(Bio)Signatures of Planet Earth from (Spectro)Polarimetry - Michael Sterzik, European Southern Observatory Stefano Bagnulo, Armagh Observatory

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(Bio)Signatures of Planet Earth from (Spectro)Polarimetry - Michael Sterzik, European Southern Observatory Stefano Bagnulo, Armagh Observatory
(Bio)Signatures of Planet Earth

   from (Spectro)Polarimetry

Michael Sterzik, European Southern Observatory

Stefano Bagnulo, Armagh Observatory
(Bio)Signatures of Planet Earth from (Spectro)Polarimetry - Michael Sterzik, European Southern Observatory Stefano Bagnulo, Armagh Observatory
a             b                   c

              ‘ Holds Life?
    Which World
d             e                   f

    Polarimetry will help.
       Talk by Fossati
       Poster B4 by Bagnulo
       Poster B18 by Miles-Paez
(Bio)Signatures of Planet Earth from (Spectro)Polarimetry - Michael Sterzik, European Southern Observatory Stefano Bagnulo, Armagh Observatory
322                                                                                                 BAILEY

Polarimetric Signatures of Planet Earth                           occurring at the minimum scattering angle, and
                                                                  this occurs at:

                                                                                x0 ! !"((4 " n2)/3)                (2)
                                                                                                                         On Venus, the liquid is sulfuric acid (about 75%
                                                                                                                         H2SO4 to 25% H2O) with a refractive index of 1.44
                                                                                                                         (Hansen and Hovenier, 1974), whereas on Titan,
                                                                                                                         it is liquid methane at a temperature of #100K,
                                                                                                                         which has a refractive index of 1.29 (Badoz et al.,

                        rainbow polarization
                                                                  For water, the resulting scattering angle is about     1992).
                                                                  139° (for blue light), which gives a rainbow with         The light of the rainbow is highly polarized in
                                                                  a semivertex angle of 41° about the anti-solar         a direction perpendicular to the scattering plane.
                                                                  point. Light that internally reflects twice inside a   This arises because the angle of incidence within
                                                                  droplet gives a secondary rainbow at a scattering      the drop is close to the Brewster angle, at which
                                                                  angle of about 128°. The region between the pri-       light with parallel polarization is fully transmit-
                                                                  mary and secondary rainbows is dark (Alexan-           ted, but light with perpendicular polarization is
                                                                  der’s dark band), but some light is scattered into     partially reflected. For water, the primary rain-
                                                                  angles inside the primary rainbow and outside          bow has a polarization of about 96% and the sec-
                                                                  the secondary rainbow.                                 ondary rainbow about 90% for large droplets
                                                                     Figure 1 shows the variation of primary rain-       (Adam, 2002).
                                                                  bow scattering angle with refractive index de-
                                                                  rived from Eqs. 1 and 2. This variation of scat-       Rainbows in Lorenz-Mie theory
                                                                  tering angle with refractive index gives rise to the
                                                                  familiar colors of the rainbow since the refractive       The familiar brightly colored rainbows arise
                                                                  index of water varies from about 1.344 at 400 nm       from water droplets with a size of 1 mm or larger.
                                                                  to 1.329 at 800 nm, which gives a range of scat-       However, the rainbow scattering phenomenon
                                                                  tering angles from 139.5° to 137.4°. It also means     persists for much smaller droplets. As the drop-
                                                                  that different scattering liquids will give rise to    lets become smaller, diffraction effects broaden
                                                                  different rainbow angles. Liquid droplet clouds,       the scattering peak (as a function of scattering an-
                                                                  and probably rain, are known to occur in the at-       gle), and this means that rainbows from small
                                                                  mospheres of Venus and Titan as well as Earth.         droplets (fogbows or cloudbows) no longer show
                                                                                                                         distinct colors. Nevertheless, there is still a strong,
                                                                                                                         highly polarized scattering peak at the primary
                                                                                                                         rainbow angle. It is the ability to observe rainbow
                                                                                                                         scattering from cloud droplets that makes rain-
                                                                                                                         bow scattering a feasible technique for studying
                                                                                                              Venus      extrasolar planets.
                                                                                                                            The rainbow scattering from small particles can
                                                                                                                         be best studied using Lorenz-Mie scattering the-
                                                                                                                         ory. To investigate the rainbow properties, I have
                                                                                                      Earth              carried out a series of calculations of the normal-
                                                                                                                         ized scattering matrix Fij (Mishchenko et al., 2002,
                                                                                                                         Eq. 4.51) for a size distribution of spherical
                                                                                              Titan                      droplets. The calculations used the code of
                                                                                                                         Mishchenko et al. (2002, section 5.10). The size dis-
                                                                                                                         tribution of spherical droplets is specified using
                                                                                                                         the power-law distribution of Hansen and Travis
                                                                                                                         (1974):

                                                                                                                              n(r) !   $
                                                                                                                                       constant # r"3, r1 $ r $ r2,
                                                                                                                                        0,             otherwise
                                                                                                                                                                             (3)

                                                                                                                         As described by Mishchenko et al. (1997), the val-
                                                                FIG. 1. Primary rainbow scattering angle as a function ues of r1 and r2 can be expressed in terms of the
                                                                of refractive index, as determined by the ray optics ap- cross-section-area weighted effective radius reff
Hansen, J. E. & Hovenier, J. W. Interpretation of the polarization  of Venus. Journal of Atmospheric Science 31, 1137–1160 (1974).
                                                                proximation. The rainbow angles are indicated (at a
Bréon, F. M. & Goloub, P. Cloud droplet effective radius from spaceborne
                                                                wavelength ofpolarization
                                                                                400 nm) for measurements.
                                                                                                                           andresearch
                                                                                                                 Geophysical
                                                                                              three substances known    to
                                                                                                                                effectiveletters
                                                                                                                                          variance    eff.
                                                                                                                                                 25, !1879–1882 (1998).
Bailey, J. Rainbows, Polarization, and the Search for Habitable form  liquid Astrobiology
                                                                  Planets.    droplet clouds 7,
                                                                                              in 320–332
                                                                                                  the solar system:
                                                                                                            (2007). liquid   The components of the normalized scattering
                                                                methane (Titan), water (Earth), and sulfuric acid (Venus). matrix describe the intensity and polarization of
(Bio)Signatures of Planet Earth from (Spectro)Polarimetry - Michael Sterzik, European Southern Observatory Stefano Bagnulo, Armagh Observatory
Polarimetric Signatures of Planet Earth
                                                                                   – 27 –

               pure ocean surface                                                                                              pure land surface

                                                                                  no clouds

                                                                                    clouds

                                 Phase Angle                                                                                         Phase Angle

 McCullough, P. R. Models of Polarized Light from Oceans and Atmospheres of Earth-like Extrasolar Planets. arXiv astro-ph, (2006).

 Williams, D. M. & Gaidos, E. Detecting the glint of starlight on the oceans of distant planets. Icarus 195, 927–937 (2008).
(Bio)Signatures of Planet Earth from (Spectro)Polarimetry - Michael Sterzik, European Southern Observatory Stefano Bagnulo, Armagh Observatory
996
                Models of the Earth’s Polarization  D. M. Stam: Spectropolarimetry of Earth-like exoplanets

         0.25                                                                         1.0

                                                          Degree of polarization Ps
                 1.0                                                                        0.0
     0.20                                                                             0.8

   0.15                                                                               0.6
                                                                                                 VRT          calc.       include
Flux F

                                                                0.1                          Fig. 3. The flux F (left) and the degree of

   0.10
             0.4                                 0.4                                                        Rayleigh
                                                                                             linear polarization P (right) of starlight re-
                                                                                             flected by model     planets with clear atmo-
                                                                                                                                                  s

                                                                                                        phase            angle
                                                 0.2                                         spheres and isotropically reflecting, com-
   0.05                                                                                      pletely depolarizing     surfaces  as functions
         0.0                                     0.0     1.0                                 of the wavelength, for various values of

                                                    0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0 0.0, 0.1, 0.2, 0.4,ocean
   0.00                                                                                      the (wavelength independent) surface albedo:
      0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0                                                                            0.8, and 1.0. The planetary
              Wavelength λ (in µm)                          Wavelength λof(in
                                         D. M. Stam: Spectropolarimetry       µm) exoplanets
                                                                           Earth-like        phase angle α is 90 .                          999
                                                                                                                                              ◦

   0.25                                           1.0
                                                                                                              clouds
 (quadrature) is
              1.0relatively high (provided there is an observable
                                                        0.0         absorption of light in the
                                                                                                      “vegetation”
                                                                                               Fig.Huggins
                                                                                                    7. The wavelength
                                                                                                              band of Odependent
                                                                                                                              decreases    (left)
                                                                                                                                        F the
                                                             Degree of polarization Ps

                                                                                                                                                       3
 exoplanet).
   0.20                                           0.8               amount ocean               and P light,
                                                                              of multiple scattered    (right)which
                                                                                                               of starlight thathas
                                                                                                                      usually  sis reflected
                                                                                                                                     a lowerby
                                                                                               clear and cloudy horizontally homogeneous
     Each curve in Fig. 3 can be thought of as consisting of acleardegree of polarization than the singly-scattered light. In gen-
                                                                                                                         model planets with surfaces covered by de-
continuum
   0.15      cloudy
              with superimposed high-spectral resolution          0.6       features. eral, with increasing atmospheric
                                                                                                                          work in progress
                                                                                                                                      absorption     optical   thickness,
Flux F

                                                                                                                         ciduous forest    (thin solid  lines) and    a specu-
The continua of the flux and polarization curves are determined Ps will                               tend towards thelar
                                                                                                  forest                  degree    of polarization
                                                                                                                             reflecting                  of light
                                                                                                                                         ocean (thin dashed          singly-
                                                                                                                                                                  lines). Note
by0.10
    the scattering of light by gaseous molecules in the atmosphere0.4      cloudy           scattered by the atmospheric       constituents
                                                                                                                         that the               (for these
                                                                                                                                   lines pertaining    to Psmodel
                                                                                                                                                              of the plan-
                                                                                                                                                                        cloudy
and by the surface albedo. The high-spectral resolution features ets: only gaseous molecules),
are0.05           clear
     due to the absorption      of light by the gases O0.2         3 , O2 , and H2 O        single-scattering angle Θfrom inhomogenities
                                                                                                                            andeach
                                                                                                                                   whicharedepends
                                                                                                                         atmospheres
                                                                                                                                  thusother.
                                                                                                                                        on the
                                                                                                                                               virtuallystrongly
                                                                                                                                               Forplanetary
                                                                                                                                                    comparison, phase
                                                                                                                                                                     on the
                                                                                                                                                          indistinguishable
                                                                                                                                                                      we an-
                                                                                                                                                                          have
(see below).
           0.0 Note that the strength and shape of the absorption
   0.00 depend on the spectral resolution (0.001 0.0
bands
       0.3calculations.
            0.4 0.5 0.6 0.7 0.8 0.9 1.0
                                                                          1.0
                                                                      0.3 0.4 0.5 0.6
                                                                                            gle α. From Fig. 1b, it can
                                                                   µm) of the nu- 90◦ , Ps of light singly-scattered
                                                                                                 0.7This
                                                                                                       0.8explains
                                                                                                                           realistic clouds
                                                                                                                         alsobe  seen that
                                                                                                                               included
                                                                                                                         planets with
                                                                                                             0.9 1.0the high
                                                                                                                         1.0 (thick
                                                                                                                                          the at
                                                                                                                                    by surface
                                                                                                                                                  a scattering
                                                                                                                                               spectra
                                                                                                                                        gaseousalbedos
                                                                                                                                     solid
                                                                                                                                                           equal is
                                                                                                                                                    molecules
                                                                                                                                                                   angle
                                                                                                                                                        of the clear       of
                                                                                                                                                                         model
                                                                                                                                                                    to about
                                                                                                                                                                       0.0 and
merical                                                                                     0.95.                               values  oflines),
                                                                                                                                             Ps at shown    before in
                                                                                                                                                    the shortest        Fig. 3.
                                                                                                                                                                      wave-
                 Wavelength (in µm)                                               Wavelength (in µm)
     In the total flux curves (Fig. 3a), the contribution of light lengths in Fig. 3b. WithThe                              aerosols/haze
                                                                                                                              planetarywavelength,
                                                                                                                          increasing
scattered by atmospheric molecules is greatest around 0.34 µm: multiple-scattered light decreases, simply because of the de-
                                                                                                                                          phase angle isthe   ◦
                                                                                                                                                           90 amount
                                                                                                                                                                .          of

at shorter
be  observed
Huggins
            wavelengths,
               on  the
           absorption
                        moon’s
                         band,
                              light
                                 and
                                     is absorbed
                                   nightside.
                                      at   longer
                                                        by O3 in the
                                                  Interestingly,
                                                    wavelengths,
                                                                       the
                                                                         the
                                                                            so-called
                                                                            reflection
                                                                              amount
by chlorophyll leaves a much stronger signature in Ps than in F, the last fact, the
                                                                                            crease   in the atmospheric
                                                                                             singly-scattered
                                                                                            Consequently,      P
           Stam, D. M. Spectropolarimetric signatures of Earth-like extrasolar planets. A&A 482, 989–1007 (2008)  by
                                                                                                                  of the  realistic surfaces
                                                                                                                           molecular
                                                                                                                     gaseous
                                                                                                                         planet    with
                                                                                                                                        scattering
                                                                                                                                molecules
                                                                                                                                         the
                                                                                                                                              (see
                                                                                                                                              black
                                                                                                                                                      optical
                                                                                                                                                     Fig.  1b).
                                                                                                                                                      surface
                                                                                                                 s continuum P of the cloudy planets is neg-
                                                                                                                                                               thickness.
                                                                                                                                                                   Thanks to
                                                                                                                                                                  increases
of starlight that is scattered by the atmospheric molecules de- with wavelength, to approach itss single-scattering value at the
(Bio)Signatures of Planet Earth from (Spectro)Polarimetry - Michael Sterzik, European Southern Observatory Stefano Bagnulo, Armagh Observatory
Earth aspect variations
(Bio)Signatures of Planet Earth from (Spectro)Polarimetry - Michael Sterzik, European Southern Observatory Stefano Bagnulo, Armagh Observatory
Earthshine

                                Phase angle

courtesy of E. Pallé
1957SAnAp...4

                                     195
                 Early Polarimetry of Planet Earth

                                                                                                 1957SAnAp...4....3D
                  Difficult!

                                                                   fractional Polarization [‰]

                                                                                                                                       Phase Angle
                Wavelength dependency                                                                                  Moon surface depolarization

Dollfus, A. Étude des planètes par la polarisation de leur lumière. Supplements aux Annales d'Astrophysique 4, 3–114 (1957).
Spectropolarimetry of
        Earthshine with FORS@VLT

Sterzik, M. F., Bagnulo, S. & Pallé, E. Biosignatures as revealed by spectropolarimetry of Earthshine. Nature 483, 64–66 (2012).
Spectropolarimetry of ES:
Observing Date                  25-Apr-2011:UT09   10-Jun-2011:UT01
View of Earth as seen from
the Moon

                                                          12

Sun-Earth-Moon phase                 87 deg             102 deg
ocean fraction in Earthshine          18%                46%
vegetation fraction in                7%                  3%
Earthshine

tundra, shrub, ice and desert         3%                  1%
fraction in Earthshine

total cloud fraction in               72%                50%
Earthshine

cloud fraction t > 6                  42%                27%
10-Jun-2011:UT01
                                  25                                                1.0

                                       10 % vegetation does NOT fit !
                                  20
                                                     PU=U/I                         0.5
fraction of polarization PQ [%]

                                  15

                                                                                           P [%]
                                                                                    0.0
                                  10

                                   5                                                −0.5

                                   0
                                                                                    −1.0
                                        500     600             700     800   900
                                                      wavelength [nm]
25-Apr-2011:UT09
                                  25                                                1.0

                                       12 % vegetation DOES fit !
                                  20
                                                                                    0.5
fraction of polarization PQ [%]

                                  15

                                                                                           P [%]
                                                                                    0.0
                                  10

                                   5                                                −0.5

                                   0
                                                                                    −1.0
                                        500     600             700     800   900
                                                      wavelength [nm]
More (Spectro-)Polarimetry
                           A.No. 2]
                              Bazzon                                   Earthshine
                                     et al.: Measurement of the earthshine        Polarization
                                                                           polarization in theSpectra
                                                                                               B, V, R, and I band as function of phase
                    A. Bazzon et al.: Measurement of the earthshine polarization in the B, V, R, and I band as function of phase
                                                                                                                                                                                                  38-5

                                             of ES
                                                                                                                   Unfortunately it is not clear whether they measured the back-
                                                                                                                   scattering from maria or highlands. Sterzik et al. (2012) attribute
                                                                                                                   the polarization differences between the two epochs mainly to in-
                                                                                                                   trinsic differences of the polarization of Earth because the earth-
                                                                                                                   shine stems from different surface areas and were taken for days
                                                                                                                   with different cloud coverage. Considering our polarization val-
                                                                                                                   ues for highlands and maria then it could be possible that the
                                                                                                                   differences measured by Sterzik et al. (2012) are at least partly
                                                                                                                   due to the mare/highland depolarization difference (or surface
                                                                                                                   albedo difference).                                                                                                                                                                          A&A 562,
                                                                                                                          Another spectra-polarimetric observation of the earthshine
                                                                                                                   was published by Takahashi et al. (2013). They also find a rise 18
                                                                                                                                                                                                                                                                                        This work
                                                                                                                   of the fractional polarization of the earthshine towards the blue 16                                                                                                 Sterzik et al. 2012
                                                                                                                   but with a much flatter slope. Unfortunately they do not re- 14                                                                                                      Bazzon et al. 2013: highlands
                                                                                                                                                                                                                                                                                        Bazzon et al. 2013: maria
                                                                                                                   port whether their results were obtained from maria or high- 12                                                                              2
                                                                                                                                                                                                                                                                     H O

                                                                                                                   lands either. Therefore, only a qualitative comparison with our 10

                                                                                                                                                                                                                   p* (%)
                                                                                                                   data can be made. The observations of Takahashi et al. (2013) 8                                                                2
                                                                                                                                                                                                                                                       O    2
                                                                                                                                                                                                                                                               HO
                                                                                                                                                                                                                                                                    2
                                                                                                                                                                                                                                                                           O
                                                                                                                                                                                                                                                      H2O

                                                                                                                   are conducted at 5 consecutive nights and cover phase angles 6                                                           H2O

                                                                                                                   α = 49◦ − 96◦ . In the blue they find that the maximum polariza- 4
                                                                                                                   tion is reached at α ≈ 90◦ . However, for wavelengths > 600 nm 2
                                                                                                                   the polarization keeps increasing up to and including their last 0
                                                                                                                   measurement at α = 96◦ . They conclude that the phase with 0.3                                                                0.6       0.9         1.2        1.5         1.8          2.1
                                                                                                                   the highest fractional polarization αmax is shifted towards larger                                                                                 Wavelength (µm)

                                                                                                                   phase angles which could be explained by an increasing con-                                               Fig. 3. Our visible and NIR spectropolarimetric measurements of the
                                                                                                                   tribution of the Earth surface reflection. In our data we do earthshine                                   not            compared to literature data. A 10-pixel binning was applied
                          A. Bazzon et al.: Measurement of the earthshine polarization                             see    this  in  the
                                                                                                                                  shift   B,
                                                                                                                                           but V,     R,
                                                                                                                                                    neither and     I band
                                                                                                                                                                    can     we  as  function
                                                                                                                                                                                   exclude      itof  phase
                                                                                                                                                                                                    because      we   were   not
Fig. 7. Fractional polarization Q/I and U/I of the earthshine measured for highland (top) and mare regions (bottom) for the four                                                                                             to   the  NIR  spectrum   of region B. The uncertainty per wavelength is plot-
different filters B, V, R and I (left to right). The solid curves are qmax sin2 fits to the data.                   able  Thetoerror
                                                                                                                                 derive
                                                                                                                                      bars meaningful
                                                                                                                                             give the statistical      data 1σ due to the very strong stray light            ted as vertical gray error bars. Wavelengths of strong telluric absorption
                                                                                                                     Unfortunately                 it is and  not      clear     whether                                             Miles-Páez,      P. Some
                                                                                                                                                                                                                                                         A., Pallé,   E. & Zapatero         Osorio,      M. R.
noise ∆noise of the data whereas the mare I band data at phase angle 109.5◦ are additionally                       from    affected    by a substantial
                                                                                                                              the moonshine                      systematic
                                                                                                                                                                       the weak         signalthey  from measured        thehave
                                                                                                                                                                                                             the earthshine.   back-  been removed.              molecular      species seen      in “emission”       (in-
offset ∆syst > 0.5 %. The dots in the V panel for the mare region indicate the measurementsscattering                   of Dollfus (1957)from     and maria        or
                                                                                                                                                        a correspondinghighlands.         Sterzik       et  al.  (2012)    attribute
                                                                                                                                                                                                                             dicativeSimultaneous
                                                                                                                                                                                                                                         of  strong     optical and
                                                                                                                                                                                                                                                     atmospheric     fluxnear-infrared
                                                                                                                                                                                                                                                                             absorption   and linear
                                                                                                                                                                                                                                                                                                less    multiscattering
qmax sin2 fit (dashed line) is also given.
                                                                                                                   In    this    regime         our       linear       extrapolation           method        to   subtract    the
                                                                                                                     the polarization                                                                               mainlyprocesses  spectropolarimetry
                                                                                                                                                                                                                                           occurring at those   of particular
                                                                                                                                                                                                                                                                   the earthshine.        A&A 562,
                                                                                                                                                                                                                                                                                 wavelengths)              L5 (2014).
                                                                                                                                                                                                                                                                                                     are labeled.    The
                                                                                                                   background             stray differences
                                                                                                                                                       light from between    the earthshine the two      epochs
                                                                                                                                                                                                      signal     introduces     toa in-
                                                                                                                     trinsicsystematic
                                                                                                                   strong         differences               of the polarization
                                                                                                                                                      overestimate               ∆syst of the of Earth
                                                                                                                                                                                                    result because
                                                                                                                                                                                                             (see Sect.      vertical
                                                                                                                                                                                                                         the4.2).
                                                                                                                                                                                                                               earth-    dashed   line separates   the  ALFOSC        and  LIRIS      data.
and the estimated statistical 1σ uncertainties of the individual also support phase curves qmax sin p (α). She calculates polariza-
data points ∆noise . The mare V band panel shows also the mea- tion phase curves assuming
                                                                                                                     shine
                                                                                                                   Takahashi     stems
                                                                                                                           a range of
                                                                                                                                            from
                                                                                                                                      etsurface
                                                                                                                                           al.    (2013) different
                                                                                                                                                      types (e.g.also       surface
                                                                                                                                                                          use
                                                                                                                                                                       forest-
                                                                                                                                                                                        areas
                                                                                                                                                                                  a linear         and were taken
                                                                                                                                                                                               extrapolation        method forto days
surements by Dollfus (1957) which are in good agreement with covered areas with Lambertian                           with different
                                                                                                                   determine                     cloud
                                                                                                                                      the earthshine
                                                                                                                                reflection,   dark     oceancoverage.
                                                                                                                                                                 with   spec- Considering
                                                                                                                                                                      polarization                      our polarization
                                                                                                                                                                                           but unfortunately            they doval- We compare our measurements with data from the literature
our data.                                                                            ular reflection) and cloud      ues      for
                                                                                                                           coverages.highlands
                                                                                                                                           We     find      and
                                                                                                                                                          that    themaria
                                                                                                                                                                        broad     then
                                                                                                                   not describe their data reduction in detail. Therefore, consider-      it  could      be    possible    that     the
                                                                                                                                                                                                                             in Fig. 3. To improve the quality of the NIR linear polarization
     Our earthshine data show a very good correlation between shape of her model phase curves can be well fitted by curves
                                                                                                   p                 differences
                                                                                                                   ing
the polarization taken simultaneously for the highland and mare ∼ qmax sin (α + α0 ) with p ≈ 1.5 − 3 and α0 ≈ 0 − 10 .   the              measured
                                                                                                                                 limitations            of
                                                                                                                                                        ◦     our ◦by    Sterzik
                                                                                                                                                                      linear           et  al.
                                                                                                                                                                                  extrapolation, (2012)  it  are
                                                                                                                                                                                                            could  at  least
                                                                                                                                                                                                                      be       partly spectrum of region B, we applied a ten-pixel binning in
                                                                                                                                                                                                                             degree
                                                                                                                                                                                                                          possi-
regions. Independent of color filter and phase angle the polariza-                        Furthermore, she finds     duethat
                                                                                                                   ble        to the
                                                                                                                                   the shift
                                                                                                                           characteristic  mare/highland
                                                                                                                                                     of αatmax
                                                                                                                                              features           lowreporteddepolarization
                                                                                                                                                                        phase         by Takahashi    difference
                                                                                                                                                                                                             et al. (2013)   the is spectral dimension. Overlaid in Fig. 3 are the optical p∗ val-
                                                                                                                                                                                                                       (or surface
                                                                                                                                                                                                            ◦
tion for the mare region is a factor of 1.30 ± 0.01 higher than for angles due to the rainbow                      due
                                                                                                                     albedoto   thedifference).
                                                                                                                            effect     strong
                                                                                                                                    and    negative stray       light atatphase angles > 90 .
                                                                                                                                                          polarization                                                       ues obtained at a spectral resolution of 3 nm and for two sep-
the highland region as illustrated in Figure 8.                                      large phase angles due to second order scattering. We cannot
     Good correlations are also found between different colors assess the presence of such features                        Overall,
                                                                                                                             Another       the
                                                                                                                                      because         spectral
                                                                                                                                              spectra-polarimetric
                                                                                                                                                   of the coarse phase  dependence             of    the    polarization
                                                                                                                                                                                        observation of the earthshine        arated
                                                                                                                                                                                                                                of dates by Sterzik et al. (2012), and the broadband filter
taken for the same observing date. When we plot the polariza- sampling of our data. Sterzik                                      et al. (2012)
                                                                                                                     was published                          and Takahashi
                                                                                                                                                    by Takahashi                 et al.et(2013).
                                                                                                                                                                                           al. (2013)  They      also findmeasurements
                                                                                                                                                                                                             is qualitatively  a rise               of Moon highlands and maria made by Bazzon
tion (Q/I)es in the V, R and I band versus the polarization in the                        Besides the qmax sin       2
                                                                                                                   similar
                                                                                                                     of the to
                                                                                                                       (α)   curve    our measurements
                                                                                                                                     we  also
                                                                                                                                  fractional      tried    functions
                                                                                                                                                        polarization     withbutofthe thelevel     and slope
                                                                                                                                                                                            earthshine             of the the
                                                                                                                                                                                                               towards       et blue
                                                                                                                                                                                                                           frac-   al. (2013) for a Sun-Earth-Moon phase angle similar to ours.
Fig.
B  band 13.
         (Fig.Top:we Earthshine
               9)A.,   find that the H.  polarization
                                     ratios
                                          M.are&independent       results      at quadrature
                                                                     ofMeasurement
                                                                        αE . We      more free           for
                                                                                                     parameters     to fit the data, e.g. using a curve like
get
maria
     Bazzon,
     the ratios
                        Schmid,
                0.72highlands
                       ± 0.02, 0.49 (+).
          (∗) earthshine
               and                    ± 0.02The
                                                    Gisler, D.
                                               and thin0.28 ±lines0.05 for
                                                                         givethetheqmax
                                                                                               of
                                                                                            sin p (α et
                                                                                        Sterzik       + αal.         but with a much flatter slope. Unfortunately they do not optical
                                                                                                                   tional       polarization
                                                                                                          0 ) and varying the exponent p between values
                                                                                                                                                          differ         quantitatively.           Because        Sterzik   etAll
                                                                                                                                                                                                                               al.  re-       data display a qualitatively similar pattern (previously
         the                    polarization          in   the    B,   V,  R,   and     I band
ratios of the polarization between V and B band, R and B band, of 1.5-3 and by introducing
(2012)      spectro-polarimetry               for we   waning          (dashed)          and(a)–(e)
                                                                                                 waxing
                                                                                                                   (2012)
                                                                                                                     port        andshift
                                                                                                                         Takahashi,
                                                                                                                               whether
                                                                                                                           a phase     Takahashi
                                                                                                                                             αJ.  . et
                                                                                                                                               ı0their
                                                                                                                                                    However,    Phase
                                                                                                                                                               et
                                                                                                                                                         al.results al.
                                                                                                                                                                    such(2013)  Variation
                                                                                                                                                                             were
                                                                                                                                                                            fits
                                                                                                                                                               10 (60ı ), our
                                                                                                                                                                                      provide
                                                                                                                                                                                       obtained     noEarthshine
                                                                                                                                                                                                   of   information
                                                                                                                                                                                                       from
                                                                                                                                                                           March 11 (72ı ), March 12 (84ı ), and
                                                                                                                                                                                                                          ordiscussed),
                                                                                                                                                                                                                 maria about   high-           but they differ quantitatively in the amount of polar-
and      asBfunction
      I and                    ofFig.
               band respectively.     3.
                                    phase Polarization
                                      Therefore, .  arXiv spectra
                                                            concludeof Earthshine.
                                                                         that
                                                                astro-ph.EP,   to    Panels
                                                                                       (2013).
                                                                                     provide    not   are
                                                                                                      a   results from March
                                                                                                                   the
                                                                                                        significantly
                                                                        ◦ bars signify standard deviation in thelands     lunar
                                                                                                                         better   09 (! =to49the
                                                                                                                                     surface
                                                                                                                               Polarization
                                                                                                                                  match
                                                                                                                                 either.
                                                                                                                                                  ), March
                                                                                                                                                     albedo
                                                                                                                                                        Spectra.
                                                                                                                                                      data.
                                                                                                                                              Therefore,            for
                                                                                                                                                              Because
                                                                                                                                                            is shownonly
                                                                                                                                                                           their
                                                                                                                                                                         Publicationsmeasuring
                                                                                                                                                                                 a qualitative of     area
                                                                                                                                                                                                    the       and
                                                                                                                                                                                                       comparison   do   not ization
                                                                                                                                                                                                                          withas-   our per wavelength and the spectral slope. The spectral slope
(dotted)
first        moon
      order we          at Earth
                 can assume     the phases
                                 March
                                     same13 (96
                                            shape87◦forand
                                                ı ), respectively.
                                                             the 102  Errorrespectively
                                                                  polarization       data cover  and     the
                                                                                                     predominantly      observed
                                                                                                                          phase    sets. Noaround
                                                                                                                                   angles     error    barquadrature    in (a)  because
                                                                                                                                                                            theJapan    only one effective  set was
Takahashi
phase   curve foretallal.        obtained.  Panel    (f) is a
                          (2013) spectro-polarimetry (dash-dot)
                       wavelengths.                            plot of results  for all the dates.
                                                                                     shape of at     Derived
                                                                                                       96
                                                                                                  the phase
                                                                                                        ı
                                                                                                                   sess
                                                                                                               spectra
                                                                                                           ◦ curvedata
                                                                                                             .          are the   stray
                                                                                                                               Astronomical
                                                                                                                             binned
                                                                                                                       is not can    by  3 light
                                                                                                                                           nm    (5    effects
                                                                                                                                                     pixels)
                                                                                                                                       be constrained.
                                                                                                                                very well    made.  ı        The observations of Takahashi et al. (2013) et al. (2012) and Bazzon et al. (2013) data is steeper
                                                                                                                                                          Society
                                                                                                                                                               to     from
                                                                                                                                                                   obtain of
                                                                                                                                                                           a    the
                                                                                                                                                                              better bright
                                                                                                                                                                                     S=N 65,    moonshine
                                                                                                                                                                                                38
                                                                                                                                                                                           ratio.    (2013).
                                                                                                                                                                                                   The results    their
                                                                                                                                                                                                               from          of
                                                                                                                                                                                                                         results   Sterzik
MYSTIC 3D-vec. rad. transfer

n be
 rth-
 ther       brief section about Monte Carlo method with polarization
                                                                     Fig. 2. Example calculation for a simulation of the earth as seen by
and-        Emde et al. (2010)
                                                                     the moon for a homogeneous atmosphere for a phase angle of 0°.
  ob-          fully spherical geometry
ans-                   w/ C. Emde (Monte Carlo code for the phYSically correct Tracing of photons In Cloudy atmospheres)
ount
 oud
face
 and
 ma-
 ible
ence
 hod
 due
  the
  ice
 dge
ons.
  ap-
  for
met-                                         4                                             C. Emde et al.: Spectropolarimetric signatures of Earth-like planets
om-
T in     Emde, C., Buras, R., Mayer, B. &
            Fig. 1.M.Example
         Blumthaler,             calculation
                        The impact  of aerosols for a simulation of the earth as seen Fig. 3. Example calculation for a simulation of the earth as   seen by
            by the moon.
         on polarized        Surface
                      sky radiance:     albedo is taken from ECHAM model and the
                                    model
         development, validation, and                                                 the moon for a homogeneous atmosphere for a phase angle        of 90°.
            simulation    is done   without
         applications. Atmos. Chem. Phys. 10,
                                              atmosphere. The  phase angle is 80°.
         383–396–396 (2010).

        Emde, C., Buras, R. & Mayer, B. An                                 40      show image of simulation for geometry of 25 April 2011,
          efficient method to compute high                                      include clouds, atmosphere, aerosol
          spectral resolution polarized
          solar radiances using the Monte
                                                                                   ALIS Emde et al. (2011) show spectrum for example
          Carlo approach. Journal of                                            above
          Quantitative Spectroscopy and
          Radiative Transfer 112, 1622–                                            REPTRAN Gasteiger et al. (2014)
          1631 (2011).
MYSTIC 3D-vec. rad. transfer

   Fig. 7. Wavelength dependent flux F , polarization difference Q and degree of polarization P . The solid lines show MYSTIC calculations and
   the error bars correspond to the standard deviation. A Lambertian surface albedo of 0 is assumed. The aerosol mixtures have been defined
   according to Hess et al. (1998); Emde et al. (2010).

   Fig. 8. Same as Fig. 7 but for a green surface.
towards 3D-vec. rad. transfer
8                                                          C. Emde et al.: Spectropolarimetric signatures of Earth-like planets

Fig. 9. Sensitivity on cirrus cloud top height. The geometrical thickness of the cloud layer is 1 km. The optical thickness of the cloud at
550 nm is 2 and a general habit mixture as in Baum et al. (2005) is assumed. The underlying surface albedo is 0.

Fig. 9. Sensitivity on cirrus cloud top height. The geometrical thickness of the cloud layer is 1 km. The optical thickness of the cloud at
550 nm is 2 and a general habit mixture as in Baum et al. (2005) is assumed. The underlying surface albedo is 0.

Fig. 10. Sensitivity on cirrus optical thickness. The cloud layer is placed at 10km–11km altitude. A general habit mixture as in Baum et al.
(2005) is assumed. The underlying surface albedo is 0.
Spectro-Polarimetry of Planet
  Earth through Earthshine
 (+) robust tool to retrieve integrated surface and
 atmospheric properties

 (+) sensitive on biosignatures (VRE, O2, H2O)

 (-) restricted phase coverage

 (-) improve lunar depolarisation models

 (-) improve Earth VRT atmosphere/surface/haze modeling

 (-) long shot towards biosignatures on exo-planets…

 (+) SP of Planet Earth can constrain the design of future
 exo-Life machines
Construction of the 39m-ELT
     has been approved
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