly known as ‘tea staining.’ It is most often seen near the                                                                                                                                                        URR
                                                                                                                                                                                                                                                                                                     I                   U   E NI
                                                                                                                                                                                                                                                                                                                                U S -RE
                                                                                                                                                                                                                                                                                                                                    E   SIST
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   end-users and specifiers of nickel-                                                                                                                                    Institute have been refreshed and                     and to harness their benefits in a                          OCC
                                                                                                                                                                                                                                                                                                                     HE THSE
                                                                                                                                                                                                                                                                                                                 TO TE TO
                                                                                                                                                                                                                                                                                                            IDLEGUID GU  LOEYATO
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                                                                 seashore or in locations where road salt is used. Tea staining occurs                                                                                                                                                                  PR  ACLPR AC
                                                                                                                                                                                                                                                                                                         ICAA
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                                                                                                                                                                                                                                                                                                                                                      08THE
                                                                                                                                                                                                                                                                                                                                                   11ALL OYSUSE

                                                                                                                                                                          re-published. The digital quality of                  wide range of applications. This
                                                                                                                                                                                                                                                                                                                            OF NICKEL-CONTAINING       NO ALLOYS
                                                                                                                                                                                                                                                                                                                                                          242
   containing materials seeking                                                                                                                                                                                                                                                                   OF N                                                     NO 242

                                                                 when local conditions (such as temperature, relative humidity and pres-
   technical support. The team is on                                                                                                                                      the guides has been improved and                      information is of value to materials
                                                                 ence of corrosive substances on the surface) are too aggressive for that
   hand to provide technical advice                                                                                                                                       all publications are searchable. The                  specifiers, welders, fabricators and
                                                                 stainless steel alloy in its installed condition. The potential for staining                                                                                                                                                                                                        Dist
                                                                                                                                                                                                                                                                                                                                                          ribut
                                                                                                                                                                                                                                                                                                                                                                ed by
                                                                                                                                                                                                                                                                                                                                                              NICK
                                                                                                                                                                                                                                                                                                                                                                    ELd by
                                                                                                                                                                                                                                                                                                                                                                 bute

   free of charge on a wide range                                                                                                                                         original publications were written                    engineers, and is available for free
                                                                                                                                                                                                                                                                                                                                                           Distri ITUTEKEL
                                                                                                                                                                                                                                                                                                                                                                    NIC dE by
                                                                                                                                                                                                                                                                                                                                                            INST trib
                                                                                                                                                                                                                                                                                                                                               by
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                                                                                                                                                                                                                                                                                                                                                                 INS NICKEL
                                                                                                                                                                                                                                                                                                                                     ProdProduce
                                                                                                                                                                                                                                                                                                                                                                              TEby

                                                                 is increased in sheltered areas, such as under eaves, that do not benefit
                                                                                                                                                                                                                                                                                                                                                    ed by           Distrib uted
                                                                                                                                                                                                                                                                                                                                      INCO    O duc                  INSTITU
                                                                                                                                                                                                                                                                                                                                          INCPro                            NICKEL
                                                                                                                                                                                                                                                                                                                                                 O
                                                                                                                                                                                                                                                                                                                                                Produc ed by          Distributed
                                                                                                                                                                                                                                                                                                                                             INC                        INSTITUTEby

   of applications such as stainless                                                                                                                                      by experts in their field and the                     download from the Nickel Institute
                                                                                                                                                                                                                                                                                                                                                 Produced by
                                                                                                                                                                                                                                                                                                                                                INCO                          NICKEL
                                                                                                                                                                                                                                                                                                                                                 INCO                     INSTITUTE

                                                                 from rinsing by rain allowing concentration of corrosive substances.
   steel, nickel alloys and nickel                                                                                                                                        information they provide is still very                website. nickelinstitute.org
                                                                 Also, horizontal and rougher surfaces can more easily retain corrosive
   plating to enable nickel to be used
   with confidence.                                              substances, thus smoother surfaces and surfaces that can easily drain

                                                                                                                                                                            UNS DETAILS
   https://inquiries.nickelinstitute.org/                        are less susceptible to corrosion.                                                                                                                                Chemical compositions (% by weight) of the alloys and stainless steels
                                                                                                                                                                                                                                   mentioned in this issue of Nickel.
                                                                 Type 304L (UNS S30403) is typically suitable away from the seashore
                                                                 and in areas not exposed to road salts. Otherwise 316L (S31603) is                                        UNS           Al      C      Co      Cr      Cu         Fe     Mn      Mo       N      Nb       Ni      P       S                   Si                    Ti                                V                W
                                                                 usually adequate, however there are some coastal areas where more

      NICKEL
                                                                                                                                                                           N01555         -     0.07    0.05   0.01     0.01       0.05     -       -       -     0.025   54.0-     -       -                    -                   bal                                -                -
                                                                                                                                                                           pg 5                 max     max    max      max        max                             max    57.0
                                                                 corrosion-resistant grades, such as 2205 (S32205) and super duplex
                                                   O N L I N E

                                                                                                                                                                           N06022         -     0.015   2.5    20.0-      -        2.0-   0.50    12.5-     -       -      bal    0.02    0.02               0.08                      -                           0.35                2.5-
                                                                 (S32750 or S32760) may be required.                                                                       pg 7                  max    max    22.5                6.0    max     14.5                            max     max                max                                                   max                 3.5
                                                                                                                                                                           N06625        0.40   0.10     -     20.0-               5.0    0.50    8.0-            3.15-    bal    0.015   0.015              0.50                  0.40
                                                                 An appropriate stainless steel alloy                                                                      pg 7          max    max            23.0                max    max     10.0            4.15             max     max               max                   max

                                                                 is a low maintenance material but                                                                         S17400         -     0.07     -     15.00-   3.00-      bal    1.00      -       -     0.15-   3.00-   0.040   0.030              1.00
      WWW.NICKELINSTITUTE.ORG                                                                                                                                              pg 7                 max            17.50    5.00              max                     0.45    5.00     max     max               max
                                                                 is not always maintenance-free.                                                                           S20910         -     0.06     -     20.5-      -        bal    4.00-   1.50-   0.20-   0.10-   11.5-   0.040   0.030              0.75                      -                          0.10-                  -
      SUBSCRIBE to Nickel magazine free of charge and                                                                                                                      pg 8                 max            23.5                       6.00    3.00    0.40    0.30    13.5     max     max               max                                                  0.30
      receive a printed copy or an e-mail notice when a          Natural rain washing may be
                                                                                                                                                                           S30400         -     0.08     -     18.0-      -        bal    2.00      -       -       -     8.0-    0.045   0.030              1.00                      -                                -                -
      new issue is published. www.nickelinstitute.org                                                                                                                      pg 2, 8              max            20.0                       max                             10.5     max     max               max
                                                                 sufficient, otherwise manual
      READ Nickel magazine online in several languages.                                                                                                                    S30403         -     0.030    -     18.0-      -        bal    2.00      -       -       -     8.0-    0.045   0.030              1.00                      -                                -                -
                                                                 washing may be needed.                                                                                    pg 14                 max           20.0                       max                             12.0     max     max               max
      www.nickelinstitute.org/nickel-magazine/
                                                                                                                                                                           S31254         -     0.020    -     19.5-    0.50-      bal    1.00    6.0-    0.18-     -     17.5-   0.030   0.010              0.80                      -                                 -               -
      SEARCH BACK ISSUES of Nickel magazine from our
                                                                 Tea staining is discussed                                                                                 pg 7                  max           20.5     1.00              max     6.5     0.22            18.5     max     max               max
      online archive, going back to 2009.                        in greater detail in the NI                                                                               S31603         -     0.030    -     16.0-      -        bal    2.00    2.00-     -       -     10.0-   0.045   0.030              1.00                      -                                 -               -
      www.nickelinstitute.org/nickel-magazine/                                                                                                                             pg 5, 7, 14           max           18.0                       max     3.00                    14.0     max     max               max
                                                                 publication Stainless Steels                                                                              S32205         -     0.030    -     22.0-      -        bal    2.00    3.00-   0.14-     -     4.50-   0.030   0.020              1.00                      -                                 -               -
      FOLLOW US on Twitter @NickelInstitute                                                                                                                                pg 14, 16             max           23.0                       max     3.50    0.20            6.50     max     max               max
                                                                 in Architecture, Building and
                                                                                                                                                                           S32304         -     0.030    -     21.5-    0.05-      bal    2.50    0.05-   0.05-     -     3.0-    0.040   0.040              1.00                      -                                 -               -
      JOIN US on LinkedIn –
                                                                 Construction – Guidelines for                                                                             pg 2                  max           24.5     0.60              max     0.60    0.20            5.5      max     max               max
      visit the Nickel Institute’s page
                                                                                                                                                                           S32750         -     0.030    -     24.0-      -        bal    1.20    3.0-    0.24-     -     6.0-    0.035   0.020              0.80                      -                                 -               -
                                                                                                                                                FROM PUBL 11 024 BY TMR

                                                                 Corrosion Prevention (11 024)                                                                             pg 12, 14             max           26.0                       max     5.0     0.32            8.0      max     max               max
      WATCH nickel-related videos on
      the Nickel Institute YouTube channel                       available for download from the                                                                           S32760         -     0.030    -     24.0-    0.50-      bal    1.00    3.0-    0.20-     -     6.0-    0.030   0.010              1.00                      -                                 -             0.50-
                                                                                                                                                                           pg 14                 max           26.0     1.00              max     4.0     0.30            8.0      max     max               max                                                                       1.00
      www.youtube.com/user/NickelInstitute
                                                                 Nickel Institute website:                                                                                 S41500         -     0.05     -     11.5-    0.50-      bal      -     0.50-     -       -     3.5-    0.030   0.03.              0.60                      -                                -                -
                                                                                                                                                                           pg 8                 max            14.0     1.00                      1.00                    5.5      max    max                max
                                                                 nickelinstitute.org/library

14 | NICKEL, VOL. 36, Nº 2, 2021                                                                                                                                                                                                                                                                                  NICKEL, VOL. 36, Nº 2, 2021 | 15
NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
KING ABDULAZIZ CENTER
               FOR WORLD CULTURE
                                                   Located in Dhahran, Saudi Arabia, the Center was designed by architects
                                                   from Snøhetta of Norway and was completed in 2017. Resembling five
                                                   smooth ‘boulders’ randomly piled together, this spectacular building complex
                                                   contains libraries, educational facilities, exhibition halls, theaters, museums,
                                                   a mosque, and dining facilities. At the lowest point in the Center, an exhibit
                                                   acknowledges oil as the historical foundation of the Kingdom’s economic
                                                   prosperity. History gives way to the present at ground level where the Great
                                                   Hall showcases the best of world cultural experiences. The future is then
                                                   contemplated and forecast in the 90 m (295 ft) high Knowledge Tower.
                                                   The boulders are covered with            and clean appearance. Each tube
                                                   closely-spaced stainless steel tubes     section is unique and was bent to fit
                                                   to create a veil that stands proud of    its precise position using a computer-
                                                   the building’s weather-proof panels.     controlled machine. If placed end-to-
©SNØHETTA

                                                   Fabricated by Seele of Germany,          end, the 93,000 plus tube sections,
                                                   the tubes (7.6 mm diameter x 2 mm
                                                                                            weighing over 1,000 tons, would
               The ‘boulders’ are covered          wall thickness) are made of duplex
                                                   Alloy 2205 (UNS S32205) stainless        have a total length of 360 km
               with closely-spaced stainless
                                                   steel. This alloy, containing 5.5 %      (220 miles). The tubes help to keep
               steel tubes to create a veil that
                                                   nickel, was selected for its excel-      the building cool by shading the
               stands proud of the building’s
                                                   lent strength, ductility, long-term      exterior surfaces and by reflecting
               weather-proof panels.
                                                   abrasion and corrosion resistance,       and conducting away heat.

            16 NICKEL,
               | NICKEL,VOL.
                         VOL.36,36,NºNº2,2,2021
                                            2021
NICKELM Critical nickel: providing sustainable solutions - Nickel Institute
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